Patent classifications
C11C3/123
PURIFICATION OF RECYCLED AND RENEWABLE ORGANIC MATERIAL
A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material includes more than 1 ppm silicon as silicon compounds and/or more than 10 ppm phosphorous as phosphorous compounds. The method can include providing a feed of the lipid material; heat treating the organic material in presence of an adsorbent and the filtering organic material and hydrotreating the lipid material in a presence of a hydrotreating catalyst to obtain purified hydrotreated organic material having less than 20% organic material and/or less than 30% of the original phosphorous content of the organic material.
METHOD FOR REDUCING DEACTIVATION OF A HYDROTREATMENT CATALYST
The present invention relates to a method for reducing deactivation of a hydrotreatment catalyst. The hydrotreatment catalyst is used as a main active catalyst for producing renewable hydrocarbons by hydrotreatment from a renewable feedstock which comprises at least an oxygen containing compound, at least one metal containing compound and at least one phosphorus containing compound as impurities. The method comprising adjusting the metal to phosphorus (M:P) weight ratio of the renewable feedstock to a value within the range from 0.70 to 1.26, measured as elemental metal and elemental phosphorus, subjecting the obtained feedstock to a temperature of from 190 to 400° C. under reducing conditions, thereby forming a solid precipitate comprising at least one metal and phosphorus containing compound, and contacting the obtained liquid renewable feedstock with the main active catalyst, in the presence of hydrogen.
Method of manufacturing renewable diesel from biological feedstock
A method for producing renewable diesel includes introducing a primary feedstock comprising biologically-derived triglycerides with catalyst poisons into a first reaction chamber and hydrolyzing the primary feedstock within the first reaction and liquid-liquid extraction chamber for at least an hour such that the reacted triglycerides are separated into an aqueous solution comprising glycerol and catalyst poisons, and an intermediate feedstock comprising free fatty acids and catalyst poisons. The method also includes distilling the intermediate feedstock to separate the intermediate feedstock into a purified intermediate stream and a lower volume bottom stream containing unreacted triglyceride, diglyceride, monoglyceride, FFA and catalyst poisons. The method also includes combining the purified intermediate feedstock with a hydrogen stream and converting, in a second reaction chamber comprising a metallic catalyst bed, the purified intermediate feedstock into a product comprising long-chain alkanes. The method also includes hydrotreating the purified intermediate feedstock into a renewable diesel product.
PURIFICATION OF RECYCLED AND RENEWABLE ORGANIC MATERIAL
A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material contains one or more impurities selected from a group consisting of silicon compounds, phosphorous, Cl and sterols. Exemplary embodiments include (a) providing the recycled or renewable organic material; (c) heat treating the recycled or renewable organic material at 100 to 450° C.; and (f) hydrotreating the heat treated recycled or renewable organic material in a presence of a hydrotreating catalyst; to obtain purified hydrotreated recycled or renewable organic material.
PREPARATION METHOD AND SYSTEM OF LOW-CARBON JET BIOFUEL BASED ON WHOLE LIFE CYCLE
Disclosed are a preparation method and a system of low-carbon jet biofuel based on whole life cycle. A low-carbon method and a system of using whole life cycle involving whole process from raw material acquisition, fuel preparation to fuel application are related. A prepared jet biofuel can be used in six types of aircrafts and engines thereof. Aircrafts using the jet biofuel can have a portion of greenhouse gas emission reduction of 50% to 80%.
METHOD OF MANUFACTURING RENEWABLE DIESEL FROM BIOLOGICAL FEEDSTOCK
A method for producing renewable diesel includes introducing a primary feedstock comprising biologically-derived triglycerides with catalyst poisons into a first reaction chamber and hydrolyzing the primary feedstock within the first reaction and liquid-liquid extraction chamber for at least an hour such that the reacted triglycerides are separated into an aqueous solution comprising glycerol and catalyst poisons, and an intermediate feedstock comprising free fatty acids and catalyst poisons. The method also includes distilling the intermediate feedstock to separate the intermediate feedstock into a purified intermediate stream and a lower volume bottom stream containing unreacted triglyceride, diglyceride, monoglyceride, FFA and catalyst poisons. The method also includes combining the purified intermediate feedstock with a hydrogen stream and converting, in a second reaction chamber comprising a metallic catalyst bed, the purified intermediate feedstock into a product comprising long-chain alkanes. The method also includes hydrotreating the purified intermediate feedstock into a renewable diesel product.
METHOD OF PROCESSING A BIO-BASED MATERIAL AND APPARATUS FOR PROCESSING THE SAME
The present invention relates to a method for processing a renewable bio-based material comprising the step of reacting the bio-based material with hydrogen in the presence of a catalyst on a support in a reactor to form a treated oil; (i) passing the treated oil through a distillation unit and an adsorption unit to form green diesel; and/or (ii) passing the treated oil through at least one distillation column to separate the treated oil into at least one component and passing the at least one component through an adsorption column; and wherein the reactor comprises a cooling function for controlling the temperature of the reactor, wherein the cooling function is at least one of an internal cooling function and an external cooling function.
Purification of recycled and renewable organic material
A method is disclosed of purifying a recycled or renewable organic material, wherein the recycled or renewable organic material contains one or more impurities selected from a group consisting of silicon compounds, phosphorous, Cl and sterols. Exemplary embodiments include (a) providing the recycled or renewable organic material; (c) heat treating the recycled or renewable organic material at 100 to 450? C.; and (f) hydrotreating the heat treated recycled or renewable organic material in a presence of a hydrotreating catalyst; to obtain purified hydrotreated recycled or renewable organic material.
OPTIMIZED PROCESS FOR THE HYDROTREATING AND HYDROCONVERSION OF FEEDSTOCKS DERIVED FROM RENEWABLE SOURCES
The present invention describes a process for treating a feedstock obtained from a renewable source, comprising a step a) of hydrotreating said feedstock, a step b) of separation into at least a light fraction and at least a hydrocarbon liquid effluent, a step c) of removing at least a portion of the water from the hydrocarbon liquid effluent, a step d) of hydroconversion of at least a portion of the hydrocarbon liquid effluent, said hydroconversion step d) being characterized firstly by the use of a bifunctional catalyst comprising a molybdenum and/or tungsten sulfide phase promoted with nickel and/or cobalt and secondly by a ratio between the partial pressure of hydrogen sulfide and of hydrogen at the inlet of the hydroconversion unit of 10 less than 5?10.sup.?5 and a step e) of fractionation of the effluent obtained from step d) to obtain at least a middle distillate fraction.
Process for the selective hydrogenation of vegetable oils
Process for the catalytic hydrogenation of vegetable oils wherein the oil is placed in contact with molecular hydrogen in the presence of a metal catalyst, and the process is performed in the absence of water or in the presence of a quantity of water equal to or less than 5:1 with respect to the weight of the metal catalyst and at a temperature equal to or less than 50 C.