The present invention provides methods for producing golf balls having polyurethane covers and the resultant balls. Multi-piece golf balls having an inner core and outer cover with one or more intermediate layers disposed between the core and cover can be formed. The methods involve producing hydroxyl-terminated adducts and isocyanate-terminated prepolymers. Thermoset and thermoplastic polyurethane compositions can be prepared. The resulting polyurethane compositions and golf ball covers have high thermal stability and good wear-resistance and durability.

A golf ball a core, one or more intermediate layers, and one or more cover layers. The core may comprise an inner portion and an outer portion. One or more layers of the golf ball may be formed by the application of ultrasonic welding on two half shells to form. One or more of the layers may be formed by a number of different chemical compositions, and may have varying thicknesses, hardnesses, coefficients of restitution, and PGA compression. The golf ball itself may have varying coefficient of restitution and PGA compression, depending on the layers.

An object of the present disclosure is to provide a golf ball having improved flight distance on driver shots and excellent spin performance on approach shots (particularly under the condition that there is grass between the golf ball and the club face) and on middle iron shots. The present disclosure provides a golf ball comprising a spherical core and a cover disposed outside the spherical core, wherein when a center hardness of the spherical core (Shore C hardness), hardnesses at 2.5 mm, 5 mm, 7.5 mm, 10 mm, 12.5 mm and 15 mm points from a center of the spherical core toward a surface of the spherical core (Shore C hardness), and a surface hardness of the spherical core (Shore C hardness) are represented by H.sub.0, H.sub.2.5, H.sub.5, H.sub.7.4, H.sub.10, H.sub.12.5, H.sub.15 and H.sub.s respectively, the following relation is satisfied:

(H.sub.2.5−H.sub.0)>(H.sub.12.5−H.sub.10)>(H.sub.s−H.sub.15).

A golf ball a core, one or more intermediate layers, and one or more cover layers. The core may comprise an inner portion and an outer portion. One or more layers of the golf ball may be formed by the application of ultrasonic welding on two half shells to form. One or more of the layers may be formed by a number of different chemical compositions, and may have varying thicknesses, hardnesses, coefficients of restitution, and PGA compression. The golf ball itself may have varying coefficient of restitution and PGA compression, depending on the layers.

Golf balls having cores with increased hardness gradients are provided. The cores have an increased “positive” hardness gradient (or a “hard-to-soft” hardness) where the outer surface of the core is harder than the center. The increased positive hardness gradient can be achieved by introducing a water-releasing agent into the core rubber formulation during the curing process. The resulting golf balls have reduced spin and sufficient impact durability.

Golf balls having cores with increased hardness gradients are provided. The cores have an increased “positive” hardness gradient (or a “hard-to-soft” hardness) where the outer surface of the core is harder than the center. The increased positive hardness gradient can be achieved by introducing a water-releasing agent into the core rubber formulation during the curing process. The resulting golf balls have reduced spin and sufficient impact durability.

Golf balls having cores with increased hardness gradients are provided. The cores have an increased “positive” hardness gradient (or a “hard-to-soft” hardness) where the outer surface of the core is harder than the center. The increased positive hardness gradient can be achieved by introducing a water-releasing agent into the core rubber formulation during the curing process. The resulting golf balls have reduced spin and sufficient impact durability.

A golf ball having a core and a cover that is formed of a resin composition which includes (A) a polyurethane or a polyurea and (B) a styrenic resin material, when dropped from a height of 3 m and made to collide with a metal plate, has velocities 200 ms before and 200 ms after contact that satisfy the condition: (incident velocity)(rebound velocity)0.80 m/s. The ball has a good controllability on approach shots without a loss in the distance achieved on shots with a driver, and thus is particularly useful to professional golfers and skilled amateurs.

In a multi-piece solid golf ball having a core, an intermediate layer encasing the core and a cover which encases the intermediate layer and has numerous dimples on an outside surface thereof, the intermediate layer is formed of a resin material, the cover is formed of a urethane resin material, the core has a diameter of at least 38.0 mm, the core has a deflection when compressed under a final load of 1,275 N (130 kgf) from an initial load of 98 N (10 kgf) of at least 3.9 mm, the core has a center and a surface such that the value obtained by subtracting the JIS-C hardness at the core center from the JIS-C hardness at the core surface is at least 15, the sphere obtained by encasing the core with the intermediate layer (intermediate layer-encased sphere) has a surface hardness on the Shore D hardness scale of at least 69, the ball has a surface hardness on the Shore D hardness scale of 62 or less, and the (intermediate layer thickness)/(core diameter) value is from 0.025 to 0.043, the (cover thickness)/(core diameter) value is from 0.014 to 0.027.

A golf ball includes a core, a mid layer, and a cover. A ratio R1 calculated by mathematical formula (1): R1=(Df1Df2)/(Df2Df3) is not less than 5.00. A ratio R2 calculated by mathematical formula (2): R2=(T2*H2)/H3 is not less than 2.00. A ratio R3 calculated by mathematical formula (3): R3=D1/T3 is not less than 50. In mathematical formulas (1) to (3), Df1 represents an amount of compressive deformation of the core, Df2 represents an amount of compressive deformation of a sphere including the core and the mid layer, Df3 represents an amount of compressive deformation of the golf ball, T2 represents a thickness of the mid layer, H2 represents a hardness of the mid layer, H3 represents a hardness of the cover, D1 represents a diameter of the core, and T3 represents a thickness of the cover.