A golf ball with improved durability is disclosed herein. The golf ball has a core comprising a polybutadiene material and methyl methacrylate, butadiene, styrene (MBS) with a weight percentage of MBS ranging from 0.5 to 5 weight percent of the core.

A golf ball with a core comprising polybutadiene and graphene is disclosed herein. The golf ball has a single core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an inner core comprising polybutadiene and graphene. Alternatively, the golf ball has a dual core with an outer core comprising polybutadiene and graphene.

A rubber composition for golf balls includes (A) a base rubber, (B) an acrylate ester or methacrylate ester containing an isocyanate group or a blocked isocyanate group, (C) diacrylic acid, dimethacrylic acid or a metal salt thereof, and (D) an organic peroxide. In a golf ball having a core formed of the rubber composition and a cover of one or more layers which encases the core, the rubber composition exhibits a spin rate-lowering effect on shots and can thus improve the flight performance of the ball.

A method for forming a golf ball core with a nanofiller masterbatch is disclosed herein. The method includes mixing the nanofiller masterbatch, a graphene masterbatch material with other materials to form a core mixture, wherein the masterbatch preferably comprises 1-80% by weight of nanofillers and 20-99% by weight of a carrier polymer.

A method for forming a golf ball core with a nanofiller masterbatch is disclosed herein. The method includes mixing the nanofiller masterbatch, a graphene masterbatch material with other materials to form a core mixture, wherein the masterbatch preferably comprises 1-80% by weight of nanofillers and 20-99% by weight of a carrier polymer.

Multi-layered golf balls having at least one layer made of a foamed silicone composition are provided. Multi-layered golf balls having at least one layer made of non-foamed silicone elastomer composition also are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The foamed silicones have good thermal stability and durability without sacrificing resiliency. The non-foamed silicone elastomers have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

Multi-piece golf balls having a multi-layered solid core and multi-layered cover are provided.

A golf ball 2 includes a core 4, a mid layer 6, a cover 8, and dimples 10. A difference DH in hardness between a surface and a central point of the core 4, a thickness Tm and a hardness Hm of the mid layer 6, a thickness Tc and a hardness Hc of the cover 8, and an amount of compressive deformation Sb meet the following mathematical formulas.

(DH*Hm)/(Hc*Tc)>80

((Sb*Tc)/(Hc* Hm*Tm))*1000>0.75

An area ratio So of dimples 10 and a ratio Rs of a number of the dimples 10 each having a diameter of equal to or greater than 9.60% but equal to or less than 10.37% of a diameter of the golf ball 2 meet the following mathematical formula (3).

Rs≧−2.5*So+273   (3)

A golf ball includes: a radio frequency identification (RFID) tag including an IC chip and an antenna; a protection layer surrounding the outer periphery of the RFID tag; a relaxation layer surrounding the outer periphery of the protection layer; a core surrounding the outer periphery of the relaxation layer; and a cover surrounding the outer periphery of the core. The curing temperature of the protection layer is 60° C. or less, and the protection layer is formed with a material having a hardness of Shore D 60 or more. The relaxation layer is formed with a thermoplastic elastomer-based material having a hardness with a difference from a hardness of a surface of the core on a side contacting the relaxation layer of Shore D 20 or less.

A golf ball includes a core having an outer surface and a geometric center; an inner cover layer, and an outer cover layer. The inner cover layer includes an ionomeric material and has a material hardness of about 60 Shore D or greater. The outer cover layer is formed from a polyurea or polyurethane and has a material hardness of about 60 Shore M or greater. The outer surface of the core has a hardness of about 68 to 92 Shore C. The geometric center of the core has a hardness of about 45 to 85 Shore C. The core outer surface hardness is greater than the geometric center hardness by about 5 to 21 Shore C to define a positive hardness gradient. The core also has a volume weighted average hardness, H.sub.V, of about 70 to 80, where

[00001]${\stackrel{\_}{H}}_V=\frac{I_V}{V_c}.$