A thermoplastic multi-layer golf ball has a core center including a first thermoplastic material, a core layer including a second thermoplastic material, and a cover including a third thermoplastic material. The core center has a diameter of 21-29 mm and a surface Shore D hardness H1 of less than about 50. The core layer is at least about 5 mm thick with an outer surface Shore D hardness H2 of more than about 50. The cover has an outer surface Shore D hardness H3 of more than about 60. H3 is up to about 20 Shore D units higher than H2, and H2 is up to about 10 Shore D units higher than H1. The core layer has a specific gravity that is at least 0.1 g/cm.sup.3 greater than the specific gravity of the core center.

Multi-layered golf balls having at least one layer made of a foamed silicone composition are provided. Multi-layered golf balls having at least one layer made of non-foamed silicone elastomer composition also are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The foamed silicones have good thermal stability and durability without sacrificing resiliency. The non-foamed silicone elastomers have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

In a golf ball having a core, envelope layer, intermediate layer and cover, the (core diameter)/(ball diameter) value falls within a particular range, the core has a specific hardness profile, and the Shore C hardness relationships among the core center and surface hardnesses and the surface hardnesses of the envelope layer-encased sphere, intermediate layer-encased sphere and ball satisfy the following conditions:

core surface hardness<surface hardness of envelope layer-encased sphere<surface hardness of intermediate layer-encased sphere>ball surface hardness,  (1)

(surface hardness of envelope layer-encased sphere)−(core center hardness)≥28.  (2)

Also, the envelope layer, intermediate layer and cover have respective thicknesses which satisfy the condition:

cover thickness<intermediate layer thickness  (3)

cover thickness<envelope layer thickness  (4)

envelope layer thickness≥0.8 mm.  (5)

This ball enables mid-level and skilled amateur golfers to achieve superior distances on driver shots and on iron shots, and moreover has a soft yet good feel at impact.

In a golf ball having a core composed of one or more layer, the outermost layer of the core is formed of a rubber composition containing a base rubber and an α,β-unsaturated metal carboxylate, an envelope layer directly encasing the core is formed of a resin composition containing a thermoplastic resin having a structure that includes α,β-ethylenically unsaturated carboxylic acid copolymerization units, and a surface of the core outermost layer and the envelope layer adjoin each other through an intervening oxazoline group-containing substance. The golf ball has improved adhesion between the rubber-based core and the cover layer that directly encases the core and is formed of an ionomer resin or other α,β-ethylenically unsaturated carboxylic acid copolymer-containing resin material.

An object of the present invention is to provide a golf ball traveling a great flight distance and having a good shot feeling and durability on driver shots. The present invention provides a golf ball comprising a core, at least one intermediate layer covering the core and a cover covering the intermediate layer, wherein the core is formed from a core rubber composition containing (a) a base rubber containing a polybutadiene, (b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator, and (d) a terpene-based resin, and a material hardness (Hm) of the intermediate layer and a material hardness (Hc) of the cover satisfy an equation of Hm≤Hc.

The invention provides a distance golf ball endowed with a good flight performance when struck with a driver or an iron by an ordinary amateur golfer, a good durability to repeated impact and a soft feel. The ball is a multi-piece solid golf ball having a core, an intermediate layer and a cover, wherein the core is formed as one or more layer of a rubber composition, the intermediate layer is formed primarily of an ionomer resin, the intermediate layer and the cover are both single layers, each containing an inorganic granular filler, and the ball satisfies the following conditions: surface hardness of ball > surface hardness of sphere consisting of core encased by intermediate layer (intermediate layer-encased sphere), Shore D hardness at surface of ball - Shore D hardness at center of core ≥ 37, specific gravity of cover > specific gravity of intermediate layer.

A golf ball for amateur golfers is endowed with an excellent flight and a good feel at impact that is soft yet solid when hit by a golfer whose head speed is not very high. The ball, which includes a core and a cover, has a compressive deformation B when subjected to a final load of 30 kgf from an initial load state of 5 kgf that is from 0.72 to 0.97 mm and a compressive deformation C when subjected to a final load of 60 kgf from an initial load state of 5 kgf that is from 1.55 to 1.85 mm. In addition, the core has a hardness profile which satisfies specific conditions.

An object of the present invention is to provide a golf ball traveling a great flight distance and having a good shot feeling on long iron shots. The present invention provides a golf ball comprising a core, at least one intermediate layer covering the core and a cover covering the intermediate layer, wherein the core is formed from a core rubber composition containing (a) a base rubber containing a polybutadiene, (b) an α,β-unsaturated carboxylic acid having 3 to 8 carbon atoms and/or a metal salt thereof as a co-crosslinking agent, (c) a crosslinking initiator, and (d) a terpene-based resin, and a material hardness (Hm) of the intermediate layer is higher than a material hardness (Hc) of the cover, and the material hardness (Hc) of the cover is 50 or more in Shore D hardness.

In a golf ball having a core, an intermediate layer and a cover, the core is formed primarily of a base rubber and has a diameter set in a specific range, and the intermediate layer and cover are each formed of resin materials. The core has an internal hardness such that, regarding the hardness at the core center, the hardnesses at positions located at 2 mm intervals from the core center outward up to 16 mm and the core surface hardness, the hardness differences therebetween are set within a specific range. The ball surface hardness is set so as to be higher than the surface hardness of the intermediate layer-encased sphere. This ball achieves a satisfactory distance on full shots not only with a driver, but also with a long iron or a middle iron, in addition to which it has an excellent durability to repeated impact.

In a multi-piece solid golf ball having a core, an envelope layer, an intermediate layer and a cover, the envelope layer is formed into two layers—an inner envelope layer and an outer envelope layer. The inner envelope layer-encased sphere, outer envelope layer-encased sphere, intermediate layer-encased sphere and ball have respective surface hardness that satisfy a specific relationship. The inner envelope layer or outer envelope layer is formed primarily of one or more elastomer, and further the core has a particular hardness profile. This ball has an excellent flight when struck by golfers whose head speeds are not that fast and has a good, soft feel at impact, thus making it highly suitable for amateur golfers.