Patent classifications
B01D2255/504
HONEYCOMB STRUCTURE
The honeycomb structure includes a honeycomb structure body having porous partition walls, and a plugging portion disposed in one of open ends of each cell, a thickness of the partition walls is 0.30 mm or more and 0.51 mm or less, a cell density is 30 cells/cm.sup.2 or more and 93 cells/cm.sup.2 or less, a filtration area (cm.sup.2) of inflow cells included per cm.sup.3 of the honeycomb structure body is defined as an inflow side filtration area G (cm.sup.2/cm.sup.3), a value obtained by dividing a pore volume Vp (cm.sup.3) formed in the partition walls by a total volume Va (L) including the cells is defined as a pore volume ratio A (cm.sup.3/L), and in this case, a product of the inflow side filtration area G (cm.sup.2/cm.sup.3) and the pore volume ratio A (cm.sup.3/L) is 1800 cm.sup.2/L or more and 3200 cm.sup.2/L or less.
Method for removing N2O and NOx from the nitric acid production process, and an installation suitable for same
The invention relates to a process and apparatus for preparing nitric acid by catalytic oxidation of NH.sub.3 by means of oxygen and subsequent reaction of the NO.sub.x formed with an absorption medium in an absorption tower, which comprises a catalyst bed for N.sub.2O decomposition arranged in the process gas downstream of the catalytic NH.sub.3 oxidation and upstream of the absorption tower in the flow direction and a catalyst bed for NO.sub.x reduction and effecting a further decrease in the amount of N.sub.2O arranged in the tailgas downstream of the absorption tower in the flow direction, wherein the amount of N.sub.2O removed in the catalyst bed for N.sub.2O removal arranged in the process gas is not more than that which results in an N.sub.2O content of >100 ppmv and a molar N.sub.2O/NO.sub.x ratio of >0.25 before entry of the tailgas into the catalyst bed for NO.sub.x reduction and the catalyst bed for NO.sub.x reduction and effecting a further decrease in the amount of N.sub.2O arranged in the tailgas contains at least one iron-loaded zeolite catalyst and NH.sub.3 is added to the tailgas before entry into the catalyst bed in such an amount that an NO.sub.x concentration of <40 ppmv results at the outlet from the catalyst bed and the operating parameters are selected in such a way that an N.sub.2O concentration of <200 ppmv results.
Core-shell structured catalyst, preparation method thereof and method for treating industrial tail gas
The present disclosure relates to the technical field of industrial waste gas purification, in particular to a core-shell structured catalyst, a preparation method and use thereof. The present disclosure provides a core-shell structured catalyst including a metal oxide-molecular sieve as a core and porous silica (SiO.sub.2) as a shell, where the metal oxide-molecular sieve includes a molecular sieve and a metal oxide loaded on the molecular sieve, the metal oxide includes an oxide of a first metal and an oxide of a second metal, the first metal is Fe, Cu, Ti, Ni or Mn, and the second metal is Ce or La. The core-shell structured catalyst of the present disclosure can enable effective removal of HCN and AsH.sub.3 at the same time with a stable effect, and no secondary pollution.
SCR CATALYST HAVING EXCELLENT SULFUR TOLERANCE
Provided is an SCR catalyst for removing nitrogen oxides (NO.sub.x) from exhaust gas, comprising: 0.01-70 wt % of zeolite having an average pore size of 5 Å or more; 25-90 wt % of titanium dioxide (TiO.sub.2); and 4-10 wt % of vanadium pentoxide (V.sub.2O.sub.5). The SCR catalyst according to the present invention exhibits denitrification performance in a low-temperature area that is superior to that of a conventional SCR catalyst, has improved tolerance for a sulfur compound, and also has an excellent regeneration rate.
Diesel oxidation catalyst and exhaust system
An oxidation catalyst for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a first washcoat region comprising platinum (Pt), manganese (Mn) and a first support material; a second washcoat region comprising a platinum group metal (PGM) and a second support material; and a substrate having an inlet end and an outlet end; wherein the second washcoat region is arranged to contact the exhaust gas at the outlet end of the substrate and after contact of the exhaust gas with the first washcoat region.
Catalyst for Adsorbing Hydrocarbon and Hydrocarbon Trap Comprising the Same
A catalyst for adsorbing hydrocarbon includes a first catalyst configured to adsorb short-chain hydrocarbons and including zeolites having a pore size of about 0.30 nm to about 0.44 nm and a second catalyst configured to adsorb a long-chain hydrocarbon and including zeolites ion-exchanged with a transition metal. The catalyst can be coated on a substrate of a hydrocarbon trap.
Manganese-containing diesel oxidation catalyst
An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat layer comprising a Pt component and a Pd component, and a second washcoat layer including a refractory metal oxide support containing manganese, a zeolite, and a platinum component is described.
Diesel oxidation catalyst and exhaust system
An oxidation catalyst for treating an exhaust gas from a diesel engine comprises: a first washcoat region for oxidising carbon monoxide (CO) and hydrocarbons (HCs), wherein the first washcoat region comprises a first platinum group metal (PGM) and a first support material, and wherein the first washcoat region does not comprise manganese or an oxide thereof; a second washcoat region for oxidising nitric oxide (NO), wherein the second washcoat region comprises platinum (Pt), manganese (Mn) and a second support material comprising a refractory metal oxide, which is silica-alumina or alumina doped with silica in a total amount of 0.5 to 45% by weight of the alumina, wherein the platinum (Pt) is disposed or supported on the second support material and the manganese (Mn) is disposed or supported on the second support material; and a substrate having an inlet end and an outlet end, and wherein the first washcoat region is a first washcoat layer and the second washcoat region is a second washcoat layer, and the second washcoat layer is disposed on the first washcoat layer; and wherein when the oxidation catalyst comprises a hydrocarbon adsorbent, which is a zeolite, then the first washcoat region further comprises the hydrocarbon adsorbent.
Ammonia slip catalyst with in-situ PT fixing
The invention relates to a catalytic article comprising a substrate having an inlet and an outlet; a first coating comprising a blend of: (1) platinum on a support, and (2) a first SCR catalyst; and a second coating comprising a second SCR catalyst; wherein the support comprises at least one of a zeolite or a SiO.sub.2—Al.sub.2O.sub.3 mixed oxide. The platinum may be fixed on the support in solution.
PROCESS FOR PREPARING ZEOLITE MATERIAL HAVING AN AFX FRAMEWORK STRUCTURE AND ZEOLITE MATERIAL AS PREPARED
Disclosed herein is a process for preparing a zeolite material having an AFX framework structure including X2O3 and YO2 via interzeolite conversion, the process including (1) providing a mixture including a first zeolite material having a non-FAU framework structure including X2O3 and YO2 and an organic structure directing agent selected from the group consisting of diquaternary ammonium cation containing compounds, and (2) heating the mixture from (1) to form a second zeolite material having an AFX framework structure including X2O3 and YO2, wherein X is a trivalent element and Y is a tetravalent element, and where the organic structure directing agent is not 1,4-bis(1,4-diazabicyclo[2.2.2]octane)butyl dihydroxide when the first material zeolite has a CHA framework structure. Further disclosed herein is the zeolite material having an AFX framework structure as obtainable or obtained from the process, and a method of using the same as a catalytically active material.