The present disclosure provides catalyst compositions and catalytic articles capable of storing and/or reducing nitrogen oxide (NO.sub.x) emissions in engine exhaust, catalyst articles coated with such compositions, and processes for preparing such catalyst compositions and articles. The catalyst compositions include copper and palladium co-exchanged zeolites. Further provided is a process for preparing such co-exchanged zeolites, an exhaust gas treatment system including the catalytic articles disclosed herein, and methods for reducing NO in an exhaust gas stream using such catalytic articles and systems.

A passive NOx absorber for treating an exhaust gas from a diesel engine is described. The passive NOx absorber comprises a first washcoat region comprising a zeolite catalyst, the zeolite catalyst comprising a noble metal and a zeolite having a SAR of 2-15.

In accordance with the technology herein disclosed, an exhaust gas purification catalyst exhibiting a high exhaust gas purifying performance using a new rare earth-containing material is provided. The exhaust gas purification catalyst herein disclosed includes a base material and a catalyst layer formed on the surface of the base material. The catalyst layer of such an exhaust gas purification catalyst includes rare earth-carrying alumina 50 including a primary particle of a rare earth particle 40 including at least one rare earth element carried on the surface of an alumina carrier 30 including alumina, and the average particle diameter D.sub.50 based on TEM observation of the rare earth particle 40 in the rare earth-carrying alumina 50 is 10 nm or less. As a result of this, it is possible to provide an exhaust gas purification catalyst having high NOx adsorption performance and CO adsorption performance

Described are exhaust gas treatment systems for treatment of a gasoline engine exhaust gas stream. The exhaust gas treatment systems comprise an ammonia generating catalyst and an ammonia selective catalytic reduction (SCR) catalyst downstream of the ammonia generating catalyst. The ammonia generating catalyst comprises a NO.sub.x storage component, a refractory metal oxide support, a platinum component, and a palladium component. The ammonia generating catalyst is substantially free of ceria. The platinum and palladium components are present in a platinum to palladium ratio of greater than about 1 to 1.

An exhaust aftertreatment system includes a cross-flow selective catalytic reduction catalyst. The cross-flow selective catalytic reduction catalyst includes a housing and a substrate assembly. The substrate assembly includes a plurality of first substrate layers defining a plurality of first flow channels and a plurality of second substrate layers defining a plurality of second flow channels. The exhaust aftertreatment system includes a passive NO.sub.x adsorber. The passive NO.sub.x adsorber includes a housing. The housing includes an inlet in exhaust gas receiving communication with the plurality of first flow channels of the cross-flow selective catalytic reduction catalyst. The housing includes an outlet in exhaust gas providing communication with the plurality of second flow channels of the cross-flow selective catalytic reduction catalyst. The passive NO.sub.x adsorber includes a substrate positioned in the housing. The substrate includes a passive NO.sub.x adsorber washcoat.

The present disclosure is directed to an emission treatment system for NO.sub.x abatement in an exhaust stream of an ammonia-fueled engine, the emission treatment system including a selective catalytic reduction (SCR) catalyst disposed on a substrate in fluid communication with the exhaust stream, an oxidation catalyst disposed on a substrate positioned either upstream or downstream of the SCR catalyst and in fluid communication with the exhaust stream and the SCR catalyst, and optionally, one or more adsorption components disposed on a substrate positioned upstream and/or downstream of the SCR catalyst and in fluid communication with the exhaust stream and the SCR catalyst, the adsorption component chosen from low temperature NO.sub.x adsorbers (LT-NA), low temperature ammonia adsorbers (LT-AA), low temperature water vapor adsorbers (LT-WA), and combinations thereof. The disclosure further provides a related method of treatment of an exhaust gas.

An exhaust gas treatment system includes an exhaust gas pathway configured to receive exhaust gas from an internal combustion engine. The exhaust gas treatment system further includes a treatment element configured to reduce an emissions component of the exhaust gas, and a sample collector positioned within the exhaust gas pathway downstream of the treatment element. The sample collector includes a plurality of inlet openings spaced about a periphery of the exhaust gas pathway and configured to receive a sample of exhaust gas from the exhaust gas pathway, and an outlet in fluid communication with the plurality of inlet openings. A sensor located at the outlet of the sample collector is configured to measure a characteristic of the sample.

An oxidation catalyst for treating an exhaust gas produced by a diesel engine comprises a catalytic region and a substrate, wherein the catalytic region comprises a catalytic material comprising: bismuth (Bi) or an oxide thereof; a Group 8 metal or an oxide thereof; a platinum group metal (PGM) selected from the group consisting of (i) platinum (Pt), (ii) palladium (Pd) and (iii) platinum (Pt) and palladium (Pd); and a support material, which comprises alumina, silica, a mixed oxide of alumina and a refractory oxide, a mixed oxide of silica and a refractory oxide, a composite oxide of alumina and a refractory oxide, a composite oxide of silica and a refractory oxide, alumina doped with a refractory oxide or silica doped with a refractory oxide.

An exhaust gas purification catalyst device comprising a base material and a catalyst coating layer provided on the base material, wherein the catalyst coating layer contains zeolite particles, inorganic oxide particles other than the zeolite particles, and a catalyst precious metal, and the ratio d.sub.ZEO/d.sub.OX between the average particle diameter d.sub.ZEO of the zeolite particles and the average particle diameter d.sub.OX of the inorganic oxide particles other than the zeolite particles is 3.4 or less.

A nitrogen oxide storage material comprising: Mg.sub.1-yAl.sub.2O.sub.4-y, wherein y is a number satisfying 0≤y≤0.2, a noble metal, an oxide of a metal other than the noble metal, and a barium compound, the noble metal, the oxide, and the barium compound being loaded on Mg.sub.1-yAl.sub.2O.sub.4-y. The metal oxide comprises at least one metal oxide selected from zirconium oxide, praseodymium oxide, niobium oxide, and iron oxide.