The present invention relates to a method for the production of hydrogen. Hydrogen is used in many different chemical and industrial processes. Hydrogen is also an important fuel for future transportation and other uses as it does not generate any carbon dioxide emissions when used. The invention provides for a process for producing hydrogen comprising the steps of partially oxidizing a hydrocarbon to obtain a synthesis gas, providing the synthesis gas to a reactor in which carbon monoxide is converted to carbon dioxide, removing the carbon dioxide to obtain hydrogen. The carbon dioxide is used in a chemical process and/or stored in a geological reservoir.

The present invention relates to a system for producing synthetic fuels, in particular jet fuel (kerosene), gasoline and/or diesel, comprising: a) an apparatus for separately extracting carbon dioxide and water from ambient air, b) a synthesis gas production apparatus for producing a raw synthesis gas comprising carbon monoxide, hydrogen, carbon dioxide and water, the synthesis gas production apparatus having a supply line for carbon dioxide leading from the apparatus for separately extracting carbon dioxide and water from ambient air, a supply line for air and a supply line for water, c) a separating apparatus for separating carbon dioxide and water from the raw synthesis gas produced in the synthesis gas production apparatus, d) a Fischer-Tropsch apparatus for producing hydrocarbons by means of a Fischer-Tropsch process from the synthesis gas from which carbon dioxide and water were separated in the separating apparatus, e) a refining apparatus for refining the hydrocarbons produced in the Fischer-Tropsch apparatus into synthetic fuels, f) a desalination apparatus for desalinating water, the desalination apparatus having a water supply line from the apparatus for separately extracting carbon dioxide and water from ambient air and a water discharge line to the Fischer-Tropsch apparatus, and g) a water purification apparatus, which comprises a water supply line leading from the Fischer-Tropsch apparatus for purifying water produced therein, the system further comprising a pre-reformer for converting hydrocarbons other than methane into methane, carbon oxides, water and hydrogen and i) a water vapor supply line leading from the water purification apparatus to the pre-reformer, ii) a process gas supply line leading from the refining apparatus to the pre-reformer and/or a return gas line leading from the Fischer-Tropsch apparatus to the pre-reformer and iii) a circulation line leading from the pre-reformer to the supply line for water connected to the synthesis gas production apparatus.

A DAC method as well as a unit containing an adsorber structure having an array of adsorber elements with a support layer and on both sides thereof a sorbent layer (1, 2), wherein the adsorber elements are parallel and spaced apart forming parallel fluid passages for flow-through of ambient atmospheric air and steam. The method involves the following sequential and repeating steps: (a) adsorption by flow-through; (b) isolating the sorbent; (c) injecting a stream of saturated steam through the parallel fluid passages and inducing an increase of the temperature; (d) extracting desorbed carbon dioxide from the unit and separating it from steam; (e) bringing the sorbent material to ambient temperature conditions wherein in step (a) the speed of the air is in the range of 2-8 m/s, and wherein at least in step (d) the speed of the steam is at least 0.2 m/s.

The present invention provides: a gas separation method which is capable of desirably separating a slight amount of a component from a mixed gas under mild conditions such that the pressure difference between both sides of a gas separation membrane is 1 atmosphere or less; and a gas separation membrane which is suitable for use in this gas separation method. According to the present invention, in a gas separation method wherein a specific gas (A) in a mixed gas, which contains the specific gas (A) at a concentration of 1,000 ppm by mass or less, is selectively permeated with use of a gas separation membrane, an extremely thin gas separation membrane that has a film thickness of 1 μm or less is used, so that the gas (A) is desirably separated under mild conditions such that the pressure difference between both sides of the gas separation membrane is 1 atmosphere or less.

Described are gas-processing systems that include a pre-heater, that are useful for processing a flow of gas flowing the gas to contact media (e.g., purification media, catalyst, adsorbent), and related methods.

Described are porous, sintered metal bodies that include multiple layers made from different metal particles and that may be useful as porous filter membranes, as well as methods of making and using the porous, sintered metal bodies.

A system for separating carbon dioxide from a carrier gas includes a CO.sub.2 enrichment subsystem that receives a carrier gas stream and produces an enriched carbon dioxide fluid stream. The system also includes a CO.sub.2 polishing subsystem in fluid communication with the CO.sub.2 enrichment subsystem that produces a carbon dioxide rich fluid stream. In a corresponding method, a carrier gas is received in a CO.sub.2 enrichment subsystem and an enriched carbon dioxide fluid stream is produced. The enriched carbon dioxide fluid stream is directed to a CO.sub.2 polishing subsystem wherein a stream further enriched in carbon dioxide is produced.

Methods and systems for treating volatile organic compounds (VOCs) generated in a hydrocarbon treating process are disclosed. An effluent stream containing the VOCs, as well as carbon dioxide (CO.sub.2) is combined with hot exhaust gas from a turbine and provided to a waste heat recovery unit (WHRU). The WHRU is adapted to contain a catalyst bed containing oxidation catalyst capable of effecting the oxidation of the VOCs. The temperature of the catalyzing reaction can be tailored based on the position of the catalyst bed within the temperature gradient of the WHRU. The methods and systems described herein solve the problem of effecting the removal of VOCs from the effluent. Heating the CO.sub.2-containing effluent in the WHRU also lend buoyancy to the effluent, thereby facilitating its dispersal upon release.

An adsorbate-selective metal organic framework includes a transition metal; and a plurality of organic molecules coordinated to the transition metal so as to preserve open coordination sites for selectively adsorbing molecules that have low-lying π* orbitals. The transition metal has a lowest energy spin state in the presence of the selectively adsorbed molecules that are strongly bonding to the transition metal through π-donating interactions which is different than the lowest energy spin state in the absence of these adsorbed molecules. The transition metal has also a lowest energy spin state in the presence of non-selected molecules that are weakly bonding to the transition metal through σ- and/or π-accepting and/or donating interactions.

Fuel tank inerting systems are provided. The systems include a fuel tank, an air source arranged to supply air into a reactive flow path, a catalytic reactor having a plurality of sub-reactors along the flow path, and a heat exchanger. The sub-reactors are arranged relative to the heat exchanger such that the flow path passes through at least a portion of the heat exchanger between two sub-reactors along the flow path. At least one fuel injector is arranged relative to at least one sub-reactor. The fuel injector is configured to inject fuel into the flow path at at least one of upstream of and in the respective at least one sub-reactor to generate a fuel-air mixture. A fuel tank ullage supply line fluidly connects the flow path to the fuel tank to supply an inert gas to a ullage of the fuel tank.