Patent classifications
B01D2257/2068
METHODS FOR PRODUCING ANHYDROUS HYDROGEN IODIDE (HI)
A method of removing water from a mixture of hydrogen iodide (HI) and water includes providing a mixture comprising hydrogen iodide and water and contacting the mixture with an adsorbent to selectively adsorb water from the mixture, contacting the mixture with a weak acid to absorb water from the mixture and/or separating the water from hydrogen iodide (HI) by azeotropic distillation to produce anhydrous hydrogen iodide (HI).
SELECTIVE ADSORPTION OF HALOCARBON IMPURITIES CONTAINING CL, BR AND I IN FLUOROCARBONS OR HYDROFLUOROCARBONS USING ADSORBENT SUPPORTED METAL OXIDE
Methods for purification of a fluorocarbon or hydrofluorocarbon containing at least one undesired halocarbon impurities comprise flowing the fluorocarbon or hydrofluorocarbon through at least one adsorbent beds to selectively adsorb the at least one undesired halocarbon impurities through physical adsorption and/or chemical adsorption, wherein the at least one adsorbent beds contain a metal oxide supported on an adsorbent in an inert atmosphere.
ORGANIC IODINE TRAPPING APPARATUS
There is provided an organic iodine trapping apparatus that can efficiently trap an organic iodine without using complicated or large equipment. An organic iodine trapping apparatus 30 is an apparatus that traps an organic iodine, including: a trapping vessel 1 through which gas containing an organic iodine is passed; an organic iodine remover 2 (Example: trihexyl (tetradecyl) phosphonium chloride, or the like) that is disposed in or injected into the trapping vessel 1 and decomposes the organic iodine; and a trapping material 3 that is disposed in or injected into the trapping vessel 1 and traps iodine ions generated by decomposition of the organic iodine, in which the trapping material 3 is a metal (Example: silver or the like) or a metal compound (Example: silver chloride, silver oxide, or the like).
Enhanced injection of mercury oxidants
The disclosure relates generally to reducing mercury emissions from a coal power plant. Specifically, a method for treating a gas stream containing mercury is provided that includes injecting a mercury oxidant or absorbent and a carrying agent into a gas stream that was produced by heating or burning a carbonaceous fuel comprising mercury. The carrying agent vaporizes after being injected into the gas stream. The mercury oxidant or absorbent and a carrying agent may be injected before passing the gas stream into a gas scrubber.
PROCESS FOR PREPARING ETHYLENE CARBONATE AND ETHYLENE GLYCOL
A process for producing ethylene glycol and/or ethylene carbonate, said process comprising contacting at least a portion of a recycle gas stream comprising an alkyl iodide impurity with a guard bed system positioned upstream of an ethylene oxide reactor to produce a treated recycle gas stream, wherein the guard bed system comprises silver on alumina; contacting an epoxidation feed stream comprising an ethylene feed stream, oxygen, chloride moderator, and at least a portion of the treated recycle gas stream with an epoxidation catalyst in the ethylene oxide reactor to produce an epoxidation reaction product comprising ethylene oxide; and contacting at least a portion of the epoxidation reaction product comprising ethylene oxide with a liquid absorbent in the presence of an iodide-containing catalyst in an absorber to produce a product stream comprising ethylene carbonate and/or ethylene glycol and the recycle gas stream comprising the alkyl iodide impurity.
METHOD FOR PRODUCING ACETIC ACID
Provided is a method for producing acetic acid, which includes an absorption step that suppresses corrosion inside a distillation column when a solution after that has absorbed a target component is subjected to distillation. The method for producing acetic acid according to an embodiment of the present invention includes an absorption step of supplying, to an absorption column, at least a portion of offgas generated in an acetic acid production process, bringing the offgas into contact with an absorbent containing one or more liquids selected from the group consisting of a hydrocarbon, an ester of a carboxylic acid having 3 or more carbon atoms, an ester of a carboxylic acid and an alcohol having 2 or more carbon atoms, and an ether, to allow the absorbent to absorb an iodine compound in the offgas, and separating into a gas component having a lower iodine compound concentration than the offgas and a solution containing the absorbent and the iodine compound.
COLUMN FOR CARRYING OUT MASS EXCHANGE PROCESSES, IN PARTICULAR DESORPTION AND ABSORPTION PROCESSES, MASS EXCHANGE APPARATUS WITH THE SAME AND METHOD FOR EXTRACTING IODINE FROM DRILLING AND/OR FORMATION WATER OF OIL OR GAS FIELDS BY AIR
Method for extracting iodine from water, using a column including a vertical cylindrical container including a first cylindrical container section having a first height and a first diameter, a second cylindrical container section having a second height and a second diameter, a third cylindrical container section having a third height and a third diameter and a fourth cylindrical container section having a fourth height and a fourth diameter, from bottom to top in longitudinal direction of the container, a gas inlet in the wall of the first container section and a liquid outlet in the first container section, a polyethylene packing in each of the second and third container sections, a liquid inlet in the wall of the third container section, a liquid distributor in the third container section and in fluid connection with the liquid inlet, and a gas mixture outlet in the fourth container section.
Processes for producing high-purity trifluoroiodomethane
The present disclosure provides a method for purifying trifluoroiodomethane. The method includes providing a process stream comprising trifluoroiodomethane, organic impurities, and acid impurities; reacting the process stream with a basic aqueous solution, the basic aqueous solution comprising water and at least one base selected from the group of an alkali metal carbonate and an alkali metal hydroxide; and separating at least some of the organic impurities from the process stream.
PROCESS FOR PREPARING ETHYLENE CARBONATE AND ETHYLENE GLYCOL USING AN ALKYL IODIDE GUARD BED SYSTEM
The invention relates to a process for producing ethylene glycol and/or ethylene carbonate, said process comprising contacting at least a portion of a recycle gas stream comprising an alkyl iodide impurity with a guard bed system positioned upstream of an ethylene oxide reactor to produce a treated recycle gas stream, wherein the guard bed system comprises silver on alumina; contacting a feed gas stream comprising ethylene, oxygen and at least a portion of the treated recycle gas stream with an epoxidation catalyst in the ethylene oxide reactor to produce an epoxidation reaction product comprising ethylene oxide; and contacting at least a portion of the epoxidation reaction product comprising ethylene oxide with an aqueous absorbent in the presence of an iodide-containing catalyst in an absorber to produce an aqueous product stream comprising ethylene carbonate and/or ethylene glycol and the recycle gas stream comprising the alkyl iodide impurity.
Catalytic recombiner and filter apparatus
A catalytic recombiner and filter apparatus is especially suited for placement in a containment of a nuclear reactor. The apparatus has a natural convection flow duct with a number of catalytic elements for recombining hydrogen and oxygen contained in a gas flow through the flow duct. The catalytic recombiner and filter apparatus provides for reliable hydrogen reduction and iodine filtering for a gas flow even for a comparatively long period of operation. The catalytic recombiner and filter apparatus includes a number of adsorber elements with iodine adsorbing surfaces and with macroscopic flow channels in between. The iodine adsorbing surfaces are flown over by the gas flow, and the adsorber elements are arranged, when in use, downstream of the catalytic elements in a direction of the gas flow.