A honeycomb structure includes plugged honeycomb segments, bonding layers and a circumferential wall. The bonding layers includes bottomed-hollow unbonded portions, which extend toward an internal side in an axial direction from an end face of the honeycomb structure, in portions of circumferential bonding layers bonding the honeycomb segments on an outermost circumference. The unbonded portions exist on respective extended lines extending from an intersection of the bonding layers which is closest to a centroid of the end face. An opening length of the unbonded portion is 1 to 10 mm, a ratio of an opening depth of the unbonded portion to a length of the honeycomb segment is 10 to 45%, and a ratio of a distance from the circumferential wall to a point at which an open end of the unbonded portion ends to a length of the circumferential bonding layer is 5 to 100%.

A thermal shock resistant and asymmetric honeycomb ceramic wall-flow filter, comprising: an inlet honeycomb ceramic surface and an outlet honeycomb ceramic surface. Inlet channels (1) and outlet channels (2) are provided on both the inlet honeycomb ceramic surface and the outlet honeycomb ceramic surface. The inlet channels (1) are in communication with the outlet channels (2). Outlet ends of the inlet channels (1) and inlet ends of the outlet channels (2) are sealed. An inner diameter of the inlet channel (1) is greater than that of the outlet channel (2). A cross-section of the inlet channel (1) is a square, and is provided with a fillet, or two adjacent edges are connected by two connecting lines, or two adjacent edges are connected by two connecting lines or a circular arc located between the two connecting lines. A cross-section of the outlet channel (2) is a square, and is also provided with a fillet or a chamfer. The filter has good mechanical properties, low back pressure, and excellent thermal shock resistance.

The plugged honeycomb structure includes a plurality of honeycomb segments, a bonding layer, and plugging portions which plug open ends of cells of each honeycomb segment, and in the honeycomb segment, at least two types of cells having different sectional shapes are formed to constitute predetermined repeated arrangement patterns, and in rim circumferential wall cells including rims of the cells surrounded with partition walls and segment circumferential walls, an inflow open area of each corner rim circumferential wall cell disposed in each corner portion of the honeycomb segment is 1.1 times or more as large as an average inflow open area of non-corner rim circumferential wall cells arranged in portions other than the corner portions, or an outflow open area of the corner rim circumferential wall cell is 1.1 times or more as large as an average outflow open area of the non-corner rim circumferential wall cells.

A honeycomb structure including a plurality of porous honeycomb block bodies bound via joining material layers A. Each of the porous honeycomb block bodies includes a plurality of porous honeycomb segments bound via joining material layers B, each of the porous honeycomb segment includes: partition walls that defines a plurality of cells to form flow paths for a fluid, each of cells extending from an inflow end face that is an end face on a fluid inflow side to an outflow end face that is an end face on a fluid outflow side; and an outer peripheral wall located at the outermost periphery. At least a part of the joining material layers A has higher toughness than that of the joining material layers B.

The plugged honeycomb structure includes a plurality of honeycomb segments, a bonding layer, and plugging portions which plug open ends of cells of each honeycomb segment, and in the honeycomb segment, at least two types of cells having different sectional shapes are formed to constitute predetermined repeated arrangement patterns, and a ratio of a value R2s obtained by dividing an average sectional area S2.sub.in of inflow cells by an average sectional area S2.sub.out of outflow cells in a partial rim circumferential wall cell region is in a range of 1.7 times or more and 2.0 times or less to a value R1s obtained by dividing an average sectional area S1.sub.in of the inflow cells by an average sectional area S1.sub.out of the outflow cells in a whole rim partition wall cell region.

A plugged honeycomb structure includes: a plurality of honeycomb segments, a bonding layer, and a plugging portions to plug open ends of cells of each of the honeycomb segments. The honeycomb segment is configured so that the cells having at least two kinds of different shapes are disposed in a cross section orthogonal to an extension direction of the cells, the honeycomb segment has a center region and an circumferential region located in the circumference of the center region, the center region has a cell arrangement pattern such that inflow cells surround one outflow cell, in the inflow end face of the honeycomb segment, the circumferential region has an open frontal area that is smaller than an open frontal area of the center region, the segment circumferential wall of the honeycomb segment and the bonding layer have a special thickness.

A honeycomb structure including prismatic columnar honeycomb segments and a bonding layer, wherein the bonding layer has rows in each of which bonding layer portions each disposed between two honeycomb segments arranged to face each other are arranged to extend from one point of a peripheral edge of a bonded body of the honeycomb segments to the other point thereof, in a cross section, the bonding layer of each of the-rows is disposed so that among the bonding layer portions arranged in one direction, an outermost circumference bonding layer portion and at least one of the other bonding layer portions are not superimposed on each other on an extension line of the one direction, and a ratio of shift of side surfaces of adjacent honeycomb segments to a length of one side of a side surface of honeycomb segments having the same cross-sectional shape is 10% or less.

A honeycomb structure includes honeycomb segments, bonding layers and a circumferential wall. The bonding layers include bottomed-hollow voids which extend toward an internal side in an axial direction from an end face of the honeycomb structure and which are formed at at least one of intersections, and a ratio of a depth of each void in the axial direction to a length of each honeycomb segment in the axial direction is 5% or more.

A honeycomb structure includes plugged honeycomb segments, bonding layers and a circumferential wall. The bonding layers includes bottomed-hollow unbonded portions, which extend toward an internal side in an axial direction from an end face of the honeycomb structure, in portions of circumferential bonding layers bonding the honeycomb segments on an outermost circumference. The unbonded portions exist on respective extended lines extending from an intersection of the bonding layers which is closest to a centroid of the end face. An opening length of the unbonded portion is 1 to 10 mm, a ratio of an opening depth of the unbonded portion to a length of the honeycomb segment is 10 to 45%, and a ratio of a distance from the circumferential wall to a point at which an open end of the unbonded portion ends to a length of the circumferential bonding layer is 5 to 100%.

A honeycomb segment joined body includes a plurality of honeycomb segments; and joining layers for bonding side surfaces of the plurality of honeycomb segments. Each of the joining layers is a cured product of a pasty joining material, and has a standard deviation of joined widths of 0.30 or less. The honeycomb segment joined body is produced by applying pressurization with vibration when joining side surfaces of a plurality of honeycomb segments using a pasty joining material.