Patent classifications
B01D53/228
APPARATUS FOR SEPARATING HYDROGEN FROM A GAS MIXTURE AND PROCESS FOR THE PRODUCTION THEREOF
The invention relates to an apparatus for separating hydrogen from a gas mixture, comprising a vessel which defines an inlet collection space for the gas mixture and an offtake collection space for hydrogen, where the inlet collection space is separated from the offtake collection space by means of a hydrogen-permeable membrane. The invention is also directed to a process for producing an apparatus for separating hydrogen from a gas mixture, which comprises a hydrogen-permeable membrane, a gas mixture inlet, a hydrogen offtake and a residual gas outlet.
METHOD OF PREPARING HETEROGENEOUS ZEOLITE MEMBRANES
Disclosed are a heterogeneous zeolite membrane and a method of preparing the same, and more particularly a heterogeneous zeolite membrane that has CHA and DDR zeolite structures by growing seed particles into a crystal structure different from that of the zeolite membrane and can thus separate CO.sub.2/N.sub.2 and CO.sub.2/CH.sub.4 even under wet conditions, a method of preparing the same, and a method of capturing and removing carbon dioxide using the membrane.
CHA ZEOLITE MEMBRANE AND METHOD OF PREPARING THE SAME
Disclosed are a CHA zeolite membrane and a method of preparing the same, and more particularly, a CHA zeolite membrane having high capacity to separate CO.sub.2/N.sub.2 and CO.sub.2/CH.sub.4 even under wet conditions using a membrane produced using a synthetic precursor having a controlled ratio of Si and Al, a method of preparing the same, and a method of capturing and removing carbon dioxide using the membrane.
FILTER SYSTEM FOR WATER AND GAS REMOVAL AND SYSTEMS AND METHODS OF USE THEREOF
Disclosed are embodiments of a cabin filter system including a sorbent material for removing gas and/or water from a cabin. The filter system also includes at least one heater configured to transmit thermal energy (e.g., microwave energy) to the sorbent material. Also disclosed are methods of using such filter systems.
Membrane device for water and energy exchange
A device for exchange of water molecule and temperature between two fluids. The device comprises thin molecular sieve membrane sheets that allow water molecules to permeate through while blocking cross-over of the exchanging fluids. The device provides two sets of flow channels having a hydraulic diameter ranged from 0.5 to 2.0 mm for respective process and sweep fluid flows. The two sets of the channels are separated by a membrane sheet having a thickness less than 200 μm. The thin molecule sieve membrane may be prepared by forming an ultra-thin zeolite membrane layer on a porous metal-based support sheet which provides very high water permeance so that the exchange can be conducted in a compact membrane module at high throughput. The device can be used to remove water from a process stream of higher water content by use of a sweep fluid of lower water content or higher water affinity. For example, the device can be used to condition outdoor fresh air close to the temperature and humidity of indoor air by conducting humidity and heat exchange between the fresh air flow drawn from outdoors and waste air discharged indoors.
A GAS SEPARATION ARTICLE, A METHOD FOR PRODUCING SAID GAS SEPARATION ARTICLE AND USE THEREOF
The disclosure provides a method for producing a gas separation article, said gas separation article comprising: a gas separation membrane, optionally a support, and optionally an additional support said method comprising the steps of: a) providing a matrix comprising: a matrix material having a viscosity from 1 cP to 40000 cP, particles, said particles being free from functionalized carbon nanotubes, and optionally a solvent, b) contacting the matrix of step a) with a support comprising at least one side, said at least one side facing said matrix, thereby forming (i) a matrix side in contact with the support and (ii) a matrix side opposite the side in contact with the support, c) optionally contacting the matrix side opposite the side contacting the support with an additional support, d) subjecting said matrix being in contact with said support to one or more electric fields whereby the particles form particle groups in a plurality of substantially parallel planes, said particle groups in each of said plurality of substantially parallel planes being aligned substantially parallel with the one or more electric fields, e) fixating the matrix material so as to fixate the particle groups thereby forming a gas separation membrane, and f) optionally removing the support and/or the additional support.
The disclosure also provides a gas separation membrane obtainable by the aforementioned method as well as use thereof for separation of gases in a gas mixture.
A METHOD FOR PRODUCING A GAS SEPARATION ARTICLE AND USE THEREOF
The present disclosure provides a method for producing a gas separation article, said gas separation article comprising: a gas separation membrane, optionally a support, and optionally an additional support, said method comprising the steps of: a) providing a matrix, said matrix having a viscosity from 1 centipoise to 40000 centipoise, said matrix comprising or consisting of one or more monomers, oligomers and/or polymers, and optionally a solvent, b) contacting the matrix of step a) with a support comprising at least one side, said at least one side facing said matrix, thereby forming (i) a matrix side contacting the support and (ii) a matrix side opposite the side contacting the support, c) optionally contacting the matrix side opposite the side contacting the support with an additional support, d) subjecting said matrix contacted with said support to one or more electric fields that is/are substantially parallel to a plane in which the support extends, or substantially perpendicular to a plane in which the support extends e) fixating the one or more monomers, oligomers and/or polymers of the matrix subjected to one or more electric fields in step d) thereby forming a solid gas separation membrane, and f) optionally removing the support and/or the additional support.
The present disclosure also gas separation article obtainable by the aforementioned method as well as use of said gas separation article for separation of gases in a gas mixture.
AMORPHOUS FLUORINATED COPOLYMERS AND METHODS OF MAKING AND USING THE SAME
Described herein are amorphous fluorinated copolymers produced by the polymerization of one or more fluorinated ring monomers and one or more fluorinated comonomers containing multiple ether oxygens. The copolymers are suitable in many high-technology applications, such as optical fibers, anti-reflection coatings, protective coatings, and gas separation membranes. In one aspect, the copolymers are useful is in the field of membrane-based gas separation processes. In one aspect, amorphous copolymer is produced by polymerizing (a) one or more fluorinated ring monomers in the amount of 1 mol % to 99.5 mol %, wherein the fluorinated ring monomer is at least a five membered ring and (b) a comonomer in the amount of from 0.5 mol % to 99 mol %, wherein the comonomer comprises a fluorinated compound with two or more ether oxygens.
GAS SEPARATION METHOD AND ZEOLITE MEMBRANE
A gas separation method includes supplying a mixed gas to a zeolite membrane complex and permeating a high permeability gas through the zeolite membrane complex to separate the high permeability gas from other gases. The mixed gas includes a high permeability gas and a trace gas that is lower in concentration than the high permeability gas. The molar concentration of a first gas included in the trace gas in the mixed gas is higher than the molar concentration of a second gas included in the trace gas in the mixed gas. The adsorption equilibrium constant of the first gas on the zeolite membrane is less than 60 times that of the high permeability gas. The adsorption equilibrium constant of the second gas on the zeolite membrane is 400 times or more that of the high permeability gas.
OLEOPHOBIC FLUOROPOLYMERS AND FILTER MATERIALS PREPARED THEREFROM
The disclosure provides an improved process for preparing oleophobic fluoropolymers. The resulting fluropolymers were found to be effective in imparting hydrophobic and oleophobic properties to porous polymeric membranes such as PTFE. The treated PTFE membrane can reach an oleophobic level of 6 or above, (according to the AATCC-118-1997 oil repellency test method) with a low air flux loss.