Natural gas liquefaction process in combination with a synthesis gas production process, where the steam derived from the synthesis gas production process is used as a heating source for the implementation of the pre-treatment step for eliminating the impurities liable to freeze during the natural gas liquefaction process.

A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide with a spinel formula, and crystals of ZnO, CuO, and at least one Group VIB metal oxide, and preferably, at least one acidic oxide of B, P. or Si, as well. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.

A gas purification device includes: a converter packed with a catalyst for hydrolyzing both carbonyl sulfide and hydrogen cyanide; an upstream heat exchanger for heat exchange between a gas to be introduced into the converter and a cooling fluid for cooling the gas; a reaction-temperature estimation member for estimating a reaction temperature inside the converter; and a flow-rate adjustment member for adjusting a flow rate of the cooling fluid flowing into the upstream heat exchanger based on an estimated value of the reaction-temperature estimation member to control the reaction temperature.

A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide with a spinel formula, and crystals of ZnO, CuO, and at least one Group VIB metal oxide, and preferably, at least one acidic oxide of B, P, or Si, as well. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.

Disclosed are processes for purifying feed streams containing hydrogen sulfide and sulfur-containing impurities by removing sulfur-containing impurities, such as elemental sulfur and polysulfanes, using solid catalytic sorbents. Also disclosed are processes for producing hydrogen sulfide.

A method for treatment of a gas having 10 to 0.5% by volume of at least one of COS and CS.sub.2, and 30 ppm to 5% by volume of unsaturated hydrocarbons: a) hydrogenation of organic compounds unsaturated with respect to paraffins by contacting the gas with a hydrogenation catalyst in the presence of hydrogen at 100 to 400 C., to provide an effluent that is low in unsaturated hydrocarbon compounds, the hydrogenation catalyst having at least one metal that is palladium, platinum, nickel, or cobalt deposited on a porous substrate. b) catalytic hydrolysis-hydrogenation in the presence of water of COS and/or CS.sub.2 present in the effluent of a) to provide an H.sub.2S-rich effluent by bringing the effluent from a) into contact with a hydrolysis-hydrogenation catalyst.

A process for simultaneous removal of hydrogen sulfide (H.sub.2S ) and heavy metals from mixture includes charging a contaminated aqueous composition containing heavy metal ions to a reactor. The process also includes passing a H.sub.2S -containing gas composition via a plurality of gas spargers through the contaminated aqueous composition present in the reactor to form a H.sub.2S-containing contaminated aqueous composition and a purified gas composition. The process further includes reacting the H.sub.2S from the H.sub.2S -containing contaminated aqueous composition with the heavy metal ions in the H.sub.2S -containing contaminated aqueous composition to form a metal sulfide precipitate in a metal-sulfide-containing contaminated aqueous composition. In addition, the process includes at least partially introducing the metal-sulfide-containing contaminated aqueous composition to a solid-liquid separator and removing the metal sulfide precipitate from the metal-sulfide-containing contaminated aqueous composition to form a purified aqueous composition.

Natural gas liquefaction process in combination with a synthesis gas production process, where the steam derived from the synthesis gas production process is used as a heating source for the implementation of the pre-treatment step for eliminating the impurities liable to freeze during the natural gas liquefaction process.

A catalytically active filter for use in hot gas filtration to simultaneously remove solid particles and one or more undesirable compounds from a hot gas stream is partly or fully impregnated with a suitable catalyst. The compounds are selected from HCN, arsenic, organic sulfur compounds and carbonyls. The filter is prepared by making an impregnation liquid, which comprises a catalytically effective amount of at least one active metal and an oxide support, impregnating the filter substrate with the impregnation liquid by dipping it in the liquid or spraying it with the liquid to control the amount of liquid and drying and optionally calcining the impregnated filter.

Presented is a catalyst composition having exceptional properties for converting sulfur, sulfur compounds, and carbon monoxide contained in gas streams by catalyzed hydrolysis, hydrogenation and water-gas shift reactions. The catalyst comprises underbedded molybdenum and cobalt with an overlayer of molybdenum and cobalt. These metals are present in the catalyst within certain concentration ranges and relative weight ratios. The underbedded metals are present in the catalyst within a specified range relative to the overlayer and total metals. The underbedded metals are formed by co-mulling an inorganic oxide with the catalytically active metals of molybdenum and cobalt. The co-mulled mixture is calcined and then impregnated with overlaid molybdenum and cobalt.