An electrochemical sensor with an ion-selective membrane that comprises a crosslinked alkyl methacrylate homopolymer or copolymer of two or more alkyl methacrylates 1. with a covalently attached electrically neutral or electrically charged ionophore that is selective for a target cation or anion, or 2. with a covalently attached cationic or anionic ionic site, or 3. with a covalently attached cationic or anionic ionic site and covalently attached electrically neutral or electrically charged ionophore.

An electrochemical sensor with an ion-selective membrane that comprises a crosslinked alkyl methacrylate homopolymer or copolymer of two or more alkyl methacrylates 1. with a covalently attached electrically neutral or electrically charged ionophore that is selective for a target cation or anion, or 2. with a covalently attached cationic or anionic ionic site, or 3. with a covalently attached cationic or anionic ionic site and covalently attached electrically neutral or electrically charged ionophore.

A porous membrane obtainable by a process comprising curing a composition comprising: (i) cross-linking agent(s) comprising at least one ligand group; (ii) inert solvent(s); (iii) polymerization initiator(s); and (vi) optionally monomer(s) other than component (i) which are reactive with component (i); wherein the composition satisfies the following equation: Z=wt(i)/(wt(i)+wt(iii)+wt(iv)) wherein: Z has a value of at least 0.6; wt(i) is the number of grammes of component (i) present in the composition; wt(iii) is the number of grammes of component (iii) present in the composition; and wt(iv) is the number of grammes of component (iv) present in the composition.

A nonwoven web obtained by electrospinning, suitable for the filtration of nano- and/or submicron aerosols, including a multiplicity of fibers of composition C1, the composition C1 including at least 50% by weight of at least one polymer P1 based on the repeat unit resulting from vinylidene fluoride (VDF), the fibers of composition C1 having a degree of crystallinity in polar phase(s), preferentially in solely beta phase, of at least 65% by weight, with respect to their total weight. Also, a process for the manufacture of the web, to a membrane including the web and also to a process for the washing/sterilization of the web or of the membrane.

The gas separation membrane element contains a gas separation membrane, and a sealing portion for preventing mixture of a source gas and a specific gas permeated through a gas separation membrane. The gas separation membrane has a first porous layer including a porous membrane, and a hydrophilic resin composition layer disposed on the first porous layer. The sealing portion is a region in which a cured material of a sealant penetrates in at least the first porous layer in the gas separation membrane, and a thermal expansion coefficient A of the sealing portion and a thermal expansion coefficient B of a material forming the first porous layer satisfy a relation (I):
0.35≤A/B≤1.0  (I).

The gas separation membrane element contains a gas separation membrane, and a sealing portion for preventing mixture of a source gas and a specific gas permeated through a gas separation membrane. The gas separation membrane has a first porous layer including a porous membrane, and a hydrophilic resin composition layer disposed on the first porous layer. The sealing portion is a region in which a cured material of a sealant penetrates in at least the first porous layer in the gas separation membrane, and a thermal expansion coefficient A of the sealing portion and a thermal expansion coefficient B of a material forming the first porous layer satisfy a relation (I):
0.35≤A/B≤1.0  (I).

Disclosed are methods for coupling a ligand to a composite material. Covalent bonds are formed between functionalized composite materials and ligands as a ligand solution flows through or across the composite materials. The composite materials are useful as chromatographic separation media.

Disclosed are methods for coupling a ligand to a composite material. Covalent bonds are formed between functionalized composite materials and ligands as a ligand solution flows through or across the composite materials. The composite materials are useful as chromatographic separation media.

The invention relates to dense synthetic membranes made from polymerised phosphonium-based ionic liquids which were found to be particularly suitable for use in gas separation. The membranes are obtainable by copolymerization via UV-curing of a composition comprising a phosphonium-based ionic liquid monomer, a co-monomer, a cross-linker, a surfactant and a photo-initiator, the remainder of the polymerization mixture consisting of water. The invention also relates to a process of manufacturing said membranes, resulting in solid, dense and mechanically stable membranes, and to the use of the membranes so produced in the separation of gas mixtures, particularly gas mixtures containing carbon dioxide.

The invention relates to dense synthetic membranes made from polymerised phosphonium-based ionic liquids which were found to be particularly suitable for use in gas separation. The membranes are obtainable by copolymerization via UV-curing of a composition comprising a phosphonium-based ionic liquid monomer, a co-monomer, a cross-linker, a surfactant and a photo-initiator, the remainder of the polymerization mixture consisting of water. The invention also relates to a process of manufacturing said membranes, resulting in solid, dense and mechanically stable membranes, and to the use of the membranes so produced in the separation of gas mixtures, particularly gas mixtures containing carbon dioxide.