B01J20/18

ZEOLITE ADSORBENTS HAVING A HIGH EXTERNAL SURFACE AREA AND USES THEREOF

The present invention concerns the use, for gas separation, of at least one zeolite adsorbent material comprising at least one FAU zeolite, said adsorbent having an external surface area greater than 20 m.sup.2.Math.g.sup.−1, a non-zeolite phase (PNZ) content such that 0<PNZ≦30%, and an Si/Al atomic ratio of between 1 and 2.5. The invention also concerns a zeolite adsorbent material having an Si/Al ratio such that 1≦Si/Al<2.5, a mesoporous volume of between 0.08 cm.sup.3.Math.g.sup.−1 and 0.25 cm.sup.3.Math.g.sup.−1, a (Vmicro−Vmeso)/Vmicro ratio of between −0.5 and 1.0, non-inclusive, and a non-zeolite phase (PNZ) content such that 0<PNZ≦30%.

ZEOLITE ADSORBENTS HAVING A HIGH EXTERNAL SURFACE AREA AND USES THEREOF

The present invention concerns the use, for gas separation, of at least one zeolite adsorbent material comprising at least one FAU zeolite, said adsorbent having an external surface area greater than 20 m.sup.2.Math.g.sup.−1, a non-zeolite phase (PNZ) content such that 0<PNZ≦30%, and an Si/Al atomic ratio of between 1 and 2.5. The invention also concerns a zeolite adsorbent material having an Si/Al ratio such that 1≦Si/Al<2.5, a mesoporous volume of between 0.08 cm.sup.3.Math.g.sup.−1 and 0.25 cm.sup.3.Math.g.sup.−1, a (Vmicro−Vmeso)/Vmicro ratio of between −0.5 and 1.0, non-inclusive, and a non-zeolite phase (PNZ) content such that 0<PNZ≦30%.

ADSORBENT AND METHOD FOR PRODUCING SAME

Provided is an adsorbent for removal of iodide ions and iodate ions, which exhibits excellent adsorption performance of iodide ions and iodate ions. An adsorbent according to the present invention comprises cerium(IV) hydroxide and a poorly soluble silver compound. It is preferable that the content of cerium(IV) hydroxide is 50% by mass or more and 99% by mass or less, and the content of the poorly soluble silver compound is 1% by mass or more and 50% by mass or less. It is also preferable that the poorly soluble silver compound is at least one selected from silver zeolite, silver phosphate, silver chloride, and silver carbonate.

ADSORBENT AND METHOD FOR PRODUCING SAME

Provided is an adsorbent for removal of iodide ions and iodate ions, which exhibits excellent adsorption performance of iodide ions and iodate ions. An adsorbent according to the present invention comprises cerium(IV) hydroxide and a poorly soluble silver compound. It is preferable that the content of cerium(IV) hydroxide is 50% by mass or more and 99% by mass or less, and the content of the poorly soluble silver compound is 1% by mass or more and 50% by mass or less. It is also preferable that the poorly soluble silver compound is at least one selected from silver zeolite, silver phosphate, silver chloride, and silver carbonate.

METHODS FOR REGENERATING SOLID ADSORBENTS

The invention provides for a method of regenerating a solid adsorbent, such as a molecular sieve or activated carbon, using stable fluorinated hydrocarbon compounds such as, for example, HFC-245cb (1,1,1,2,2-pentafluoropropane, as a regeneration fluid.

METHODS FOR REGENERATING SOLID ADSORBENTS

The invention provides for a method of regenerating a solid adsorbent, such as a molecular sieve or activated carbon, using stable fluorinated hydrocarbon compounds such as, for example, HFC-245cb (1,1,1,2,2-pentafluoropropane, as a regeneration fluid.

ADDITIVE ASSEMBLY FOR ELECTRONIC VAPING DEVICE

An additive assembly for an e-vaping device includes an adsorbent material that includes adsorbed carbon dioxide. The additive assembly may be in fluid communication with a vaporizer assembly that forms a generated vapor. The adsorbent material may release the carbon dioxide into the generated vapor based on at least a portion of the generated vapor adsorbing on the adsorbent material. The additive assembly may include a flavor material including a flavorant. The adsorbent material may generate heat based on at least a portion of the generated vapor adsorbing on the adsorbent material, and the flavor material may release flavorant into the generated vapor based at least in part on the heat generated by the adsorbent material. One or more of the adsorbent material and the flavor material may be included in beads. Adsorbent material and flavor material may be included in multiple additive structures within the additive assembly.

ADDITIVE ASSEMBLY FOR ELECTRONIC VAPING DEVICE

An additive assembly for an e-vaping device includes an adsorbent material that includes adsorbed carbon dioxide. The additive assembly may be in fluid communication with a vaporizer assembly that forms a generated vapor. The adsorbent material may release the carbon dioxide into the generated vapor based on at least a portion of the generated vapor adsorbing on the adsorbent material. The additive assembly may include a flavor material including a flavorant. The adsorbent material may generate heat based on at least a portion of the generated vapor adsorbing on the adsorbent material, and the flavor material may release flavorant into the generated vapor based at least in part on the heat generated by the adsorbent material. One or more of the adsorbent material and the flavor material may be included in beads. Adsorbent material and flavor material may be included in multiple additive structures within the additive assembly.

Self-supporting structures having active materials

A method and system for manufacturing and using a self-supporting structure in processing unit for adsorption or catalytic processes. The self-supporting structure has greater than 50% by weight of the active material in the self-supporting structure to provide an open-celled structure providing access to the active material. The self-supporting structures, which may be disposed in a processing unit, may be used in swing adsorption processes and other processes to enhance the recovery of hydrocarbons.

HYDROCARBON ADSORBENT
20230234022 · 2023-07-27 · ·

A hydrocarbon adsorbent having high hydrocarbon adsorbing properties even after exposed to a high temperature/high humidity reducing atmosphere, includes a FAU type zeolite having in ESR measurement a spin concentration of a least 1.0 × 10^19 (spins/g) and a ratio of a peak intensity at a magnetic field of at least 260 mT and at most 270 mT to a peak intensity at a magnetic field of at least 300 mT and at most 320 mT of at least 0.25 and at most 0.50 Å and containing bivalent copper. The hydrocarbon adsorbent may be used for a method for adsorbing hydrocarbons to be exposed to a high temperature/high humidity environment, and may be used particularly for a method for adsorbing hydrocarbons in an exhaust gas of an internal combustion engine, such as an automobile exhaust gas.