Methods for making acrylic acid, acrylic acid derivatives, or mixtures thereof by contacting a stream containing hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof with either an active catalyst containing an amorphous and partially-dehydrated phosphate salt or a precursor catalyst containing a crystalline phosphate salt in a reactor with a low corrosion rate are provided.

Methods for making acrylic acid, acrylic acid derivatives, or mixtures thereof by contacting a stream containing hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof with either an active catalyst containing an amorphous and partially-dehydrated phosphate salt or a precursor catalyst containing a crystalline phosphate salt in a reactor with a low corrosion rate are provided.

A combination for carrying out microwave assisted reactions is disclosed, such as acid digestion and solvent extraction. The combination includes a microwave transparent pressure-resistant reaction vessel and a flexible film fluoropolymer liner inside the reaction vessel. The flexible film liner has a size and shape that substantially conforms to the inner walls of the reaction vessel. A pressure-relief closure is positioned on the reaction vessel and the flexible film liner, and an infrared temperature detector that operates in wavelengths (frequencies) to which both the reaction vessel and the flexible liner are transparent, so that an exact fit and conductive heating to the outside of the reaction vessel are not required.

High quality carbon nanochains or carbon nanotubes are produced by methods that include mixing a carbon-containing feedstock with a catalyst to form a feedstock/catalyst mixture, or coating a catalyst with a carbon-containing feedstock, and subjecting the feedstock/catalyst mixture or feedstock-coated catalyst to irradiation with a laser to convert the feedstock into carbon nanochains or carbon nanotubes in the presence of the catalyst. In some instances, the feedstock is converted to a char by pyrolysis and the char is instead subjected to laser irradiation. The carbon-containing feedstock can be a biomass or a carbonaceous material. In some instances, the catalyst is a metal salt, preferably a transition metal salt. In some instances, the catalyst is an elemental metal, an alloy, or a combination thereof.

Methods for making acrylic acid, acrylic acid derivatives, or mixtures thereof by contacting a stream containing hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof with either an active catalyst containing an amorphous and partially-dehydrated phosphate salt or a precursor catalyst containing a crystalline phosphate salt in a reactor with a low corrosion rate are provided.

Methods for making acrylic acid, acrylic acid derivatives, or mixtures thereof by contacting a stream containing hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof with either an active catalyst containing an amorphous and partially-dehydrated phosphate salt or a precursor catalyst containing a crystalline phosphate salt in a reactor with a low corrosion rate are provided.

Disclosed is a hydrothermal synthesis device for continuously preparing an inorganic slurry using a hydrothermal method. The hydrothermal synthesis device includes a mixer to mix at least one precursor solution for preparing an inorganic material, injected via at least one supply tube, to prepare an intermediate slurry, a connection tube provided at a side of the mixer, continuously discharging the prepared intermediate slurry to a reactor, and having an inner surface contacting a precursor solution mixture on which abrasive polishing has been performed, and the reactor performing hydrothermal reaction of the intermediate slurry supplied from the connection tube by receiving a liquid stream heated to supercritical or subcritical conditions using a heat exchanger and connected to the connection tube into which the intermediate slurry prepared from the mixer is introduced and to at least one injection tube into which the heated liquid stream is injected.

A high-temperature decomposition reactor is provided. The reactor includes a reaction vessel, a furnace, and an insulation layer. The reaction vessel includes an inner volume configured to contain a quantity of carbonated medium while the quantity of carbonated medium transitions to a quantity of carbonation medium. The furnace is disposed around the reaction vessel and includes a furnace material. The furnace material is configured to simultaneously absorb heat and transmit heat. In some instances, the furnace material transmits heat to the inner volume to heat the carbonated medium. The insulation layer is disposed around the furnace and configured to prevent thermal losses from the reactor.

The invention is for use in gas chemistry for producing hydrogen-containing gas on the base of a CO and H.sub.2 mixture (syngas) from natural gas and other hydrocarbon gases. The object of the invention is to suppress side reactions resulting in soot formation when conducting the process in high productivity mode, and also to provide for an uncomplicated reactor design while maintaining compact dimensions thereof. The method for producing a hydrogen-containing gas comprises mixing natural gas with oxygen, partially oxidizing the natural gas with oxygen at a temperature ranging from 1300 C. to 1700 C. resulting in obtaining hydrogen-containing gas, and cooling the stream of the hydrogen-containing gas produced. Said cooling is performed until the temperature drops below 550 C. and at a rate above 100000 C./sec. The reactor comprises the following steps, which are arranged in series along the technological process: means for supplying natural gas and oxygen, a natural gas and oxygen mixing zone, a zone for conducting the reaction by partially oxidizing the natural gas with oxygen, and a zone for cooling the stream of the hydrogen-containing gas produced, which is equipped with a cooling body of revolution in order to provide an intensive cooling of the stream of hydrogen-containing gas by contacting thereof with said body of revolution.