A method for enabling gas exchange and chemical reactions with one or more liquid streams contained in a reactive process vessel are provided. One or more exchange layers within the process vessel can be composed of both collector media and releaser media. The exchange layers allow elements to facilitate increased performance of vessel operations by promoting gas component mixing and diffusion. Improved rates of gas component exchange mean less coking and more gas components available for reaction.

A gas replacement process and a gas replacement apparatus are employed, in the nitro compound hydrogenation reaction process. The gas replacement process at least includes a first step of subjecting a stream to be replaced to the gas replacement in presence of a first replacement gas, and then a second step of subjecting to the gas replacement in presence of the second replacement gas. Assuming the superficial velocity of the first replacement gas is V1, and the superficial velocity of the second replacement gas is V2, then V2/V1≥1.5.

A cooling tower (2) for cooling a liquid (4) with a gas (6), which cooling tower (2) comprises: (i) a vessel (8) for receiving the gas (6) passing upwardly and the liquid (4) passing downwardly, with the liquid (4) being hotter than the gas (6); (ii) a gas outlet (4) which is at a top portion (16) of the vessel (8) and which is for allowing the gas (6) to pass out of the vessel (8), (iii) a support member (20) which is positioned across a bottom portion (22) of the vessel (8): (iv) a plurality of apertures (24) which are in the support member (20) and through which the gas (6) and the liquid (4) are able to pass; (v) a fluidised bed (26) of packing elements (28) on the support member (20); (vi) liquid emitting means (30) which is positioned in the vessel (8) above the fluidised bed (26), and which is for emitting alas liquid (4) to be cooled such the liquid (4) passes downwardly towards the fluidised bed (26); (vii) pump means (32) for pumping the liquid to the liquid emitting means (30); and (viii) a fan (34) for blowing the pas upwardly through the fluidised bed (26), and the cooling tower (2) being such that it includes (ix) control means (31) for controlling (a) the velocity of the gas through die vessel (8), and (b) the liquid to gas ratio in the vessel (8), whereby the fluidised bed (26) is caused to operate at a tumbling rate which when combined with selected pre-fluidised packing height causes an approach temperature of below 10° F. (5.6° C.); (x) wherein the tumbling rate is controlled by a combination of controlled gas velocity and liquid to gas ratio creating turbulent mixing and tumbling of packing elements (28) in the fluidised bed (26); (xi) and wherein the pre-fluidised height of the fluidised bed (26) is from 0.15-1.0 m.

A method for enabling gas exchange and chemical reactions with one or more liquid streams contained in a reactive process vessel are provided. One or more exchange layers within the process vessel can be composed of both collector media and releaser media. The exchange layers allow elements to facilitate increased performance of vessel operations by promoting gas component mixing and diffusion. Improved rates of gas component exchange mean less coking and more gas components available for reaction.

The invention relates to an improved catalyst based on a tableted molded catalyst body, containing a metal-containing mixture, containing copper, zinc, and aluminum, with calcium aluminate as a binder material with a weight fraction of calcium aluminate in the range of 1.0% to 30.0%, for synthesizing methanol from synthesis gas. The invention further relates to the production of the catalyst and to the use of the catalyst in the synthesis of methanol from synthesis gas.

A method for facilitating the distribution of the flow of one or more streams within a bed vessel is provided. Disposed within the bed vessel are internal materials and structures including multiple operating zones. One type of operating zone can be a processing zone composed of one or more beds of solid processing material. Another type of operating zone can be a treating zone. Treating zones can facilitate the distribution of the one or more streams fed to processing zones. The distribution can facilitate contact between the feed streams and the processing materials contained in the processing zones.

A method for facilitating the distribution of the flow of one or more streams within a bed vessel is provided. Disposed within the bed vessel are internal materials and structures including multiple operating zones. One type of operating zone can be a processing zone composed of one or more beds of solid processing material. Another type of operating zone can be a treating zone. Treating zones can facilitate the distribution of the one or more streams fed to processing zones. The distribution can facilitate contact between the feed streams and the processing materials contained in the processing zones.

A method for enabling gas exchange and chemical reactions with one or more liquid streams contained in a reactive process vessel are provided. One or more exchange layers within the process vessel can be composed of both collector media and releaser media. The exchange layers allow elements to facilitate increased performance of vessel operations by promoting gas component mixing and diffusion. Improved rates of gas component exchange mean less coking and more gas components available for reaction.

A method for facilitating the distribution of the flow of one or more streams within a bed vessel is provided. Disposed within the bed vessel are internal materials and structures including multiple operating zones. One type of operating zone can be a processing zone composed of one or more beds of solid processing material. Another type of operating zone can be a treating zone. Treating zones can facilitate the distribution of the one or more streams fed to processing zones. The distribution can facilitate contact between the feed streams and the processing materials contained in the processing zones.

A method for facilitating the distribution of the flow of one or more streams within a bed vessel is provided. Disposed within the bed vessel are internal materials and structures including multiple operating zones. One type of operating zone can be a processing zone composed of one or more beds of solid processing material. Another type of operating zone can be a treating zone. Treating zones can facilitate the distribution of the one or more streams fed to processing zones. The distribution can facilitate contact between the feed streams and the processing materials contained in the processing zones.