An object of the present invention is to provide an exhaust gas purification catalyst for purifying exhaust gas, in particular, fine composite-metal particles contained therein, and a method for producing the same; the exhaust gas purification catalyst according to the present invention includes fine composite-metal particles containing Rh and Pd, wherein, when the fine composite-metal particles in the exhaust gas purification catalyst are analyzed by STEM-EDX, the average ratio of the amount of Pd with respect to the total amount of Rh and Pd in the fine composite-metal particles is 1.7 atomic % or more and 24.8 atomic % or less.

A catalysed filter for a positive ignition internal combustion engine comprises a porous filtering substrate having a total substrate length coated with a three-way catalyst washcoat composition comprising at least one precious metal selected from the group consisting of rhodium and one or both of platinum and palladium supported on a high surface area oxide, and an oxygen storage component, which composition being axially shared by a first zone comprising inlet surfaces of a first substrate length<total substrate length and a second zone comprising outlet surfaces of a second substrate length<total substrate length, wherein a sum of the substrate length in the first zone and the substrate length in the second zone≧100% and wherein one or both of the following applies: a washcoat loading in the first zone>second zone; and a total precious metal loading in the first zone>second zone.

A low platinum catalyst and method for making same. The catalyst comprises platinum-transition metal bimetallic alloy microcrystallites over a transition metal-nitrogen-carbon composite. A method of making a catalyst comprises preparation of transition metal organic frameworks, infusion of platinum, thermal treatment, and reduction to form the microcrystallites and composite.

An emissions treatment system for an exhaust stream of an internal combustion engine including hydrocarbons, carbon monoxide, and nitrogen oxides is provided. The disclosed system can include an exhaust conduit in fluid communication with the internal combustion engine via an exhaust manifold; a first three-way conversion catalyst (TWC-1) located downstream of the internal combustion engine in the exhaust conduit; an SCR-HCT catalyst comprising a selective catalytic reduction catalyst and a hydrocarbon trap downstream of the TWC-1 in the exhaust conduit; and a third catalyst downstream of the SCR-HCT combination in the exhaust conduit, the third catalyst comprising a platinum group metal (PGM) e.g., in an amount effective to oxidize hydrocarbons. Methods of making and using such systems and components thereof are also provided.

An emissions treatment system for an exhaust stream of an internal combustion engine including hydrocarbons, carbon monoxide, and nitrogen oxides is provided. The disclosed system can include an exhaust conduit in fluid communication with the internal combustion engine via an exhaust manifold; a first three-way conversion catalyst (TWC-1) located downstream of the internal combustion engine in the exhaust conduit; an SCR-HCT catalyst comprising a selective catalytic reduction catalyst and a hydrocarbon trap downstream of the TWC-1 in the exhaust conduit; and a third catalyst downstream of the SCR-HCT combination in the exhaust conduit, the third catalyst comprising a platinum group metal (PGM) e.g., in an amount effective to oxidize hydrocarbons. Methods of making and using such systems and components thereof are also provided.

A layered catalyst composite for the treatment of exhaust gas emissions, effective to provide lean NO.sub.x trap functionality and three-way conversion functionality is described. Layered catalyst composites can comprise catalytic material on a substrate, the catalytic material comprising at least two layers. The first layer comprising rare earth oxide-high surface area refractory metal oxide particles, an alkaline earth metal supported on the rare earth oxide-high surface area refractory metal oxide particles, and at least one first platinum group metal component supported on the rare earth oxide-high surface area refractory metal oxide particles. The second layer comprising a second platinum group metal component supported on a first oxygen storage component (OSC) and/or a first refractory metal oxide support and, optionally, a third platinum group metal supported on a second refractory metal oxide support or a second oxygen storage component.

A motor vehicle emission control system includes a three zone catalytic converter component having a honeycomb support body with catalytically active coating having a precious metal content applied on the channel walls. The first coating zone extends in the longitudinal direction from the inlet-side end to a first coating boundary and has a first precious metal content. The second coating zone extends in the longitudinal direction from the first coating boundary to a second coating boundary situated downstream from the first coating boundary and has a second precious metal content that is lower than the first precious metal content. The third coating zone extends from the second coating boundary to the outlet-side end and has a third precious metal content that is lower than the second precious metal content. The coating has oxidation catalyst activity and is free of rhodium.

Structures, catalysts, and reactors suitable for use for a variety of applications, including gas-to-liquid and coal-to-liquid processes and methods of forming the structures, catalysts, and reactors are disclosed. The catalyst material can be deposited onto an inner wall of a microtubular reactor and/or onto porous support structures using atomic layer deposition techniques.

A catalytic wall-flow monolith filter having three-way catalytic activity for use in an emission treatment system of a positive ignition internal combustion engine comprising a porous filter substrate having a first face and a second face defining a longitudinal direction there between and first and second pluralities of channels extending in the longitudinal direction, wherein the first plurality of channels is open at the first face and closed at the second face and the channels of the first plurality of channels are defined in part by channel wall surfaces, wherein the second plurality of channels is open at the second face and closed at the first face and the channels of the second plurality of channels are defined in part by channel wall surfaces and wherein channel walls between the channel wall surfaces of the first plurality of channels and the channel wall surfaces of the second plurality of channels are porous, wherein a first on-wall coating comprising catalytic material having a layer thickness is present on at least the channel wall surfaces of the first plurality of channels, wherein the catalytic material on channel wall surfaces of the first plurality of channels comprises one or more platinum group metal selected from the group consisting of (i) rhodium (Rh) only; (ii) palladium (Pd) only; (iii) platinum (Pt) and rhodium (Rh); (iv) palladium (Pd) and rhodium (Rh); and (v) platinum (Pt), palladium (Pd) and rhodium (Rh) and a refractory metal oxide support, wherein: (i) an amount by weight of the one or more platinum group metal, per unit volume of the on-wall coating present on channel wall surfaces of the first plurality of channels varies continually along the longitudinal direction; and/or (ii) the layer thickness of the on-wall coating present on channel wall surfaces of the first plurality of channels varies continually along the longitudinal direction.

An exhaust gas purifying catalyst includes: a wall-flow structure substrate including an inlet cell, an outlet cell, and a porous partition; a first catalyst layer formed inside the partition such that a thickness of the first catalyst layer is between 40% and 60%, inclusive, of an overall thickness T.sub.w of the partition; and a second catalyst layer formed inside the partition such that the second catalyst layer extends across an entire region of the partition in a thickness direction thereof.