Patent classifications
B01J29/7292
Oligomerization of olefins
A process for olefin oligomerization can include contacting a feedstock comprising C.sub.n and C.sub.2n olefins/paraffins under oligomerization conditions in the presence of an oligomerization catalyst, wherein n is 2 to 15; and recovering an oligomeric product comprising C.sub.3n oligomers having a branching index of less than 2.1. Optionally, the feedstock can further comprise C.sub.3n olefins/paraffins.
Catalyst and method for preparing low aromatic hydrocarbon liquid fuel through direct conversion of syngas
A method for preparing liquid fuel by direct conversion of syngas uses the syngas as reaction raw material and conducts a catalytic conversion reaction on a fixed bed or a moving bed. The catalyst is a composite catalyst formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of the component I is a metal oxide, and the component II is at least one of zeolites with one-dimensional ten-membered ring porous channels; and a weight ratio of the active ingredient in the component I to that in the component II is 0.1-20. The reaction process has high product yield and selectivity. The selectivity for liquid fuel composed of C.sub.5-C.sub.11 can reach 50-80%. The selectivity for aromatic hydrocarbon is less than 40% in C.sub.5-C.sub.11, while the selectivity for methane side product is less than 15%.
Hydrocarbon conversion using UZM-53
A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-53. This zeolite is represented by the empirical formula:
M.sup.+.sub.mR.sub.rAl.sub.1-xE.sub.xSi.sub.yO.sub.z
where M represents sodium, potassium or a combination of sodium and potassium cations, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-53 have utility in various hydrocarbon conversion reactions.
HYDROCARBON CONVERSION USING UZM-53
A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-53. This zeolite is represented by the empirical formula:
M.sup.+.sub.mR.sub.rAl.sub.1-xE.sub.xSi.sub.yO.sub.z
where M represents sodium, potassium or a combination of sodium and potassium cations, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-53 have utility in various hydrocarbon conversion reactions.
Production of low cloud point distillate fuels
Systems and methods are provided for catalytically dewaxing a diesel boiling range feed. In some aspects, catalytic dewaxing can be performed at low hydrogen treat gas rates and/or low hydrogen purity conditions. In other aspects, the systems and methods can allow for distillate dewaxing while reducing or minimizing the amount of equipment required.
Hydrocarbon conversion using UZM-53
A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-53. This zeolite is represented by the empirical formula:
M.sup.+.sub.mR.sub.rAl.sub.1-xE.sub.xSi.sub.yO.sub.z
where M represents sodium, potassium or a combination of sodium and potassium cations, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-53 have utility in various hydrocarbon conversion reactions such as oligomerization.
HYDROCARBON CONVERSION USING UZM-53
A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-53. This zeolite is represented by the empirical formula:
M.sup.+.sub.mR.sub.rAl.sub.1-xE.sub.xSi.sub.yO.sub.z
where M represents sodium, potassium or a combination of sodium and potassium cations, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-53 have utility in various hydrocarbon conversion reactions such as oligomerization.
Hydrocarbon conversion using UZM-53
A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-53. This zeolite is represented by the empirical formula:
M.sup.+.sub.mR.sub.rAl.sub.1-xE.sub.xSi.sub.yO.sub.z
where M represents sodium, potassium or a combination of sodium and potassium cations, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-53 have utility in various hydrocarbon conversion reactions such as oligomerization.
HYDROCARBON CONVERSION USING UZM-53
A new crystalline aluminosilicate zeolite comprising a MTT framework has been synthesized that has been designated UZM-53. This zeolite is represented by the empirical formula:
M.sup.+.sub.mR.sub.rAl.sub.1xE.sub.xSi.sub.yO.sub.z
where M represents sodium, potassium or a combination of sodium and potassium cations, R is the organic structure directing agent or agents derived from reactants R1 and R2 where R1 is diisopropanolamine and R2 is a chelating diamine, and E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof. Catalysts made from UZM-53 have utility in various hydrocarbon conversion reactions such as oligomerization.
Metal-Loaded Zeolite Catalysts for the Halogen-Free Conversion of Dimethyl Ether to Methyl Acetate
A catalyst for the carbonylation of dimethyl ether to methyl acetate. The catalyst comprises a zeolite, such as a mordenite zeolite, at least one Group IB metal, such as copper, and/or at least one Group VIII metal, such as iron, and at least one Group IIB metal, such as zinc. Such a catalyst with combined metals provides enhanced catalytic activity, improved stability, and improved selectivity to methyl acetate, and does not require a halogen promoter, as compared to a metal-free or copper only zeolite.