Patent classifications
B01J29/76
Structured catalyst for steam reforming, reforming apparatus provided with structured catalyst for steam reforming, and method for manufacturing structured catalyst for steam reforming
A structured catalyst for steam reforming of the present disclosure is used for producing reformed gas containing hydrogen from a reforming raw material containing hydrocarbon, and includes a support having a porous structure constituted of a zeolite-type compound, and at least one catalytic substance present inside the support. The support includes channels connecting with each other, and the catalytic substance is metal nanoparticles and present at least in the channels of the support.
CATALYSTS WITH MODIFIED ACTIVE PHASE DISPERSION AND METHOD TO PREPARE CATALYSTS WITH MODIFIED ACTIVE PHASE DISPERSION
Catalyst particles comprising one or more active metal components and methods for manufacturing such catalyst particles are provided. The particles are a composite of a granulating agent or binder material such as an inorganic oxide, and an ultra-stable Y (hereafter “USY”) zeolite in which some of the aluminum atoms in the framework are substituted with zirconium atoms and/or titanium atoms and/or hafnium atoms. The one or more active phase components are incorporated in a composite mixture of the inorganic oxide binder and the post-framework modified USY zeolite prior to forming the catalyst particles.
CATALYSTS WITH MODIFIED ACTIVE PHASE DISPERSION AND METHOD TO PREPARE CATALYSTS WITH MODIFIED ACTIVE PHASE DISPERSION
Catalyst particles comprising one or more active metal components and methods for manufacturing such catalyst particles are provided. The particles are a composite of a granulating agent or binder material such as an inorganic oxide, and an ultra-stable Y (hereafter “USY”) zeolite in which some of the aluminum atoms in the framework are substituted with zirconium atoms and/or titanium atoms and/or hafnium atoms. The one or more active phase components are incorporated in a composite mixture of the inorganic oxide binder and the post-framework modified USY zeolite prior to forming the catalyst particles.
EXHAUST GAS TREATMENT SYSTEM COMPRISING A MULTIFUNCTIONAL CATALYST
The present invention relates to an exhaust gas treatment system for treating exhaust gas from a lean burn combustion engine, wherein said exhaust gas comprises hydrocarbons and NOx, the exhaust gas treatment system comprising: (i) a means for injecting hydrocarbons into an exhaust gas stream; (ii) a diesel oxidation catalyst (DOC) comprising a substrate and a catalyst coating provided on the substrate, wherein the catalyst coating comprises one or more platinum group metals, wherein the one or more platinum group metals comprise platinum; (iii) a means for injecting a nitrogenous reducing agent into an exhaust gas stream; and (iv) a multifunctional catalyst (MFC) comprising an oxidation catalyst, and a selective catalytic reduction (SCR) catalyst for the selective catalytic reduction of NOx, wherein the MFC comprises a substrate and a catalyst coating provided on the substrate, wherein the catalyst coating comprises the oxidation catalyst and the SCR catalyst, wherein the oxidation catalyst comprises one or more platinum group metals, wherein the one or more platinum group metals comprise palladium and/or platinum, and wherein the SCR catalyst comprises a zeolitic material loaded with copper and/or iron; wherein the means for injecting hydrocarbons, the DOC, the means for injecting a nitrogenous reducing agent, and the MFC are located in sequential order in a conduit for exhaust gas, wherein the means for injecting hydrocarbons into an exhaust gas stream is located upstream of the DOC, wherein the DOC is located upstream of the MFC, and wherein the means for injecting a nitrogenous reducing agent into the exhaust gas stream is located between the DOC and the MFC. Furthermore, the present invention relates to a method for the treatment of exhaust gas using the exhaust gas treatment system according to the present invention, and to a method for the preparation of an exhaust gas treatment system according to the present invention.
Catalyst composition comprising magnetic material adapted for inductive heating
The invention provides a catalyst composition, including a mixture of catalytically active particles and a magnetic material, such as superparamagnetic iron oxide nanoparticles, capable of inductive heating in response to an applied alternating electromagnetic field. The catalytically active particles will typically include a base metal, platinum group metal, oxide of base metal or platinum group metal, or combination thereof, and will be adapted for use in various catalytic systems, such as diesel oxidation catalysts, catalyzed soot filters, lean NOx traps, selective catalytic reduction catalysts, ammonia oxidation catalysts, or three-way catalysts. The invention also includes a system and method for heating a catalyst material, which includes a catalyst article that includes the catalyst composition and a conductor for receiving current and generating an alternating electromagnetic field in response thereto, the conductor positioned such that the generated alternating electromagnetic field is applied to at least a portion of the magnetic material.
CHA-TYPE ZEOLITE AND METHOD FOR PRODUCING THE SAME
Provided is at least one of a CHA-type zeolite having a greater amount of a paired aluminum structure than do CHA-type zeolites of the related art; a catalyst containing the CHA-type zeolite; and a method for producing these. A method for producing a CHA-type zeolite includes crystallizing a composition that contains an alumina source, a silica-alumina source, an alkali source, an organic structure-directing agent and water. Preferably, the composition is prepared by mixing the alumina source, the alkali source, the organic structure-directing agent and the water together and subsequently mixing the silica-alumina source therewith.
Structured catalyst for oxidation for exhaust gas purification, method for producing same, automobile exhaust gas treatment device, catalytic molding, and gas purification method
The structured catalyst for oxidation for exhaust gas purification includes a support having a porous structure constituted by a zeolite-type compound, and at least one type of oxidation catalyst that is present in the support and selected from the group consisting of metal and metal oxide, the support having channels that communicate with each other, and the oxidation catalyst being present in at least the channels of the support.
Structured catalyst for oxidation for exhaust gas purification, method for producing same, automobile exhaust gas treatment device, catalytic molding, and gas purification method
The structured catalyst for oxidation for exhaust gas purification includes a support having a porous structure constituted by a zeolite-type compound, and at least one type of oxidation catalyst that is present in the support and selected from the group consisting of metal and metal oxide, the support having channels that communicate with each other, and the oxidation catalyst being present in at least the channels of the support.
COMPOSITE, ZONE-COATED, DUAL-USE AMMONIA (AMOX) AND NITRIC OXIDE OXIDATION CATALYST
A composite, zone-coated, dual-use ammonia (AMOX) and nitric oxide oxidation catalyst (12) comprises: a substrate (5) having a total length L and a longitudinal axis and having a substrate surface extending axially between a first substrate end (I) and a second substrate end (O); two or more catalyst washcoat zones (1; 2) comprised of a first catalyst washcoat layer (9) comprising a refractory metal oxide support material and one or more platinum group metal components supported thereon and a second catalyst washcoat layer (11) different from the first catalyst washcoat layer (9) and comprising a refractory metal oxide support material and one or more platinum group metal components supported thereon, which two or more catalyst washcoat zones (1; 2) being arranged axially in series on and along the substrate surface, wherein a first catalyst washcoat zone (1) having a length L.sub.1, wherein L.sub.1<L, is defined at one end by the first substrate end (I) and at a second end (13) by a first end (15) of a second catalyst washcoat zone (2) having a length L.sub.2, wherein L.sub.2<L, wherein the first catalyst washcoat zone (1) comprises a first refractory metal oxide support material and one or more platinum group metal components supported thereon; and the second catalyst washcoat zone comprises a second refractory metal oxide support material and one or more platinum group metal components supported thereon; and a washcoat overlayer (G) extending axially from the first substrate end for up to 200% of the axial length of the underlying first catalyst washcoat layer, which washcoat overlayer comprising a particulate metal oxide loading of >48.8 g/l (>0.8 g/in.sup.3), wherein the particulate metal oxide is an aluminosilicate zeolite including at least one of copper, iron and manganese, wherein a total platinum group metal loading in the first catalyst washcoat zone (1) defined in grams of platinum group metal per litre of substrate volume (g/l) is different from the total platinum group metal loading in the second catalyst washcoat zone (2).
COMPOSITE, ZONE-COATED, DUAL-USE AMMONIA (AMOX) AND NITRIC OXIDE OXIDATION CATALYST
A composite, zone-coated, dual-use ammonia (AMOX) and nitric oxide oxidation catalyst (12) comprises: a substrate (5) having a total length L and a longitudinal axis and having a substrate surface extending axially between a first substrate end (I) and a second substrate end (O); two or more catalyst washcoat zones (1; 2) comprised of a first catalyst washcoat layer (9) comprising a refractory metal oxide support material and one or more platinum group metal components supported thereon and a second catalyst washcoat layer (11) different from the first catalyst washcoat layer (9) and comprising a refractory metal oxide support material and one or more platinum group metal components supported thereon, which two or more catalyst washcoat zones (1; 2) being arranged axially in series on and along the substrate surface, wherein a first catalyst washcoat zone (1) having a length L.sub.1, wherein L.sub.1<L, is defined at one end by the first substrate end (I) and at a second end (13) by a first end (15) of a second catalyst washcoat zone (2) having a length L.sub.2, wherein L.sub.2<L, wherein the first catalyst washcoat zone (1) comprises a first refractory metal oxide support material and one or more platinum group metal components supported thereon; and the second catalyst washcoat zone comprises a second refractory metal oxide support material and one or more platinum group metal components supported thereon; and a washcoat overlayer (G) extending axially from the first substrate end for up to 200% of the axial length of the underlying first catalyst washcoat layer, which washcoat overlayer comprising a particulate metal oxide loading of >48.8 g/l (>0.8 g/in.sup.3), wherein the particulate metal oxide is an aluminosilicate zeolite including at least one of copper, iron and manganese, wherein a total platinum group metal loading in the first catalyst washcoat zone (1) defined in grams of platinum group metal per litre of substrate volume (g/l) is different from the total platinum group metal loading in the second catalyst washcoat zone (2).