The present invention relates to a porous iron oxide-zirconia composite catalyst, a preparation method thereof, and a method for producing alcohol using the same, and the iron oxide-zirconia composite catalyst having a porous structure may produce alcohol at low cost by carrying out an excellent methane reforming reaction even under room temperature and room pressure conditions through an electrochemical reaction.

An ebullated bed process for the hydroconversion of heavy hydrocarbon feedstocks that provides for high conversion of the heavy hydrocarbon with a low sediment yield. The process uses for its catalyst bed small particles of a specifically defined shaped hydroprocessing catalyst which is contacted with the heavy hydrocarbon feedstock under hydroconversion conditions and yields a hydrocarbon conversion having a relatively low sediment content.

Disclosed is a composition useful in the hydrolysis of sulfur compounds that are contained in a gas stream. The composition comprises a calcined co-mulled mixture of psuedoboehmite, a cobalt compound, and a molybdenum compound such that the composition comprises gamma-alumina, at least 7.5 wt. % molybdenum, and at least 2.75 wt. % cobalt. The composition is made by forming into an agglomerate a co-mulled mixture pseudoboehmite, a cobalt component, and a molybdenum component followed by drying and calcining the agglomerate to provide a catalyst composition comprising gamma-alumina, at least 7.5 wt. % molybdenum, and at least 2.75 wt. % cobalt.

Provided herein are photocatalytic carbon filters for the removal impurities such as microorganisms, organic compounds, algal toxins, and their degradation by-products from water and wastewater. The photolytic carbon filters comprise a porous titanium substrate comprising TiO.sub.2 nanotube arrays and multi-wall carbon nanotubes disposed on the TiO.sub.2 nanotube arrays. Also provided herein are methods of manufacture and methods of use of the disclosed photocatalytic carbon filters.

A catalyst for oxidative coupling of methane, and preparation and application thereof. The catalyst comprises: a manganese sesquioxide, a tungstate, a manganese composite oxide having a perovskite structure and/or a spinel structure, and a carrier. The manganese sesquioxide, tungstate, and manganese composite oxide having a perovskite structure and/or a spinel structure are supported on the carrier, or the manganese sesquioxide and tungstate are supported on the admixture of the said manganese composite oxide having a perovskite structure and/or a spinel structure and the said carrier. Based on 100 parts by weight of the catalyst, the content of the manganese sesquioxide is a parts by weight, the content of the tungstate is b parts by weight, the content of the manganese composite oxide having the perovskite structure and/or the spinel structure is c parts by weight. e content of the carrier is d parts by weight. 0<a20, 1b20, 1c40, 20d<98.

A method of forming a chemically reactive membrane includes applying a first solution to a structure, the first solution includes a macrocyclic ligand having electron-donating ligands and a side functional group for crosslinking, crosslinking a plurality of the macrocyclic ligand to form a first network of crosslinked macrocyclic ligands, and applying a second solution to the structure, the second solution comprising a catalytic center. Each catalytic center complexes with the electron-donating ligands of each macrocyclic ligand to form catalytic sites in the first network of crosslinked macrocyclic ligands.

Provided herein are methods for making a freeze-cast material having a internal structure, the methods comprising steps of: determining the internal structure of the material, the internal structure having a plurality of pores, wherein: each of the plurality of pores has directionality; and the step of determining comprises: selecting a temperature gradient and a freezing front velocity to obtain the determined internal structure based on the selected temperature gradient and the selected freezing front velocity; directionally freezing a liquid formulation to form a frozen solid, the step of directionally freezing comprising: controlling the temperature gradient and the freezing front velocity to match the selected temperature gradient and the selected freezing front velocity during directionally freezing; wherein the liquid formulation comprises at least one solvent and at least one dispersed species; and subliming the at least one solvent out of the frozen solid to form the material.

Provided is a catalyst for exhaust gas purification, the catalyst comprising: a noble metal; an alumina support particle; and a ZrO.sub.2 semiconductor support particle deposited on a surface of the alumina support particle.

The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is in the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least one oxide with a melting point higher than 1500 C., such as alumina, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from an aqueous suspension containing precursor oxide grains for the ceramic matrix that have a specific size, by a spray-drying technique.

Disclosed is a honeycomb filter for collecting fine particles that includes a wall portion formed from a base material containing ceria-zirconia composite oxide and an inorganic binder. In a pore diameter distribution in which a pore diameter and a log differential pore volume measured through mercury porosimetry are respectively represented by a horizontal axis and a vertical axis, the wall portion has a peak in a range in which the pore diameter is greater than or equal to 0.01 m and less than 1 m and a peak in a range in which the pore diameter is greater than or equal to 1 m and less than or equal to 50 m.