A semi-continuous or continuous method and system to improve all phases of ion-exchange resin regeneration such as backwash, resin separation, chemical treatment, slow rinse, fast rinse, resin mixing, and final QA/QC to reduce, reuse and recycle water and chemicals employed in ion-exchange resin regeneration operations. Aqueous media quality is controlled in both backwash as well as ion-exchange resin separation.

A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.

A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.

A method is provided for separating anion and cation exchange resins. The specific-gravity difference between the anion and cation exchange resins is used for separation with a column body. The column body comprises an outer column and an inner column set within. The inner column has an outlet with position adjustable for outputting the anion exchange resin according to its ratio. The flow zone and the resin expansion zone can effectively shorten the time required for the separation. Besides, the required equipment is simplified. Only the size of the column body needs to be adjusted according to the amount of the mixed bed resin to-be-treated. The present invention can be applied to different proportions of mixed beds and mixed resins. On consideration of equipment cost and operating cost, the method can complete the separation of the anion and cation exchange resins in a short time with the simplified equipment.

A method is provided for separating anion and cation exchange resins. The specific-gravity difference between the anion and cation exchange resins is used for separation with a column body. The column body comprises an outer column and an inner column set within. The inner column has an outlet with position adjustable for outputting the anion exchange resin according to its ratio. The flow zone and the resin expansion zone can effectively shorten the time required for the separation. Besides, the required equipment is simplified. Only the size of the column body needs to be adjusted according to the amount of the mixed bed resin to-be-treated. The present invention can be applied to different proportions of mixed beds and mixed resins. On consideration of equipment cost and operating cost, the method can complete the separation of the anion and cation exchange resins in a short time with the simplified equipment.

A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.

A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.

A system and method configured to restore ion exchange kinetic properties and purify resin is described. Degraded ion exchange kinetic properties of anion resin will eventually result in impurity slippage through resin charges. This system and method employs an acid catalyst in combination with sulfite cleaning solution to remove organic material and to protonate iron oxides for deconstruction and removal from anion resins. The cleaning solution, when applied via a cleaning vessel utilizing an eductor(s)/plenum and wedge-wire screen draw chamber, while controlling all phases of cleaning by electronic monitoring, yields complete restoration of ion exchange kinetics on usable resin. As such, the system and method provides a safe, effective, and vastly improved method for restoring anion resin kinetics and improving regeneration quality, for improved resin performance and minimizing resin replacement costs.

Provided is a method of treating a vinyl aromatic resin (I) comprising (a) bringing the vinyl aromatic resin (I) into contact with an alcohol, and maintaining the contact between the vinyl aromatic resin (I) and the alcohol for 10 minutes or more, and (b) bringing the vinyl aromatic resin into contact with a base. wherein the vinyl aromatic resin (I), prior to steps (a) and (b), has benzyl chloride groups,
benzyl alcohol groups, and methylene bridge groups.

Provided is a method of treating a vinyl aromatic resin (I) comprising (a) bringing the vinyl aromatic resin (I) into contact with an alcohol, and maintaining the contact between the vinyl aromatic resin (I) and the alcohol for 10 minutes or more, and (b) bringing the vinyl aromatic resin into contact with a base. wherein the vinyl aromatic resin (I), prior to steps (a) and (b), has benzyl chloride groups,
benzyl alcohol groups, and methylene bridge groups.