The present disclosure provides systems and methods for hydrogen production as well as apparatuses useful in such systems and methods. Hydrogen is produced by steam reforming of a hydrocarbon in a gas heated reformer that is heated using one or more streams comprising combustion products of a fuel in an oxidant, preferably in the presence of a carbon dioxide circulating stream.

An electrically heated reactor is a tube surrounded by electrical heating means having radiative sheeting placed coaxially with regard to the reactor tube. The surface area of the sheeting facing the outer surface area of the reactor tube defines an inner surface area covering at least 60% of the reactor tube outer surface area. The distance between the reactor tube and the heating means is selected such that the ratio between the inner surface area of the electrical heating means to the reactor tube outer surface area is in the range of 0.7 to 3.0. The reactor is useful in many industrial scale high temperature gas conversion and heating technologies.

Described herein are thermal condensation reactors and processes of using the same. A presently described thermal condensation reactor includes a heat transfer chamber, wherein the heat transfer chamber is a fluidized bed having a fluidization gas flow in a first direction, and wherein the heat transfer chamber has a plurality of heating zones that may be maintained at different temperatures, and a plurality of reaction tubes disposed in the heat transfer chamber in a second direction perpendicular to the fluidization gas flow, each reaction tube having a reactant gas flow that passes through the plurality of heating zones.

Methods and systems for treating volatile organic compounds (VOCs) generated in a hydrocarbon treating process are disclosed. An effluent stream containing the VOCs, as well as carbon dioxide (CO.sub.2) is combined with hot exhaust gas from a turbine and provided to a waste heat recovery unit (WHRU). The WHRU is adapted to contain a catalyst bed containing oxidation catalyst capable of effecting the oxidation of the VOCs. The temperature of the catalyzing reaction can be tailored based on the position of the catalyst bed within the temperature gradient of the WHRU. The methods and systems described herein solve the problem of effecting the removal of VOCs from the effluent. Heating the CO.sub.2-containing effluent in the WHRU also lend buoyancy to the effluent, thereby facilitating its dispersal upon release.

A product gas manifold system for a steam reformer is provided. The product gas manifold system includes a product gas manifold including an outer jacket tube and a gas-conveying inner tube extending concentrically and coaxially over its entire length, a space between the inner and jacket tubes being at least partially filled with a first insulating material, a plurality of nozzle tubes, each for connecting a reformer tube to the product gas manifold, a second insulating material disposed around the jacket tube, a curved outer surface outwardly limiting the second layer of the second insulating material and following the shape of the jacket tube in the axial direction.

Systems and processes disclosed may be used to produce a high purity isobutane stream and a high purity 1-butene stream from mixed C4 streams having disparate starting compositions.

A reformer furnace is provided for use in converting a hydrocarbon feed into a synthesis gas stream. The reformer furnace includes at least one bayonet reformer tube located at least partly within an enclosed volume. The reformer furnace includes a first support arranged to support the second end portion of the at least one bayonet reformer tube against the second endwall of the reformer furnace.

A source material gas (31) is supplied to a catalyst (30), a first heating medium (21) is caused to flow through a first heat exchange section (22) so that a temperature of a surface of the first heat exchange section (22) on a catalyst side is maintained higher than a dew point of a reacted gas (32), a second heating medium (51) is caused to flow through a second heat exchange section (52) so that a temperature of a surface of the second heat exchange section (52) on a space (4) side is maintained not higher than the dew point of the reacted gas (32), and a liquid obtained by condensation in the space (4) is allowed to fall down so as to be separated from the source material gas.

A naphtha reforming reactor system comprising a first reactor comprising a first inlet and a first outlet, wherein the first reactor is configured to operate as an adiabatic reactor, and wherein the first reactor comprises a first naphtha reforming catalyst; and a second reactor comprising a second inlet and a second outlet, wherein the second inlet is in fluid communication with the first outlet of the first reactor, wherein the second reactor is configured to operate as an isothermal reactor, and wherein the second reactor comprises a plurality of tubes disposed within a reactor furnace, a heat source configured to heat the interior of the reactor furnace; and a second naphtha reforming catalyst disposed within the plurality of tubes, wherein the first naphtha reforming catalyst and the second naphtha reforming catalyst are the same or different.

Reactor systems, reactor coolant systems, and associated processes for polymerizing polyolefins are described. The reactor systems generally include a reactor pipe and a coolant system, in which the coolant system includes a jacket pipe surrounding at least a portion of the reactor pipe to form an annulus therebetween, at least one spacer coupling the jacket to the reactor pipe, and a coolant which flows through the annulus to remove heat from the reactor pipe. At least one of the external surface of the reactor pipe, the internal surface of the jacket, and at least one spacer, are independently modified, for example by polishing, coating, or reshaping, to reduce the fluid resistance of the coolant flow through the annulus.