This coated metal sheet for exterior covering has a metal sheet and a top coating layer disposed on the metal sheet, the top coating layer is configured from a fluororesin and contains a gloss control agent comprising 0.01-15 vol % of microporous particles and a matte agent comprising primary particles, and the coated metal sheet satisfies the belowmentioned formulae. In the number-based particle size distribution of the gloss control agent and the matte agent, R is the number average particle size (μm) of the gloss control agent, D1.sub.97.5 and D2.sub.97.5 represent the 97.5% particle size (μm) of the gloss control agent and the matte agent, Ru is the upper limit particle size (μm) of the gloss control agent, and T is the top coating layer thickness (μm).

D1.sub.97.5/T≦0.9

Ru≦1.2T

R≧1.0

0.5≦D2.sub.97.5/T≦7.0

3≦T≦40.

The disclosure relates to a self-healing laminate composition. The composition includes a first, self-healing layer with a self-healing polymer and a second, mechanical layer adjacent to the first layer. The second layer includes any desired polymer, for example a crosslinked polymer, a thermoplastic polymer, or a functional thermoset polymer. Self-healing polymers with dynamic covalent bonds are suitable, for example those with dynamic urea bonds and/or dynamic urethane bonds. A self-healing polymer that is damaged can undergo autonomous repair when separated surfaces re-contact each other due to the soft nature of the self-healing polymer, whereupon reversible bonds can reform to rejoin and repair the damaged self-healing polymer. When the self-healing laminate according to the disclosure is damaged, the self-healing mechanism of the first layer can cause the repair of both layers. The self-healing laminate composition can be used as a coating on any of a variety of substrates to provide self-healing properties to a surface

The disclosure relates to a self-healing laminate composition. The composition includes a first, self-healing layer with a self-healing polymer and a second, mechanical layer adjacent to the first layer. The second layer includes any desired polymer, for example a crosslinked polymer, a thermoplastic polymer, or a functional thermoset polymer. Self-healing polymers with dynamic covalent bonds are suitable, for example those with dynamic urea bonds and/or dynamic urethane bonds. A self-healing polymer that is damaged can undergo autonomous repair when separated surfaces re-contact each other due to the soft nature of the self-healing polymer, whereupon reversible bonds can reform to rejoin and repair the damaged self-healing polymer. When the self-healing laminate according to the disclosure is damaged, the self-healing mechanism of the first layer can cause the repair of both layers. The self-healing laminate composition can be used as a coating on any of a variety of substrates to provide self-healing properties to a surface

The present invention relates to a method for producing a multicoat paint system by producing a basecoat or a plurality of directly successive basecoats directly on a substrate coated with a first coat, producing a clearcoat directly on the one or the topmost of the plurality of basecoats, and subsequently jointly curing the one or the plurality of basecoats and the clearcoat. At least one of the basecoat materials is admixed, directly before application, either with an aqueous dispersion (D1) comprising a polyamide (PA) having an acid number of 15 to 60 mg KOH/g or with an aqueous dispersion (D2) comprising a polyamide (PA) and an amide wax (AW).

A coating composition includes a binder component (A), a flake-like aluminum pigment (B) having an average particle diameter (d50) of 18 μm to 25 μm, and a flake-like pigment (C) being a flake-like pigment other than flake-like aluminum pigments and having an average particle diameter (d50) of 8 μm to 30 μm. A content of the flake-like aluminum pigment (B) is 10 parts by mass to 50 parts by mass and a content of the flake-like pigment (C) is 0.5 parts by mass to 10 parts by mass, based on 100 parts by mass of the binder component (A). A content ratio (B)/(C) of the flake-like aluminum pigment (B) to the flake-like pigment (C) is 2/1 to 50/1 in terms of a solid content mass ratio.

Described herein are surface-treated polymeric substrates. Also described herein are polymeric coatings, which may be used as surface treatments.

An object is to provide an aqueous coating material composition having high viscosity expression property as well as a viscosity property of decreasing viscosity with increase in shear velocity; in particular, to provide an aqueous coating material composition that can form a multilayer coating film having excellent smoothness, clarity, flip-flop property, adhesion, and water resistance; in addition, to provide a method for forming a multilayer coating film using such aqueous coating material composition, as well as a coated article that has been coated with such aqueous coating material composition. As a solution, an aqueous coating material composition is provided that contains a polyester resin (A), acrylic resin particles (B), a curing agent (C), and a coloring pigment (D), wherein the polyester resin (A) is a resin containing a trifunctional or higher polyfunctional polycarboxylic acid (a1) and a polyol (a2) as monomer components.

A method includes a step of applying an aqueous 2-package type first colored paint to form an uncured first colored coating film; a step of applying an aqueous 1-package type second colored paint to form an uncured second colored coating film; a step of applying a solvent-based 2-package type clear paint to form an uncured clear coating film; and a step of heating the uncured first colored coating film, the uncured second colored coating film and the uncured clear coating film to 75 to 100° C. to simultaneously cure these films. The solvent-based 2-package type clear paint contains a hydroxyl group-containing acrylic resin and a polyisocyanate compound in a ratio of 1.5 to 2.0 equivalents of isocyanate groups in the polyisocyanate compound relative to 1 equivalent of hydroxyl groups in the hydroxyl group-containing acrylic resin.

A hydrogenated NBR composition comprising 30 to 200 parts by weight of titanium oxide and 1 to 8 parts by weight of magnesium oxide, based on 100 parts by weight of hydrogenated NBR. By forming a crosslinked rubber layer of the rubber composition on a metal plate, a gasket material with excellent blister resistance, whose roll kneadability is improved without reducing the rubber strength of hydrogenated NBR, is provided. Moreover, the rubber composition is effective as a rubber raw material for use in soft metal or a high hardness hydrogenated NBR material for which kneading processing is difficult.

A hydrogenated NBR composition comprising 30 to 200 parts by weight of titanium oxide and 1 to 8 parts by weight of magnesium oxide, based on 100 parts by weight of hydrogenated NBR. By forming a crosslinked rubber layer of the rubber composition on a metal plate, a gasket material with excellent blister resistance, whose roll kneadability is improved without reducing the rubber strength of hydrogenated NBR, is provided. Moreover, the rubber composition is effective as a rubber raw material for use in soft metal or a high hardness hydrogenated NBR material for which kneading processing is difficult.