The use of a water-soluble thermoset binder for binder jetting of a cemented carbide or cermet green body is provided. The water-soluble thermoset binder includes a compound A, being at least one organic, non-aromatic substance, including at least two hydroxyl groups and a compound B, being at least one organic, non-aromatic substance, including at least two carboxyl groups, wherein the compound A and compound B are monomers or oligomers. The binder will lead to an increased strength of the printed green body.

The use of a water-soluble thermoset binder for binder jetting of a cemented carbide or cermet green body is provided. The water-soluble thermoset binder includes a compound A, being at least one organic, non-aromatic substance, including at least two hydroxyl groups and a compound B, being at least one organic, non-aromatic substance, including at least two carboxyl groups, wherein the compound A and compound B are monomers or oligomers. The binder will lead to an increased strength of the printed green body.

A cutting tool includes a cemented carbide substrate. The cemented carbide consists of hard constituents in a metallic binder. The hard constituents include WC. The WC content in the cemented carbide is 80-93 wt %. The cemented carbide has Ni and Al, and a Ni content of 3-13 wt %, a weight ratio of Co/Ni<0.33, a weight ratio of Fe/Ni<0.25, a weight ratio of Cr/Ni<0.25 and a weight ratio of 0.02<Al/(Ni+Co+Fe)<0.1. The crack resistance W is defined as the ratio of the load applied on a Vickers hardness indentation and the total crack length of the cracks formed at the corners of the Vickers hardness indentation. The product of the hardness H(rake) at the rake face and the crack resistance W(rake) at the rake face is H(rake)*W(rake)>5000 HV100*N/μm.

A cutting tool includes a cemented carbide substrate. The cemented carbide consists of hard constituents in a metallic binder. The hard constituents include WC. The WC content in the cemented carbide is 80-93 wt %. The cemented carbide has Ni and Al, and a Ni content of 3-13 wt %, a weight ratio of Co/Ni<0.33, a weight ratio of Fe/Ni<0.25, a weight ratio of Cr/Ni<0.25 and a weight ratio of 0.02<Al/(Ni+Co+Fe)<0.1. The crack resistance W is defined as the ratio of the load applied on a Vickers hardness indentation and the total crack length of the cracks formed at the corners of the Vickers hardness indentation. The product of the hardness H(rake) at the rake face and the crack resistance W(rake) at the rake face is H(rake)*W(rake)>5000 HV100*N/μm.

A cutting tool includes a substrate of cemented carbide having hard constituents in a metallic binder. The hard constituents include WC. The WC content in the cemented carbide is 80-95 wt %. The cemented carbide has a Fe+Ni+Co+Cr content of 3-13 wt %, an atomic ratio of 0.05<Fe/(Fe+Ni+Co+Cr)<0.35, an atomic ratio of 0.05<Ni/(Fe+Ni+Co+Cr)<0.35, an atomic ratio of 0.05<Co/(Fe+Ni+Co+Cr)<0.35 and an atomic ratio of 0.05<Cr/(Fe+Ni+Co+Cr)<0.35. The crack resistance W measured on the rake face of the cutting tool is at least 25% higher than the W measured on a cross section of the bulk area of the cutting tool.

A cutting tool includes a substrate of cemented carbide having hard constituents in a metallic binder. The hard constituents include WC. The WC content in the cemented carbide is 80-95 wt %. The cemented carbide has a Fe+Ni+Co+Cr content of 3-13 wt %, an atomic ratio of 0.05<Fe/(Fe+Ni+Co+Cr)<0.35, an atomic ratio of 0.05<Ni/(Fe+Ni+Co+Cr)<0.35, an atomic ratio of 0.05<Co/(Fe+Ni+Co+Cr)<0.35 and an atomic ratio of 0.05<Cr/(Fe+Ni+Co+Cr)<0.35. The crack resistance W measured on the rake face of the cutting tool is at least 25% higher than the W measured on a cross section of the bulk area of the cutting tool.

A method for manufacturing an R-T-B based sintered magnet according the present disclosure comprises: a step for preparing a coarse ground powder which is made from an alloy for R-T-B based sintered magnets and which has an average particle size of 10-500 μm; a step for obtaining a fine powder having an average particle size of 2.0-4.5 μm, by feeding the coarse ground powder to a jet mill device that has a grinding chamber filled with inert gas and grinding the coarse ground powder; and a step for producing a sintered body of the fine powder, wherein the inert gas has been humidified, and the oxygen content of the R-T-B based sintered magnet is 1000-3500 ppm by mass.

A method for manufacturing an R-T-B based sintered magnet according the present disclosure comprises: a step for preparing a coarse ground powder which is made from an alloy for R-T-B based sintered magnets and which has an average particle size of 10-500 μm; a step for obtaining a fine powder having an average particle size of 2.0-4.5 μm, by feeding the coarse ground powder to a jet mill device that has a grinding chamber filled with inert gas and grinding the coarse ground powder; and a step for producing a sintered body of the fine powder, wherein the inert gas has been humidified, and the oxygen content of the R-T-B based sintered magnet is 1000-3500 ppm by mass.

Me-N—C catalysts, wherein Me can include a transition metal, Mn, Fe, Co, or a combination of metals with Me-INU moieties located at the exterior surface of the Me-N—C catalysts are produced by a chemical vapor deposition synthesis. The synthesis methods can utilize non-solid-contact pyrolysis wherein a metal salt can be vaporized. Gaseous metal from the vaporized metal salt can displace a metal M from the N—C zeolitic imidazolate framework. The non-solid-contact pyrolysis does not mix solid iron precursors (e.g., Me=Mn, Fe, or Co) with the solid N—C zeolitic imidazolate framework precursors during or before the synthesis, which improves the process compared to conventional methods.

Me-N—C catalysts, wherein Me can include a transition metal, Mn, Fe, Co, or a combination of metals with Me-INU moieties located at the exterior surface of the Me-N—C catalysts are produced by a chemical vapor deposition synthesis. The synthesis methods can utilize non-solid-contact pyrolysis wherein a metal salt can be vaporized. Gaseous metal from the vaporized metal salt can displace a metal M from the N—C zeolitic imidazolate framework. The non-solid-contact pyrolysis does not mix solid iron precursors (e.g., Me=Mn, Fe, or Co) with the solid N—C zeolitic imidazolate framework precursors during or before the synthesis, which improves the process compared to conventional methods.