The present invention provides wood preservative compositions comprising micronized particles. In one embodiment, the composition comprises dispersions of micronized metal or metal compounds. In another embodiment, the wood preservative composition comprises an inorganic component comprising a metal or metal compound and organic biocide. When the composition comprises an inorganic component and an organic biocide, the inorganic component or the organic biocide or both are present as micronized particles. When compositions of the present invention are used for preservation of wood, there is minimal leaching of the metal and biocide from the wood.

The present invention provides wood preservative compositions comprising micronized particles. In one embodiment, the composition comprises dispersions of micronized metal or metal compounds. In another embodiment, the wood preservative composition comprises an inorganic component comprising a metal or metal compound and organic biocide. When the composition comprises an inorganic component and an organic biocide, the inorganic component or the organic biocide or both are present as micronized particles. When compositions of the present invention are used for preservation of wood, there is minimal leaching of the metal and biocide from the wood.

The co-formulation of a wood preservative (‘treated’) with an inorganic (alkali metal silicates) based flame retardant which undergoes chemical impregnation. Once the ‘treated flame retardant” working solution has fully penetrated (sapwood) into the wood, it then undergoes a heat (fixation) process using various heating schedules to achieve chemical fixation. The treated flame retardant Modified Wood [tfrMW] products are then tested for their enhanced fire performance properties. When heated, wood undergoes thermal degradation and combustion producing gases, vapours, tars & chars. Using the ‘cone calorimeter’ test method, the [tfrMW] products showed a significant reduction in the following parameters: heat release rate (HRR), mass loss rate (MLR) & smoke generated (SEA) values compared to untreated radiata pine.

Methods for treating cellulosic materials comprising introducing a liquid treating composition into the cellulosic material, the treating composition comprising a solution prepared from at least: (i) one or more of a copper amine complex or copper ammine complex, such as copper tetraamine carbonate, (ii) one or more of ammonia or a water-soluble amine and (iii) water; and exposing the cellulosic material provided thereby to carbon dioxide and/or carbonic acid to provide treated cellulosic material, and treated cellulosic materials prepared thereby.

Methods for treating cellulosic materials comprising introducing a liquid treating composition into the cellulosic material, the treating composition comprising a solution prepared from at least: (i) one or more of a copper amine complex or copper ammine complex, such as copper tetraamine carbonate, (ii) one or more of ammonia or a water-soluble amine and (iii) water; and exposing the cellulosic material provided thereby to carbon dioxide and/or carbonic acid to provide treated cellulosic material, and treated cellulosic materials prepared thereby.

The present invention is directed to amine soluble, or solid copper triazole based wood preservative formulations containing certain types of quaternary ammonium compounds, or nonionic sufactants, and the use of these quaternary ammonium compound-, or nonionic surfactant-containing formulations to pressure treat and preserve wood. The addition of the quaternary ammonium compounds, or nonionic surfactants to the wood preservation treatment solutions allows improved penetration of the copper from the solution into wood and reduces the duration of time required to effectively pressure treat the wood with the preservation composition.

According to the present invention there is provided the use of one or more low aromatic or substantially low aromatic solvents as a carrier, for efficacious use within a preservative formulation for treating wood or other cellulosic species. The invention also provides for a wood preservative formulation comprising such a carrier. In an embodiment, the carrier is selected from the commercially-available range of Exxsol® D and Isopar® fluids.

According to the present invention there is provided the use of one or more low aromatic or substantially low aromatic solvents as a carrier, for efficacious use within a preservative formulation for treating wood or other cellulosic species. The invention also provides for a wood preservative formulation comprising such a carrier. In an embodiment, the carrier is selected from the commercially-available range of Exxsol® D and Isopar® fluids.

Methods for treating cellulosic materials comprising introducing a liquid treating composition into the cellulosic material, the treating composition comprising a solution prepared from at least: (i) one or more of a copper amine complex or copper ammine complex, such as copper tetraamine carbonate, (ii) one or more of ammonia or a water-soluble amine and (iii) water; and exposing the cellulosic material provided thereby to carbon dioxide and/or carbonic acid to provide treated cellulosic material, and treated cellulosic materials prepared thereby.

Methods for treating cellulosic materials comprising introducing a liquid treating composition into the cellulosic material, the treating composition comprising a solution prepared from at least: (i) one or more of a copper amine complex or copper ammine complex, such as copper tetraamine carbonate, (ii) one or more of ammonia or a water-soluble amine and (iii) water; and exposing the cellulosic material provided thereby to carbon dioxide and/or carbonic acid to provide treated cellulosic material, and treated cellulosic materials prepared thereby.