The present invention relates to a process for the production of hollow plastic articles in a rotational molding process as well as to hollow plastic articles made by such a process, in particular to a process for the production of hollow plastic articles which exhibit a colored surface exhibiting striking pearlescent or metallic effects.

Presented are manufacturing systems, methods, and devices for forming footwear using scrap or waste plastic materials. A method for manufacturing an article of footwear, such as an athletic shoe, begins with receiving a batch of recycled plastic, which may include thermoplastic elastomers or ethylene-vinyl acetate, and grinding the batch of recycled plastic material. The ground recycled material is processed, for example, by adding a foaming agent that activates at elevated temperatures. The processed recycled material is placed into the internal cavity of a final mold that is shaped like a segment of the footwear, such as a unitary sole structure. To form the footwear segment, the processed recycled material is heated past the threshold activation temperature of the foaming agent such that the foaming agent causes the recycled material to expand and fill the internal cavity of the final mold. The formed footwear segment is then extracted from the mold.

Disclosed herein are composite building materials having at least one textured surface. The textured surface includes at least a plurality of particles. The textured surface closely mimics conventional building materials. The building materials can contain an image printed using ink jet printing methods with inks optimized for enhanced color stability.

The invention relates to a resin composition comprising at least an organophosphorous compound and a branched amorphous carboxylic acid functional polyester, said polyester having a T.sub.g of at least 40 C., said polyester comprising at least 1 to 45% mol of 2,2-dimethyl-1,3-propanediol; a C.sub.3 to C.sub.5 aliphatic diol AD1 not including 2,2-dimethyl-1,3-propanediol; a C.sub.6 to C.sub.50 aliphatic or cycloaliphatic diol AD2; 0.1 to 10% mol of an at least trifunctional monomer; 1 to 55% mol of terephthalic acid, wherein the % mol is based on the polyester. The powder coatings of the present invention derived upon curing at low temperature of the thermosetting powder coating compositions of the invention that were storage stable and comprised said resin composition and a crosslinker having functional groups that are reactive with the carboxylic acid groups of the polyester, have limited or no blooming, good smoothness sufficient reverse impact resistance and preferably have also good degassing limit.

The invention relates to a vinyl functionalized urethane resin (VFUR) useful as a curing agent in thermosetting powder coating compositions, a process for making said vinyl functionalized urethane resin, a vinyl functionalized urethane resin composition (VFURC) useful as a curing agent in thermosetting powder coating compositions, a process for making vinyl functionalized urethane resin composition, a thermosetting powder coating composition (TPCC), a process for the preparation thereof, a cured thermosetting powder coating composition, processes for coating an article with said thermosetting powder coating composition and an article coated with said thermosetting powder coating composition as well as uses of the vinyl functionalized urethane resin or of the vinyl functionalized urethane resin composition or of the thermosetting powder coating composition or of the articles having coated and cured thereon said thermosetting powder coating composition. The invention relates also to thermosetting powder coating composition useful for powder-in-mold coating articles such as reinforced polymeric e.g. polyester resin articles and to powder-in-mold coating methods employing the thermosetting powder coating composition and use of the in-mold coated article.

Impellers made of composite materials with flow path cavities covered by an erosion resistant coating are manufactured by covering removable molds having shapes corresponding to a negative geometry of the flow path cavities, with the erosion resistant coating using plating or thermal spraying. After shaping and curing a composite material around the molds covered with the erosion resistant coating, the molds are removed, while the erosion resistant coating remains on the composite impeller.

The present invention relates to methods of manufacturing composite products having a surface effect. In some examples described, a composite product has a simulated surface, for example a stone-effect surface formed by pressing a particulate-form surface material (30) and a sheet-form curable material (40) onto a substrate (44) having an open-celled structure. In other examples, a laminate product having a veneer is formed by pressing a veneer and a sheet-form material onto a substrate including a porous structure. The veneer may comprise a wood material. In other examples, a surface effect material is bonded to a skin by pressing a sheet-form curable material to a mold surface and the surface effect material. Where the surface effect material has a high thermal conductivity, the composite product formed can feel cool to the touch.

The present invention relates to a painted molding article in which a paint composition is painted in a molding part formed of an injection molding thermoplastic resin composition, and the injection molding thermoplastic resin composition comprises: (a) a base resin including polyamide (a-1) and polyphenylene ether (a-2); (b) an impact modifier; and (c) a carbon fibril, wherein the polyamide (a-1) forms a matrix phase of the injection molding thermoplastic resin composition, the polyphenylene ether (a-2) and the impact modifier (b) form a domain phase of the injection molding thermoplastic resin composition, the carbon fibril (c) is dispersed on the domain phase and the matrix phase, the content of the carbon fibril (c) dispersed on the matrix phase is higher than the content of the carbon fibril (c) dispersed on the domain phase, and the ratio of weight of the carbon fibril (c) to weight of the polyamide (a-1) may be 0.006 to 0.03.