Articles are provided including at least one polyurethane prepared from: (a) about 1 equivalent of at least one polyisocyanate; (b) about 0.005 to about 0.35 equivalent of at least one polycaprolactone polyol; (c) about 0.01 to about 1.0 equivalent of at least one polyol selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, 1,2-ethanediol, propanediol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, dodecane diol, octadecanediol, cyclopentanediol, 1,4-cyclohexanediol, cyclohexanedimethanol, 1,4-benzenedimethanol, xylene glycol, hydroxybenzyl alcohol, dihydroxytoluene, bis(2-hydroxyethyl) terephthalate, 1,4-bis(hydroxyethyl)piperazine, N,N′,bis(2-hydroxyethyl)oxamide and mixtures thereof; and (d) about 0.01 to about 0.5 equivalent of at least one polyol selected from the group consisting of glycerol, tetramethylolmethane, trimethylolethane, trimethylolpropane, erythritol, pentaerythritol, dipentaerythritol, tripentaerythritol, sorbitan, and mixtures thereof, each based upon the about 1 equivalent of the at least one polyisocyanate, wherein the article has a Gardner Impact strength of at least about 400 in-lb according to ASTM D-5420-04.

Methods and apparatus comprising a dewetting phase and a polymerization liquid that are immiscible, and can be used for the formation of three-dimensional objects, wherein the method does not require a dead zone. Additionally, methods and apparatus that employ an optically transparent cooling apparatus to mitigate heat generated during the fabrication process, and the use of a mobile phase to provide a shearing interface to reduce interfacial adhesive forces.

Methods and apparatus comprising a dewetting phase and a polymerization liquid that are immiscible, and can be used for the formation of three-dimensional objects, wherein the method does not require a dead zone. Additionally, methods and apparatus that employ an optically transparent cooling apparatus to mitigate heat generated during the fabrication process, and the use of a mobile phase to provide a shearing interface to reduce interfacial adhesive forces.

A process for the production of an article for the cladding of floors or walls, comprising the steps of, in a mold: a) optionally applying a gel coat layer, based on a first curing polymer resin, on the inside of the mold in order to obtain a coated mold, and b) introducing into the core of the mold or into the core of the coated mold from step a) a filling composition which is based on a second curing polymer resin supplemented with at least one mineral filler, wherein core contains at least 5% wt and at most 20% wt of curing polymer resin, relative to the dry amount of filling composition, and the filling composition contains only one single initiator in a concentration of 0.5% wt to 5.0% wt relative to the amount of curing polymer resin in the filling composition.

A curable casting compound, including a polymeric binder and at least one particulate filler incorporated therein, wherein the filler is ground fruit kernels and/or fruit shells, wherein either only the at least one filler composed of ground fruit kernels and/or fruit shells or additionally at least one further particulate inorganic filler is present.

A method of forming a device of composite material includes providing a mold having an internal space forming a cavity with an inner surface, the cavity having a shape corresponding to an inner shape of the device to be formed, placing inserts at one or more pre-defined positions along the inner surface, holding the inserts at the one or more positions, introducing removable material into the cavity of the mold to form a pattern having the inserts fixed therein when the removable material is in solid form, and removing the pattern having the inserts fixed therein from the mold.

A process for the production of composite materials at low temperatures, as well as a composite material obtained by the process and articles of manufacture comprising the composite material are provided.

The present disclosure provides device having a reaction vessel with one or more permeable membranes disposed therein that separate the reaction vessel into at least a first portion and a second portion. The one or more membranes permit first reactants from a first solution in the first portion or reactants from a second solution in the second portion to seep or percolate to a reaction zone proximate a surface of the one or more membranes. A reaction of the first and second reactants forms a two-dimensional polymer film material. A roller located inside of the reaction vessel draws the two-dimensional polymer film material reaction out of the reaction zone.

The present invention relates to curable resin compositions, to methods for producing cured compositions using said curable resin compositions, and to items, in particular molded parts, produced by means of such method.

A method for manufacturing an engineered stone, the method including: providing a mixture comprising at least a stone or stone like material and a binder; compacting the mixture; curing the binder; and printing on at least a top surface of the engineered stone.