Patent classifications
B41C2210/262
Method for producing a planographic printing plate
Provided is a method of producing a planographic printing plate, including: subjecting a planographic printing plate precursor, which has a support and a positive-working image recording layer, to image-wise exposure; and developing it using an alkaline aqueous solution which contains a specific compound and has a pH of from 8.5 to 10.8, in this order. The recording layer has: a lower layer containing a water-insoluble and alkali-soluble resin and an infrared ray absorbing agent; and an upper layer containing a water-insoluble and alkali-soluble polyurethane resin and a polyorganosiloxane. The specific compound is a nonionic or anionic surfactant, or at least one compound represented by Formula (1) or (2), wherein R.sup.11, R.sup.12, and R.sup.13 each represent an alkyl group; R.sup.14 represents an alkylene group; and R.sup.15 represents a single bond or a divalent linking group containing a hetero atom; and R.sup.21, R.sup.22, and R.sup.23 each represent an alkyl group. ##STR00001##
Method for producing a planographic printing plate
Provided is a method of producing a planographic printing plate, including: subjecting a planographic printing plate precursor, which has a support and a positive-working image recording layer, to image-wise exposure; and developing it using an alkaline aqueous solution which contains a specific compound and has a pH of from 8.5 to 10.8, in this order. The recording layer has: a lower layer containing a water-insoluble and alkali-soluble resin and an infrared ray absorbing agent; and an upper layer containing a water-insoluble and alkali-soluble polyurethane resin and a polyorganosiloxane. The specific compound is a nonionic or anionic surfactant, or at least one compound represented by Formula (1) or (2), wherein R.sup.11, R.sup.12, and R.sup.13 each represent an alkyl group; R.sup.14 represents an alkylene group; and R.sup.15 represents a single bond or a divalent linking group containing a hetero atom; and R.sup.21, R.sup.22, and R.sup.23 each represent an alkyl group. ##STR00001##
Ablation-type lithographic printing members having improved exposure sensitivity and related methods
Dry, ablation-type, nitrocellulose-containing lithographic printing members include dual adjacent imaging layers, both including an absorber and at least one containing a binder (which may include or consist essentially of a melamine resin). The absorber of the nitrocellulose-containing layer is a pigment and this layer contains no absorbing dye, while the absorber of the other imaging layer includes or consists essentially of a dye.
POSITIVE TYPE PLANOGRAPHIC PRINTING PLATE PRECURSOR AND METHOD OF PRODUCING PLANOGRAPHIC PRINTING PLATE
Provided is a positive type planographic printing plate precursor including: a support; and an image recording layer provided on the support, in which the image recording layer contains: a phenol compound containing a phenolic hydroxyl group and a substituent A represented by CH.sub.2OR in a molecule thereof, and having a molecular weight of from 200 to 2,000; a polymer having at least one selected from the group consisting of a urea bond and a urethane bond in a main chain thereof; and an infrared absorbent.
NEGATIVE TYPE PHOTOSENSITIVE RESIN COMPOSITION, NEGATIVE TYPE PLANOGRAPHIC PRINTING PLATE PRECURSOR, AND METHOD OF PREPARING PLANOGRAPHIC PRINTING PLATE
A negative type photosensitive resin composition includes a polymer compound which contains a linking group represented by Formula A-1 in a main chain and an ethylenically unsaturated group; and a polymerization initiator. In Formula A-1, R.sup.1 and R.sup.2 each independently represent a hydrogen atom or a monovalent organic group, and X.sup.1 represents a linking group represented by any of Formulae A-2 to A-6.
A negative type planographic printing plate precursor includes an image recording layer containing the negative type photosensitive resin composition.
A method of preparing a planographic printing plate includes, in order, an exposure step of image-exposing the negative type planographic printing plate precursor; and a development step of performing development by removing a non-exposed portion of the exposed negative type planographic printing plate precursor using a developer.
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ON-PRESS DEVELOPMENT TYPE LITHOGRAPHIC PRINTING PLATE PRECURSOR, METHOD OF PREPARING LITHOGRAPHIC PRINTING PLATE, AND LITHOGRAPHIC PRINTING METHOD
An on-press development type lithographic printing plate precursor includes a support and an image-recording layer on the support. The image-recording layer contains a polymerization initiator, an infrared absorber, a color forming substance precursor, and an auxiliary capable of donating an electron to the infrared absorber. A polymer having an ethylenically unsaturated group and a water-soluble monofunctional monomer are present on a surface of the support on an image-recording layer side, a layer in contact with the support on the image-recording layer side contains the polymer having an ethylenically unsaturated group and the water-soluble monofunctional monomer, or a layer in contact with the support on the image-recording layer side, other than the image-recording layer, contains the polymer having an ethylenically unsaturated group and the image-recording layer contains the water-soluble monofunctional monomer.
PRINTING PLATE PRECURSOR, PLANOGRAPHIC PRINTING PLATE, BLANK PLATE FOR PRINTING, AND LAMINATE THEREOF
Provided is a printing plate precursor including: a support; a layer which contains a polymer on one side of the support; and a layer which contains a metal oxide obtained by hydrolyzing and polycondensing an organic metal compound or an inorganic metal compound and fine particles on the other side of the support, in which an average particle diameter of the fine particles is 0.3 m or greater and is greater than the thickness of the layer containing a metal oxide and fine particles, and in a case where the printing plate precursors are laminated, dislocation in stacking precursors, adhesion between precursors, and scratches can be all prevented even without using interleaving paper.
ABLATION-TYPE LITHOGRAPHIC PRINTING MEMBERS HAVING IMPROVED EXPOSURE SENSITIVITY AND RELATED METHODS
Dry, ablation-type, nitrocellulose-containing lithographic printing members include dual adjacent imaging layers, both including an absorber and at least one containing a binder (which may include or consist essentially of a melamine resin). The absorber of the nitrocellulose-containing layer is a pigment and this layer contains no absorbing dye, while the absorber of the other imaging layer includes or consists essentially of a dye.
Recording media and related methods
A recording medium comprises an oleophilic substrate and, thereover, a topmost oleophobic layer comprising a cured polymeric silicone matrix that consists essentially of the addition-cure reaction product of a vinyl-functional polydialkylsiloxane and a silane cross-linking agent. The vinyl-functional polydialkylsiloxane has a molecular weight ranging from 30,000 to 75,000 or 110,000 to 130,000. If the molecular weight of the vinyl-functional polydialkylsiloxane is within the range of 30,000 to 75,000, the molar ratio of silane groups to vinyl groups is within the range of about 11:1 to about 25:1; and if the molecular weight of the vinyl-functional polydialkylsiloxane is within the range of 110,000 to 130,000, the molar ratio of silane groups to vinyl groups is from about 5:1 to about 27:1. The recording medium may be used as a lithographic printing plate.
POSITIVE TONE LITHOGRAPHIC PRINTING PLATE PRECURSOR AND METHOD OF PREPARING LITHOGRAPHIC PRINTING PLATE
A positive-working lithographic printing plate precursor including a support and an image-recording layer formed on the support and consisting of a positive-working photosensitive resin composition, in which the positive-working photosensitive resin composition contains a compound having at least one electron-withdrawing group and at least one phenolic hydroxyl group in one molecule, an alkali-soluble resin, and an infrared absorber, and the electron-withdrawing group excludes a sulfonyl group; and a method of preparing a lithographic printing plate using the positive-working lithographic printing plate precursor.