Patent classifications
B41C2210/266
Photosensitive resin composition, lithographic printing plate precursor, and method for producing lithographic printing plate
A photosensitive resin composition contains a polymer compound having a linking group represented by Formula A-1 in the main chain; and an infrared absorbing material. In Formula A-1, R.sup.1 and R.sup.2 each independently represent a hydrogen atom or a monovalent organic group, and X.sup.1 is a specific linking group. ##STR00001##
POSITIVE TYPE PLANOGRAPHIC PRINTING PLATE PRECURSOR AND METHOD OF PRODUCING PLANOGRAPHIC PRINTING PLATE
Provided are a positive type planographic printing plate precursor including: a support which has a hydrophilic surface; and an image recording layer on the support, the image recording layer containing: a polymer compound 1 having at least one bond selected from the group consisting of a urea bond, a urethane bond, and a carbonate bond in a main chain and containing a sulfonamide group in the main chain; a polymer compound 2-1 having at least one of a constitutional unit represented by Formula S-1 or a constitutional unit represented by Formula S-2 or a polymer compound 2-2 having a constitutional unit represented by Formula EV-1 and a constitutional unit represented by Formula EV-2; and an infrared absorbent, and a method of producing a planographic printing plate obtained by using the positive type planographic printing plate precursor.
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Method for preparing flexographic printing plates
Flexographic printing members are prepared from a flexographic printing plate precursor consisting essentially of: backing film, water- or water-dispersible photosensitive layer, and cover sheet in contact with the photosensitive layer. The cover sheet is removed and a mask element is laminated directly in contact with the photosensitive layer. Exposure through the mask element provides exposed regions and non-exposed regions. The non-exposed regions are removed with an aqueous developer having: a) a C.sub.12-20 saturated or unsaturated fatty acid (or alkali metal salt) at 0.25-2.0 weight %, and at least 85 weight % of a C.sub.18 mono- or poly-unsaturated fatty acid (or alkali metal salt); b) an aminopolycarboxylic acid (or alkali metal salt) at 0.05-0.30 weight %; c) a buffer at 05-0.60 weight %; and d) water. The photosensitive layer has a controlled release of 5-500 g/cm using ASTM D-3330 Method D, between its front imaging surface and the mask element.
Method for producing a planographic printing plate
Provided is a method of producing a planographic printing plate, including: subjecting a planographic printing plate precursor, which has a support and a positive-working image recording layer, to image-wise exposure; and developing it using an alkaline aqueous solution which contains a specific compound and has a pH of from 8.5 to 10.8, in this order. The recording layer has: a lower layer containing a water-insoluble and alkali-soluble resin and an infrared ray absorbing agent; and an upper layer containing a water-insoluble and alkali-soluble polyurethane resin and a polyorganosiloxane. The specific compound is a nonionic or anionic surfactant, or at least one compound represented by Formula (1) or (2), wherein R.sup.11, R.sup.12, and R.sup.13 each represent an alkyl group; R.sup.14 represents an alkylene group; and R.sup.15 represents a single bond or a divalent linking group containing a hetero atom; and R.sup.21, R.sup.22, and R.sup.23 each represent an alkyl group. ##STR00001##
Method for producing a planographic printing plate
Provided is a method of producing a planographic printing plate, including: subjecting a planographic printing plate precursor, which has a support and a positive-working image recording layer, to image-wise exposure; and developing it using an alkaline aqueous solution which contains a specific compound and has a pH of from 8.5 to 10.8, in this order. The recording layer has: a lower layer containing a water-insoluble and alkali-soluble resin and an infrared ray absorbing agent; and an upper layer containing a water-insoluble and alkali-soluble polyurethane resin and a polyorganosiloxane. The specific compound is a nonionic or anionic surfactant, or at least one compound represented by Formula (1) or (2), wherein R.sup.11, R.sup.12, and R.sup.13 each represent an alkyl group; R.sup.14 represents an alkylene group; and R.sup.15 represents a single bond or a divalent linking group containing a hetero atom; and R.sup.21, R.sup.22, and R.sup.23 each represent an alkyl group. ##STR00001##
METHOD FOR PREPARING FLEXOGRAPHIC PRINTING PLATES
Flexographic printing members are prepared from a flexographic printing plate precursor consisting essentially of: backing film, water- or water-dispersible photosensitive layer, and cover sheet in contact with the photosensitive layer. The cover sheet is removed and a mask element is laminated directly in contact with the photosensitive layer. Exposure through the mask element provides exposed regions and non-exposed regions. The non-exposed regions are removed with an aqueous developer having: a) a C.sub.12-20 saturated or unsaturated fatty acid (or alkali metal salt) at 0.25-2.0 weight %, and at least 85 weight % of a C.sub.18 mono- or poly-unsaturated fatty acid (or alkali metal salt); b) an aminopolycarboxylic acid (or alkali metal salt) at 0.05-0.30 weight %; c) a buffer at 05-0.60 weight %; and d) water. The photosensitive layer has a controlled release of 5-500 g/cm using ASTM D-3330 Method D, between its front imaging surface and the mask element.
PHOTOSENSITIVE RESIN PRINTING PLATE PRECURSOR FOR RELIEF PRINTING, AND PRINTING PLATE
A photosensitive resin printing plate precursor is disclosed for relief printing, including a support, a photosensitive resin layer, and a cover film stacked in this order, wherein the photosensitive resin layer comprises a lower layer present on a support side and an upper layer present on a cover-film side, wherein the upper layer is a photosensitive resin layer that contains a water-soluble or water-dispersible resin (A) having a glass transition temperature measured by differential scanning calorimeter of 40 to 90 C., wherein the upper layer has a thickness of 3 to 30 micrometers, wherein the lower layer is a layer that contains a water-soluble or water-dispersible resin (B) having a glass transition temperature higher than the glass transition temperature of the water-soluble or water-dispersible resin (A) by 5 C. or more, and wherein the glass transition temperature of the resin (B) measured by differential scanning calorimeter is 95 to 135 C.
LITHOGRAPHIC IMAGING AND PRINTING WITH NEGATIVE-WORKING PHOTORESPONSIVE PRINTING MEMBERS
Negative-working, IR-sensitive printing plates utilize a radiation-sensitive composition having a component polymerizable by a free-radical mechanism, at least part of which comprises or consists essentially of a non-particulate, aliphatic urethane acrylic oligomer that is infinitely water-dilutable but not water-soluble.
PHOTOSENSITIVE RESIN COMPOSITION, LITHOGRAPHIC PRINTING PLATE PRECURSOR, AND METHOD FOR PRODUCING LITHOGRAPHIC PRINTING PLATE
There is provided a photosensitive resin composition which enables production of a lithographic printing plate precursor having a non-image portion which has good solubility in an alkali aqueous solution and which enables production of a lithographic printing plate having excellent printing durability, excellent chemical resistance, and, in particular, excellent printing durability at the time of using a low quality print material, a lithographic printing plate precursor obtained by using the photosensitive resin composition, and a method for producing a lithographic printing plate.
The photosensitive resin composition contains a polymer compound having a linking group represented by Formula A-1 in the main chain; and an infrared absorbing material. In Formula A-1, R.sup.1 and R.sup.2 each independently represent a hydrogen atom or a monovalent organic group, and X.sup.1 is a specific linking group.
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PLANOGRAPHIC PRINTING PLATE PRECURSOR, MANUFACTURING METHOD OF PLANOGRAPHIC PRINTING PLATE, AND PRINTING METHOD
An object of the present invention is to provide an on-press development-type planographic printing plate precursor which suppresses color-forming defect after a lapse of time and has excellent visibility. Another object of the present invention is to provide a manufacturing method of a planographic printing plate and a printing method. The planographic printing plate precursor of the present invention is an on-press development-type planographic printing plate precursor including a support and an image-recording layer, in which the support has an aluminum alloy plate and an anodic oxide film disposed on the aluminum alloy plate, a density of intermetallic compounds having a major axis of 2.0 m or more on a surface of the support on a side opposite to the image-recording layer is 1,000 pieces/mm.sup.2 or less, the image-recording layer contains an infrared absorber and an acid color-forming agent, and a color-forming factor of the acid color-forming agent, which is determined by a predetermined measuring method, is 20,000 or more.