Provided are a composition and a manufacturing method of a solid CO.sub.2 sorbent having excellent physical properties and chemical reaction characteristics, particularly having an excellent mid-temperature range activity for a fluidized bed process, for use in collecting a CO.sub.2 source (pre-combustion or pre-utilization) in syngas application fields such as integrated coal gasification combined cycle (IGCC) power systems, synthetic natural gas (SNG) and synthetic liquid fuel (CTL).

Systems and methods for generating power using hydrogen fuel, such as derived from natural gas, are provided. Feed materials are introduced into a compact hydrogen generator to produce carbon dioxide, hydrogen gas and steam. Sorbent material within the compact hydrogen generator acts to absorb carbon dioxide, forming a used sorbent. Hydrogen gas and steam are separated from the used sorbent and passed to a power generator such as a hydrogen turbine to produce power. The used sorbent is introduced into a calciner and heated to desorb carbon dioxide and form a regenerated sorbent which can be recycled to the compact hydrogen generator.

A hydrogen production system comprises a hydrogen pyrolysis reactor which has a hydrocarbon input, an electrical input and at least one hydrogen output. The hydrogen production system also comprises a hydrogen-fuelled generator. Means are provided to route part of the hydrogen from one of the at least one hydrogen outputs to the hydrogen-fuelled generator. The hydrogen-fuelled generator then generates an electrical output, which is routed to the electrical input of the hydrocarbon pyrolysis reactor. A related method of operating a hydrogen production system is also described.

Disclosed herein is a fuel for use in a combustor of a gas turbine, wherein the fuel is a gas mixture that comprises hydrogen and exhaust gas from a total combustor.

Systems and methods for generating power using hydrogen fuel, such as derived from natural gas, are provided. Feed materials are introduced into a compact hydrogen generator to produce carbon dioxide, hydrogen gas and steam. Sorbent material within the compact hydrogen generator acts to absorb carbon dioxide, forming a used sorbent. Hydrogen gas and steam are separated from the used sorbent and passed to a power generator such as a hydrogen turbine to produce power. The used sorbent is introduced into a calciner and heated to desorb carbon dioxide and form a regenerated sorbent which can be recycled to the compact hydrogen generator.

A process is provided for increasing the recovery of high-purity hydrogen from a steam cracking process in situations where byproduct methane yield is high relative to hydrogen. After a hydrocarbon gas stream is sent through a cold box and demethanizer, a small proportion of methane is sent through a pressure swing adsorption unit separately from a gas stream that contains hydrogen to increase high-purity hydrogen recovery by about 6%.

The present disclosure provides systems and methods for hydrogen production as well as apparatuses useful in such systems and methods. Hydrogen is produced by steam reforming of a hydrocarbon in a gas heated reformer that is heated using one or more streams comprising combustion products of a fuel in an oxidant, preferably in the presence of a carbon dioxide circulating stream.

The present invention concerns a sorption-enhanced water-gas shift (SEWGS) process for the formation of a CO.sub.2 product stream and an H.sub.2 product stream, comprising (a) a reaction step, wherein a feed gas comprising CO.sub.x, wherein x=1-2, and H.sub.2O is fed into a SEWGS reactor containing a catalyst and sorbent material capable of adsorbing CO.sub.2, thereby forming the H.sub.2 product stream and a sorbent material loaded with CO.sub.2; (b) a rinse step, wherein steam is fed to the SEWGS reactor, thereby establishing a pressure in the range of 5-50 bar; (c) a pre-blowdown step, wherein the pressure in the SEWGS reactor is reduced to establish a blowdown pressure in the range of 0.5-1.5 times the partial pressure of CO and CO.sub.2 in the feed gas of step (a); (d) a blowdown step, wherein the pressure in the SEWGS reactor is reduced to the regeneration pressure in the range of 1-5 bar, thereby releasing at least part of the CO.sub.2 from the loaded sorbent material, thereby forming the CO.sub.2 product stream; and (e) a purge step, wherein steam is fed to the SEWGS reactor, thereby releasing further CO.sub.2 molecules from the SEWGS reactor, wherein the off gas released from the reactor during step (c) is collected separately from the CO.sub.2 product stream released from the reactor during step (d). The separate collection of the off gas of pre-blowdown step (c) affords a highly efficient process with excellent CO.sub.2 purity and carbon capture ratio.

The present invention provides a process for the manufacture of a synthetic fuel comprising gasifying a carbonaceous feedstock comprising waste materials and/or biomass to generate a raw synthesis gas; supplying the raw synthesis gas to a primary clean-up zone to wash particulates and ammonia or HCl out of the raw synthesis gas; contacting the synthesis gas in a secondary clean-up zone with a physical solvent for sulphurous materials; contacting the desulphurised raw synthesis gas in a tertiary clean-up zone with a physical solvent for CO.sub.2 effective to absorb CO.sub.2; removing at least part of the absorbed CO.sub.2 in a solvent regeneration stage to recover CO.sub.2 in a form sufficiently pure for sequestration or other use; and supplying the clean synthesis gas to a further reaction train to generate a synthetic fuel.

A process for the production of hydrogen comprises: a first steam reforming step of a feedstock containing hydrocarbons to obtain a first synthesis gas; a first synthesis gas shift and cooling step on the first synthesis gas; a separation step for separating the first synthesis gas into a high concentration hydrogen stream and a tail gas stream; a second low pressure steam reforming step performed on the tail gas to obtain a second synthesis gas; a second synthesis gas shift and cooling step on the second synthesis gas; a CO2 removal step performed on the stream of hydrogen and carbon dioxide exiting the second synthesis gas shift and cooling step in order to separate a CO2 stream from a fuel grade hydrogen stream; a step of feeding at least a part of the fuel grade hydrogen stream to the first steam reforming step.