A method of producing phosphoric acid from at least one mineral containing phosphate and an element which is calcium, magnesium, iron, or aluminum. The method includes contacting the at least one mineral (or a combination of them) with a cation exchanger for a time and at a temperature sufficient to yield phosphoric acid from the mineral.

Processes for inhibiting scale produced during wet process phosphoric acid production by adding a scale inhibiting amount of a reagent having at least one amine portion including at least one primary amine, and at least one hydrocarbyl portion having an insolubilizing group attached thereto to at least one stage of a wet process phosphoric acid production process are provided herein.

A chemical phosphoric acid production unit, comprising a reactor for the production of phosphoric acid; a receiving device for receiving phosphogypsum obtained after filtration of phosphoric acid produced in the reactor; and a discharge system for discharging phosphogypsum from the receiving device. The discharge system comprises a chute of which the inlet is located inside the receiving device and arranged communicate with the receiving device, and a flap moveable around an axis of rotation and configured to open according to a predetermined angle corresponding to a predetermined section for the passage of a fraction of phosphogypsum through the inlet of the chute, and to close in order to prevent the passage of phosphogypsum into the chute.

A chemical phosphoric acid production unit, comprising a reactor for the production of phosphoric acid; a receiving device for receiving phosphogypsum obtained after filtration of phosphoric acid produced in the reactor; and a discharge system for discharging phosphogypsum from the receiving device. The discharge system comprises a chute of which the inlet is located inside the receiving device and arranged communicate with the receiving device, and a flap moveable around an axis of rotation and configured to open according to a predetermined angle corresponding to a predetermined section for the passage of a fraction of phosphogypsum through the inlet of the chute, and to close in order to prevent the passage of phosphogypsum into the chute.

A method of recovering phosphoric acid from process water includes directing a process water stream having a pH and a first concentration of phosphoric acid and at least one salt into a vessel, contacting the process water stream with a sorption agent in the vessel, the sorption agent adsorbing phosphoric acid from the process water, withdrawing a first effluent including a first concentration of the at least one salt and a second concentration of phosphoric acid from the vessel, and contacting the sorption agent including the phosphoric acid with water, at least a portion of the phosphoric acid desorbing from the ion exchange media into the water to form a second effluent having a third concentration of phosphoric acid.

A method of recovering phosphoric acid from process water includes directing a process water stream having a pH and a first concentration of phosphoric acid and at least one salt into a vessel, contacting the process water stream with a sorption agent in the vessel, the sorption agent adsorbing phosphoric acid from the process water, withdrawing a first effluent including a first concentration of the at least one salt and a second concentration of phosphoric acid from the vessel, and contacting the sorption agent including the phosphoric acid with water, at least a portion of the phosphoric acid desorbing from the ion exchange media into the water to form a second effluent having a third concentration of phosphoric acid.

A method of recovering phosphoric acid from process water includes directing a process water stream having a pH and a first concentration of phosphoric acid and at least one salt into a vessel, contacting the process water stream with a sorption agent in the vessel, the sorption agent adsorbing phosphoric acid from the process water, withdrawing a first effluent including a first concentration of the at least one salt and a second concentration of phosphoric acid from the vessel, and contacting the sorption agent including the phosphoric acid with water, at least a portion of the phosphoric acid desorbing from the ion exchange media into the water to form a second effluent having a third concentration of phosphoric acid.

A method of recovering phosphoric acid from process water includes directing a process water stream having a pH and a first concentration of phosphoric acid and at least one salt into a vessel, contacting the process water stream with a sorption agent in the vessel, the sorption agent adsorbing phosphoric acid from the process water, withdrawing a first effluent including a first concentration of the at least one salt and a second concentration of phosphoric acid from the vessel, and contacting the sorption agent including the phosphoric acid with water, at least a portion of the phosphoric acid desorbing from the ion exchange media into the water to form a second effluent having a third concentration of phosphoric acid.

Disclosed is a raw material pre-treatment process system suitable for a kiln phosphoric acid process, comprising a carbonaceous reductant, a phosphate ore and a silica pre-treatment system which are independent from one another, outlets of the carbonaceous reductant, phosphate ore pre-treatment system and silica pre-treatment system are all connected to an inner pellet material mixing device via a first delivery device, and outlets of the carbonaceous reductant and the silica pre-treatment system are both additionally connected to a shell material mixing device via a second delivery device. Also disclosed is a raw material pre-treatment process suitable for a kiln phosphoric acid process, i.e. pre-treating carbonaceous reductant, phosphate ore and silica respectively, feeding the carbonaceous reductant powder, phosphate ore powder and silica powder into the inner ball material mixing device for pelletizing, and feeding the carbonaceous reductant and silica into the shell material mixing device for mixing.

A method of producing phosphoric acid from at least one mineral containing phosphate and an element which is calcium, magnesium, iron, or aluminum. The method includes contacting the at least one mineral (or a combination of them) with a cation exchanger for a time and at a temperature sufficient to yield phosphoric acid from the mineral.