Reactors are provided that can include a first set of fluid channels and a second set of fluid channels oriented in thermal contact with the first set of fluid channels. The reactor assemblies can also provide where the channels of either one or both of the first of the set of fluid channels are non-linear. Other implementations provide for at least one of the first set of fluid channels being in thermal contact with a plurality of other channels of the second set of fluid channels. Reactor assemblies are also provided that can include a first set of fluid channels defining at least one non-linear channel having a positive function, and a second set of fluid channels defining at least another non-linear channel having a negative function in relation to the positive function of the one non-linear channel of the first set of fluid channels. Processes for distributing energy across a reactor are provided. The processes can include transporting reactants via a first set of fluid channels to a second set of fluid channels, and thermally engaging at least one of the first set of fluid channels with at least two of the second set of fluid channels.

Reactors are provided that can include a first set of fluid channels and a second set of fluid channels oriented in thermal contact with the first set of fluid channels. The reactor assemblies can also provide where the channels of either one or both of the first of the set of fluid channels are non-linear. Other implementations provide for at least one of the first set of fluid channels being in thermal contact with a plurality of other channels of the second set of fluid channels. Reactor assemblies are also provided that can include a first set of fluid channels defining at least one non-linear channel having a positive function, and a second set of fluid channels defining at least another non-linear channel having a negative function in relation to the positive function of the one non-linear channel of the first set of fluid channels. Processes for distributing energy across a reactor are provided. The processes can include transporting reactants via a first set of fluid channels to a second set of fluid channels, and thermally engaging at least one of the first set of fluid channels with at least two of the second set of fluid channels.

A fuel cell system includes a fuel cell stack, a fuel inlet conduit configured to provide a fuel to a fuel inlet of the fuel cell stack, an electrochemical pump separator containing an electrolyte, a cathode, and a carbon monoxide tolerant anode, a fuel exhaust conduit that operatively connects a fuel exhaust outlet of the fuel cell stack to an anode inlet of the electrochemical pump separator, and a product conduit which operatively connects a cathode outlet of the electrochemical pump separator to the fuel inlet conduit.

A fuel cell system includes a fuel cell stack, a fuel inlet conduit configured to provide a fuel to a fuel inlet of the fuel cell stack, an electrochemical pump separator containing an electrolyte, a cathode, and a carbon monoxide tolerant anode, a fuel exhaust conduit that operatively connects a fuel exhaust outlet of the fuel cell stack to an anode inlet of the electrochemical pump separator, and a product conduit which operatively connects a cathode outlet of the electrochemical pump separator to the fuel inlet conduit.

A method to produce syngas from a feed oil comprising the steps of increasing a pressure of a slurry catalyst; increasing a temperature of the pressurized slurry stream; increasing a pressure of the feed oil; increasing a temperature of the pressurized feed stream; mixing the hot slurry stream and the hot oil stream; increasing a temperature of the mixed stream in a combined heater to produce a hot mixed stream; maintaining upgrading reactions of hydrocarbons in the supercritical reactor to produce a supercritical effluent; reducing a pressure of the supercritical effluent; separating the depressurized effluent in a separator to produce a gas stream; separating the gas stream to produce a light hydrocarbon stream; mixing the light hydrocarbon stream and a catalyst feed; introducing the hot feed to a steam reformer; maintaining water gas shift reactions of the light hydrocarbon gases in the steam reformer to produce a reformer effluent.

A method to produce syngas from a feed oil comprising the steps of increasing a pressure of a slurry catalyst; increasing a temperature of the pressurized slurry stream; increasing a pressure of the feed oil; increasing a temperature of the pressurized feed stream; mixing the hot slurry stream and the hot oil stream; increasing a temperature of the mixed stream in a combined heater to produce a hot mixed stream; maintaining upgrading reactions of hydrocarbons in the supercritical reactor to produce a supercritical effluent; reducing a pressure of the supercritical effluent; separating the depressurized effluent in a separator to produce a gas stream; separating the gas stream to produce a light hydrocarbon stream; mixing the light hydrocarbon stream and a catalyst feed; introducing the hot feed to a steam reformer; maintaining water gas shift reactions of the light hydrocarbon gases in the steam reformer to produce a reformer effluent.

Herein discussed is a tubular comprising: an open end; an opposite closed end; and a mixed conducting membrane in at least a portion of the circumferential surface of the tubular. In an embodiment, the tubular comprises a cathode in contact with one circumferential side of the mixed conducting membrane and an anode in contact with the opposite circumferential side of the mixed conducting membrane. Methods of making and using such a tubular are also discussed herein.

Herein discussed is a tubular comprising: an open end; an opposite closed end; and a mixed conducting membrane in at least a portion of the circumferential surface of the tubular. In an embodiment, the tubular comprises a cathode in contact with one circumferential side of the mixed conducting membrane and an anode in contact with the opposite circumferential side of the mixed conducting membrane. Methods of making and using such a tubular are also discussed herein.

The present invention addresses to catalysts applicable to the conversion of CO to CO.sub.2 and H.sub.2 by the water-gas shift reaction. Such catalysts are made up of iron oxides, zirconium oxides, cerium oxides or a mixture of the same, promoted by platinum (Pt) contents between 0.1 and 0.4% m/m and with a sodium (Na) content below 0.01% m/m, based on the oxidized material. The present invention makes it possible to obtain catalysts with a high dispersion of Pt, with metallic particles of the order of 1 nm and methods of preparation by coprecipitation of soluble salts in aqueous medium using ammonium hydroxide as a precipitating agent.

The present invention addresses to catalysts applicable to the conversion of CO to CO.sub.2 and H.sub.2 by the water-gas shift reaction. Such catalysts are made up of iron oxides, zirconium oxides, cerium oxides or a mixture of the same, promoted by platinum (Pt) contents between 0.1 and 0.4% m/m and with a sodium (Na) content below 0.01% m/m, based on the oxidized material. The present invention makes it possible to obtain catalysts with a high dispersion of Pt, with metallic particles of the order of 1 nm and methods of preparation by coprecipitation of soluble salts in aqueous medium using ammonium hydroxide as a precipitating agent.