A pair of fuel cells are configured as a hydrogen purity monitor. A first cell, acting as a reference cell, is configured to generate electrical current from the electrochemical reaction of hydrogen and oxidant and has a first fuel inlet configured to receive hydrogen from a first hydrogen source. A second fuel cell, acting as a test cell, is configured to generate electrical current from the electrochemical reaction of hydrogen and oxidant and has a second fuel inlet configured to receive hydrogen from a second hydrogen source. A control system is configured to apply an electrical load to each fuel cell and determine an electrical output of each fuel cell. The control system has a comparator for comparing the electrical outputs of the first and second fuel cells and a purity monitor output configured to give an indication of hydrogen purity based on an output of the comparator.

The invention relates to a method for separating off and immobilizing carbon dioxide and/or carbon monoxide from an exhaust gas (18). In the method, a stoichiometric ratio of carbon dioxide to hydrogen, and/or of carbon monoxide to hydrogen, which is suitable for a methanation reaction is set by virtue of a corresponding quantity of hydrogen or alternatively carbon dioxide and/or possibly carbon monoxide being supplied, with an auxiliary gas (24), to the exhaust gas (18). Subsequently, a catalytic reaction is performed in which, as starting products, carbon dioxide and/or carbon monoxide and hydrogen are converted into methane and water. The methane is separated off from the product of the catalytic reaction and is subsequently split into carbon and hydrogen, wherein the carbon takes solid form. The split-off carbon is collected and disposed of.

A method of obtaining purified hydrogen and purified carbon monoxide from crude synthesis gas. A first crude synthesis gas stream is passed through a first separation zone to separate a hydrogen stream from a stream comprising carbon monoxide and methane. The carbon monoxide and methane are subjected to thermal reforming to produce a second crude synthesis gas, which is passed through a second separation zone to separate carbon monoxide from the second crude synthesis gas stream.

A method of obtaining purified hydrogen and purified carbon monoxide from crude synthesis gas. A first crude synthesis gas stream is passed through a first separation zone to separate a hydrogen stream from a stream comprising carbon monoxide and methane. The carbon monoxide and methane are subjected to thermal reforming to produce a second crude synthesis gas, which is passed through a second separation zone to separate carbon monoxide from the second crude synthesis gas stream.

The method for catalytic methanation of synthesis gas includes the following steps: 1) feeding the synthesis gas into the bottom of a reactor of an upward concurrent flow transporting bed so as to adequately mix and preheat with methanation catalyst entering the bottom of the reactor until the activation temperature of the catalyst is reached and then the methanation reaction begins; and 2) after the methanation reaction, immediately passing the product gas and the catalyst grains outputted from the transporting bed into a gas-solid separator to perform a rapid separation so as to obtain the product gas.

A process and a related equipment for making ammonia make-up synthesis gas are disclosed, where: a hydrocarbon feedstock is reformed obtaining a raw ammonia make-up syngas stream; said raw syngas is purified in a cryogenic purification section refrigerated by a nitrogen-rich stream produced in an air separation unit; the nitrogen-rich stream at output of said cryogenic section is further used for adjusting the hydrogen/nitrogen ratio of the purified make-up syngas; an oxygen-rich stream is also produced in said air separation unit and is fed to the reforming section.

Embodiments of the present disclosure are directed to a diesel reformer system comprising: a diesel autothermal reforming unit; a post-reforming unit disposed downstream of the autothermal reforming unit; a heat exchanger disposed downstream of the post-reforming unit; and a desulfurization unit disposed downstream of the heat exchanger.

Embodiments of the present disclosure are directed to a diesel reformer system comprising: a diesel autothermal reforming unit; a post-reforming unit disposed downstream of the autothermal reforming unit; a heat exchanger disposed downstream of the post-reforming unit; and a desulfurization unit disposed downstream of the heat exchanger.

An apparatus for purifying impure hydrogen fuel is described that includes a first chamber and a second chamber. The first chamber is configured to receive impure hydrogen fuel in the form of a first mixture of gases with hydrogen gas and carbon monoxide at the first concentration while the second chamber is configured to receive a second mixture of gases with hydrogen gas at the second concentration. The apparatus also includes a solid-state electrolyte that separates the first chamber and the second chamber and includes an adsorbing catalyst. The apparatus also includes a pair of electrodes installed each in the first chamber and the second chamber to create a potential difference is created across the solid-state electrolyte.

A method of removing CO from a mixture of CO and saturated and unsaturated hydrocarbons CO to CO.sub.2 is provided. In one embodiment, the method is to contact feed stream with an oxygen transfer agent; and then oxidize at least a portion of the CO to CO.sub.2 to produce a stream enriched in CO.sub.2. The saturated and unsaturated hydrocarbons in the feed are not further oxidized during the oxidation. The oxygen transfer agent includes at least one of: i) water; ii) at least one reducible metal oxide; iii) at least one reducible chalcogen; or mixtures thereof. In another embodiment, the CO is converted to methane. The unsaturated hydrocarbons in the feed are not hydrogenated. In both of these alternatives, the CO.sub.2 or methane are then removed. Systems for removing the CO are also provided.