Provided is a method for separating ammonia gas using zeolite membrane having excellent separation stability at a high temperature capable of separating ammonia gas from a mixed gas composed of multiple components including ammonia gas, hydrogen gas, and nitrogen gas to the permeation side with high selectivity and high permeability. Also provided is a method for separating ammonia by selectively permeating ammonia gas from a mixed gas containing at least ammonia gas, hydrogen gas, and nitrogen gas using a zeolite membrane, wherein the ammonia gas concentration in the mixed gas is 1.0% by volume or more.

A system for synthesizing ammonia includes a reactor including an inlet portion, an outlet portion, and an energy source arranged to deliver energy to one or more reactants receivable through the inlet portion of the reactor, and the energy source activatable to reduce nitrogen to ammonia in the presence of hydrogen, at least one hydrogen pump in fluid communication with the outlet portion of the reactor, each hydrogen pump including at least one electrochemical cell, and a recirculation circuit in fluid communication between the at least one hydrogen pump and the inlet portion of the reactor and configured to direct a respective hydrogen stream from each hydrogen pump to the inlet portion of the reactor.

Provided is a method for separating ammonia gas using zeolite membrane having excellent separation stability at a high temperature capable of separating ammonia gas from a mixed gas composed of multiple components including ammonia gas, hydrogen gas, and nitrogen gas to the permeation side with high selectivity and high permeability. Also provided is a method for separating ammonia by selectively permeating ammonia gas from a mixed gas containing at least ammonia gas, hydrogen gas, and nitrogen gas using a zeolite membrane, wherein the ammonia gas concentration in the mixed gas is 1.0% by volume or more.

A system and method for producing ammonia at high conversion rates. The system having a fluidized bed reactor with a fluidized zone with catalyst particles. The fluidized bed reactor is preferably configured to receive a continuous flow of solid sorbent particles, nitrogen, and hydrogen, with the catalyst particles being at least ten times larger than the sorbent particles. The method allows for the nitrogen and hydrogen react on a surface of the catalyst in order to generate ammonia that is adsorbed by the sorbent particles. The method extracts the adsorbed ammonia from the sorbent particles with a sorbent regenerator to product a pure ammonia product.

The present invention is directed to the removal of ammonia from an ammonia reactor product stream. Systems and methods of the present invention enable ammonia to be synthesized and removed using a broader range of process conditions than are possible with current industrial practices. In particular, the systems and methods enable the use of higher temperatures, lower pressures, and higher reactant flows.

A process for the co-production of methanol and ammonia is described comprising the steps of: (a) forming a first synthesis gas stream by reacting a first portion of a hydrocarbon feedstock and steam in a steam reformer, (b) forming a second synthesis gas stream in parallel to the first synthesis gas stream by reacting a second portion of the hydrocarbon feedstock with an oxygen-containing gas and steam in an autothermal reformer, (c) synthesising methanol from a first process gas comprising the first synthesis gas stream, and (d) synthesising ammonia from a second process gas prepared from the second synthesis gas stream, wherein a purge stream containing hydrogen is recovered from the methanol synthesis step (c) and a portion of the purge gas stream is fed to the autothermal reformer and/or the second synthesis gas in step (b).

Provided is a novel production system that does not involve, or can minimize, the transport of liquid ammonia in the production of an organic compound or the production of a microorganism by microbial fermentation. A production system for an organic compound or a microorganism includes: an ammonia synthesis apparatus in which an ammonia-containing gas is synthesized by reaction of a source gas containing hydrogen and nitrogen in the presence of a supported ruthenium catalyst; and a culture apparatus that cultures a microorganism having organic compound productivity using ammonia originating from the ammonia-containing gas obtained by using the ammonia synthesis apparatus.

The present disclosure relates to systems and methods of making ammonia using stable ammonia absorbents. The system and method for producing ammonia, comprises a reactor comprising a catalyst that converts at least a portion of nitrogen feed gas and at least a portion of hydrogen feed gas to ammonia (NH3) forming a reaction mixture comprising the ammonia, unreacted nitrogen, and unreacted hydrogen. An absorber configured to selectively absorb ammonia from the reaction mixture at a temperature of about 180 deg. C. to 330 deg. C. and a pressure of about 1-20 bar, the absorber comprising a solid absorbent. Preferably the solid absorbent is at least one metal halide and a solid support. The unabsorbed ammonium, the unreacted nitrogen, and unreacted hydrogen gas are recycled to the reactor.

Provided is a novel production system that does not involve, or can minimize, the transport of liquid ammonia in the production of an organic compound or the production of a microorganism by microbial fermentation. A production system for an organic compound or a microorganism includes: an ammonia synthesis apparatus in which an ammonia-containing gas is synthesized by reaction of a source gas containing hydrogen and nitrogen in the presence of a supported ruthenium catalyst; and a culture apparatus that cultures a microorganism having organic compound productivity using ammonia originating from the ammonia-containing gas obtained by using the ammonia synthesis apparatus.

Embodiments of the disclosure provide an apparatus and process for producing ammonia. The apparatus includes a reactor having (i) an inlet to receive an inlet gas comprising nitrogen and hydrogen, (ii) a catalyst and an absorbent disposed within an internal volume of the reactor, the catalyst configured to convert the nitrogen and hydrogen to a reaction mixture including ammonia, unreacted nitrogen, and unreacted hydrogen, the absorbent configured to selectively absorb a portion of the ammonia in the reactor during formation of the reaction mixture, and (iii) an outlet to discharge the reaction mixture from the reactor.