This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.

This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.

The present invention provides a new carbon dioxide fixation apparatus. The carbon dioxide fixation apparatus (1) of the present invention includes: a first reaction vessel (10); a carbon dioxide fixing agent feeding unit (110); and a gas-liquid mixing unit. The first reaction vessel (10) can contain a carbon dioxide fixing agent, the carbon dioxide fixing agent feeding unit (110) can feed the carbon dioxide fixing agent into the first reaction vessel (10), and the gas-liquid mixing unit can mix a gas containing carbon dioxide into the carbon dioxide fixing agent.

Embodiments of the disclosure pertain to an apparatus comprising a phase separator configured to separate a mixture comprising (i) water containing NaCl and (ii) oil and/or gas into separate streams comprising the water, the oil (when oil is in the mixture), and the gas (when gas is in the mixture), an electrochemical membrane separation cell configured to separate sodium and chloride ions in the water stream to form a stream comprising a first sodium hydroxide solution and a stream comprising (i) hydrochloric acid and/or (ii) chlorine gas, a compressor configured to compress a gas containing CO.sub.2, a spray dryer configured to mix aqueous NaOH and the compressed gas to form sodium carbonate, and a cyclone separator configured separate the sodium carbonate from any excess components of the aqueous NaOH and/or the compressed gas.

The present disclosure provides systems for carbon capture in combination with production of one or more industrially useful materials. The disclosure also provides methods for carrying out carbon capture in combination with an industrial process. In particular, carbon capture can include carrying out calcination in a reactor, separation of carbon dioxide rich flue gases from industrially useful products, and capture of at least a portion of the carbon dioxide for sequestration of other use, such as enhanced oil recovery.

The disclosure provides seven integrated methods for the chemical sequestration of carbon dioxide (CO.sub.2), nitric oxide (NO), nitrogen dioxide (NO.sub.2) (collectively NO.sub.x, where x=1, 2) and sulfur dioxide (SO.sub.2) using closed loop technology. The methods recycle process reagents and mass balance consumable reagents that can be made using electrochemical separation of sodium chloride (NaCl) or potassium chloride (KCl). The technology applies to marine and terrestrial exhaust gas sources for CO.sub.2, NOx and SO.sub.2. The integrated technology combines compatible and green processes that capture and/or convert CO.sub.2, NOx and SO.sub.2 into compounds that enhance the environment, many with commercial value.

The disclosure provides seven integrated methods for the chemical sequestration of carbon dioxide (CO.sub.2), nitric oxide (NO), nitrogen dioxide (NO.sub.2) (collectively NO.sub.x, where x=1, 2) and sulfur dioxide (SO.sub.2) using closed loop technology. The methods recycle process reagents and mass balance consumable reagents that can be made using electrochemical separation of sodium chloride (NaCl) or potassium chloride (KCl). The technology applies to marine and terrestrial exhaust gas sources for CO.sub.2, NOx and SO.sub.2. The integrated technology combines compatible and green processes that capture and/or convert CO.sub.2, NOx and SO.sub.2 into compounds that enhance the environment, many with commercial value.

A method for generating a carboxylic acid from carbon dioxide (CO.sub.2), the method includes (a) feeding a gas stream having the CO.sub.2 to a first reactor having a base (MOH) to produce bicarbonate (MHCO.sub.3) and (b) feeding the MHCO.sub.3 generated in the first reactor to a second reactor disposed downstream from the first reactor. The second reactor includes a catalyst. The method also includes (c) contacting the MHCO.sub.3 with hydrogen gas in the presence of the catalyst in the second reactor to produce formate (HCOOM) and (d) electrolysing an aqueous solution of a metal halide (MCl) in a chloro-alkali electrolysis reactor fluidly coupled to the first reactor, the second reactor, or both to produce at least a portion of the MOH, the hydrogen gas and Cl.sub.2. The portion of the MOH is used in step (a) and the carboxylic acid is formic acid (HCOOH).

A method for generating a carboxylic acid from carbon dioxide (CO.sub.2), the method includes (a) feeding a gas stream having the CO.sub.2 to a first reactor having a base (MOH) to produce bicarbonate (MHCO.sub.3) and (b) feeding the MHCO.sub.3 generated in the first reactor to a second reactor disposed downstream from the first reactor. The second reactor includes a catalyst. The method also includes (c) contacting the MHCO.sub.3 with hydrogen gas in the presence of the catalyst in the second reactor to produce formate (HCOOM) and (d) electrolysing an aqueous solution of a metal halide (MCl) in a chloro-alkali electrolysis reactor fluidly coupled to the first reactor, the second reactor, or both to produce at least a portion of the MOH, the hydrogen gas and Cl.sub.2. The portion of the MOH is used in step (a) and the carboxylic acid is formic acid (HCOOH).

Carbonate salts are efficiently produced from carbon dioxide in exhaust gas. The method for producing carbonate salts includes an atomizing step that forms an aqueous alkaline solution mist with an atomizer; a mixing step that mixes exhaust gas with the aqueous alkaline solution mist produced in the atomizing step to absorb exhaust gas carbon dioxide in the mist and combine mist positive ions with the carbon dioxide to produce mist that contains carbonate salt; and a separating step that separates the mist that contains carbonate salt produced in the mixing step from exhaust gas.