Patent classifications
C01F7/57
METHOD FOR CONTINUOUSLY PRODUCING POLYALUMINUM CHLORIDE FORM ALUMINUM SLAG
Disclosed is a method for continuously producing polyaluminum chloride from aluminum slag, comprising: blending the aluminum slag with water into a slurry in a mixing tank; pumping the slurry and a sodium hydroxide solution into a first mixing reactor; introducing the mixture obtained in the first mixing reactor into a second mixing reactor and pumping hydrochloric acid into the second mixing reactor; and filtering the resulting mixture and allowing filtrate for ripening, polymerization and sedimentation to obtain liquid polyaluminum chloride; wherein each of the reactors is pipeline-shaped, arranged horizontally and provided with a spiral conveyor shaft inside which is arranged horizontally and configured to stir and convey the mixture in a pipeline. This method realizes a continuous treatment of aluminum slag together with a continuous recovery of ammonia nitrogen and produces PAC, thereby achieving resourceful utilization and improved operability.
METHOD FOR CONTINUOUSLY PRODUCING POLYALUMINUM CHLORIDE FORM ALUMINUM SLAG
Disclosed is a method for continuously producing polyaluminum chloride from aluminum slag, comprising: blending the aluminum slag with water into a slurry in a mixing tank; pumping the slurry and a sodium hydroxide solution into a first mixing reactor; introducing the mixture obtained in the first mixing reactor into a second mixing reactor and pumping hydrochloric acid into the second mixing reactor; and filtering the resulting mixture and allowing filtrate for ripening, polymerization and sedimentation to obtain liquid polyaluminum chloride; wherein each of the reactors is pipeline-shaped, arranged horizontally and provided with a spiral conveyor shaft inside which is arranged horizontally and configured to stir and convey the mixture in a pipeline. This method realizes a continuous treatment of aluminum slag together with a continuous recovery of ammonia nitrogen and produces PAC, thereby achieving resourceful utilization and improved operability.
High purity aluminum oxide via electrodialysis
The invention describes methods for the production of a high purity aluminum salt solution via electrodialysis, and ultimately, the conversion of the high purity aluminum salt to high purity aluminum oxide.
Concentrated aqueous solutions of aluminum chlorohydrate monohydrate
A system and method for producing commercial strength solutions of aluminum chlorohydrate are provided. The method includes providing aluminum chlorohydrate monohydrate (ACHMH) powder, heating water to at least 120 F. and less than 200 F., and dissolving at least a portion of the ACHMH powder into the heated water to form the solution of aluminum chlorohydrate. The produced solution of aluminum chlorohydrate from the ACHMH powder has an aluminum oxide concentration ranging from about 18 wt % to about 27 wt %, has a basicity ranging from greater than 74% and less than 83%, and has a freezing point ranging from about 10 F. to about 16 F. The solution may also have an iron content of between about 0 to about 70 ppm as Fe.
DEVICES AND METHODS OF USING SMALL FORM ALUMINUM IN CONSECUTIVE BATCH ALUMINUM CHLOROHYDRATE PROCESSES
A method of producing aluminum chlorohydrate comprises adding small form aluminum metal pellets to a reactant receiving space of a reactor tank to form a pellet bed; adding aqueous hydrochloric acid to the reactant receiving space of the reactor tank; and continuously circulating the aqueous hydrochloric acid through the pellet bed. In some embodiments, the continuously circulating aqueous hydrochloric acid dispels reaction gases from the pellet bed. Methods described herein can, in some cases, further comprise consecutively adding additional small form aluminum metal pellets to the reactant receiving space of the reactor tank as the small form aluminum metal pellets are consumed in the pellet bed.
HIGH PURITY ALUMINUM OXIDE VIA ELECTRODIALYSIS
The invention describes methods for the production of a high purity aluminum salt solution via electrodialysis, and ultimately, the conversion of the high purity aluminum salt to high purity aluminum oxide.
Anhydrous antiperspirant compositions
Anhydrous antiperspirant stick or soft solid composition comprising an antiperspirant active system, thickening agent, and non-aqueous carrier oil, characterised in that the particulate antiperspirant active system comprises an aluminium sesequichlorohydrate of formula Al.sub.2(OH).sub.4.4Cl.sub.1.6 to Al.sub.2(OH).sub.4.9Cl.sub.1.1 activated with a water soluble calcium salt.
Method of making high performance activated aluminum sesquichlorohydrate powders
Activated aluminum sesquichlorohydrate (AASCH) powders prepared by (a) diluting the concentrated aluminum sesquichlorohydrate (ASCH) solution to from about 10% to about 25% by weight, (b) heating the diluted solution to obtain a Band III polymer concentration of at least about 20% and a Band IV polymer concentration of at least about 15%, (c) drying the heated solution to powders, and (d) optionally screen or light mill the powders to free flowing spherical particles are disclosed.
ANHYDROUS ANTIPERSPIRANT COMPOSITIONS
Anhydrous antiperspirant stick or soft solid composition comprising an antiperspirant active system, thickening agent, and non-aqueous carrier oil, characterised in that the particulate antiperspirant active system comprises an aluminium sesequichlorohydrate of formula Al.sub.2(OH).sub.4.4Cl.sub.1.6 to Al.sub.2(OH).sub.4.9Cl.sub.1.1 activated with a water soluble calcium salt.
Anhydrous antiperspirant compositions
Anhydrous antiperspirant stick or soft solid composition comprising an antiperspirant active system, thickening agent, and non-aqueous carrier oil, characterized in that the particulate antiperspirant active system comprises an aluminium sesequichlorohydrate of formula Al.sub.2OH.sub.4.4Cl.sub.1.6 to Al.sub.2OH.sub.4.9Cl.sub.1.1 activated with a water soluble calcium salt.