Patent classifications
C01G23/001
Nanostructured titanic acid salts and preparation process and use thereof
The present invention provides a nanostructured titanic acid salt and a preparation process and use thereof. The process comprises preparing a dispersion containing titanium peroxy complex; slowly adding a metal compound to the dispersion containing the titanium peroxy complex to form a solution; adding an alcohol to the solution under normal temperature and normal pressure to produce the nanostructured titanic acid salt precursor precipitate in the solution, and separating the precipitate to obtain the titanic acid salt precursor; drying the precursor, and then heat treating it to obtain the nanostructured titanic acid salt product. The present invention provides a process for preparing a titanic acid salt with simple preparation process, easy control for process parameters and easy large-scale industrial production.
PREPARATION METHOD OF A NANOTUBE HIERARCHICALLY STRUCTURED LITHIUM TITANATE AND USE AND PRODUCT THEREOF
A preparation method of a nanotube hierarchically structured lithium titanate includes the steps of: S1. dispersing a titanium source into an aqueous solution containing lithium hydroxide and hydrogen peroxide and stirring to obtain a mixed solution; S2. subjecting the mixed solution obtained in step S1 to a reaction by heating to obtain a precursor having a nanowire-like structure; S3. subjecting the precursor having a nanowire-like structure obtained in step S2 to separation and drying; S4. subjecting the precursor having a nanowire-like structure after separation and drying to a low-temperature annealing treatment; S5. subjecting the precursor having a nanowire-like structure after the low-temperature annealing treatment to a liquid thermal reaction to obtain the nanotube hierarchically structured lithium titanate. The method includes a simple process and easily controllable process parameters, and may be easily scaled-up for industrial production.
ELECTRODE FOR A SECONDARY BATTERY, SECONDARY BATTERY, BATTERY PACK AND VEHICLE
An electrode for a secondary battery comprises a current collector; and an active material-containing layer has active materials which comprise titanium-containing composite oxide having an orthorhombic crystal structure and represented by a general formula Li.sub.2+aM1.sub.2bTi.sub.6cM2.sub.dO.sub.14+;
wherein the active material-containing layer has intensity ratio Ia/Ib in an X-ray diffraction pattern of the active material-containing layer, the Ia and the Ib are obtained by powder X-ray diffraction method using Cu-K ray, the intensity ratio is within a range of 0.5Ia/Ib2, the Ia is the strongest intensity of a diffraction peak among diffraction peaks appearing within a range of 42244, and the Ib is the strongest intensity of a diffraction peak among diffraction peaks appearing within a range of 44<248.
(M1 is at least one selected from the group consisting of Sr, Ba, Ca, Mg, Na, Cs, Rb and K, M2 is at least one selected from the group consisting of Zr, Sn, V, Nb, Ta, Mo, W, Y, Fe, Co, Cr, Mn, Ni and Al a is within a range of 0a6 b is within a range of 0b<2 c is within a range of 0c<6 d is within a range of 0d<6 is within a range of 0.50.5.)
Preparation method for directly synthesizing titanium dioxide from titanium-rich organic phase prepared from ilmenite
The present invention relates to a method for directly synthesizing titanium dioxide from a titanium-rich organic phase prepared from ilmenite, and more particularly to a method in which a titanium-rich acidolysis solution is obtained by an efficient ore dissolving technology, titanium ions are transferred to the organic phase by means of an effective titanium extractant to obtain a high-purity and titanium-rich organic phase, and then the titanium dioxide is directly synthesized in the organic phase. With this method, the dissolution rate of ilmenite can be effectively improved, the process flow is shortened and production costs are reduced, and titanium dioxide with high yield and high quality is obtained.
PREPARATION METHOD FOR DIRECTLY SYNTHESIZING TITANIUM DIOXIDE FROM TITANIUM-RICH ORGANIC PHASE PREPARED FROM ILMENITE
The present invention relates to a method for directly synthesizing titanium dioxide from a titanium-rich organic phase prepared from ilmenite, and more particularly to a method in which a titanium-rich acidolysis solution is obtained by an efficient ore dissolving technology, titanium ions are transferred to the organic phase by means of an effective titanium extractant to obtain a high-purity and titanium-rich organic phase, and then the titanium dioxide is directly synthesized in the organic phase. With this method, the dissolution rate of ilmenite can be effectively improved, the process flow is shortened and production costs are reduced, and titanium dioxide with high yield and high quality is obtained.
EXTRACTION OF LITHIUM FROM BRINE
A process for the extraction of lithium from a brine, wherein a solution of the brine is contacted with a titanate adsorbent such that lithium ions are adsorbed thereon whilst rejecting substantially all other cations. The adsorbent is provided in the form of either a hydrated titanium dioxide or a sodium titanate. The process in turn produces a substantially pure lithium chloride solution
Method for preparing nanometer titanium dioxide
The present invention belongs to the field of preparation technique of inorganic functional material and provides a method for preparing nanometer titanium dioxide which comprises the following steps: (1) dissolving ilmenite powder using hydrochloric acid to obtain a raw ore solution; (2) eliminating the iron element in the raw ore solution to obtain a final solution containing titanium ions; (3) heating the final solution for hydrolysis to obtain a hydrolyzed product containing titanium dioxide; and (4) calcining the obtained hydrolyzed product to obtain nanometer titanium dioxide. The present invention has the advantages that the raw materials can be easily obtained, the energy consumption is low, both rutile type titanium dioxide and anatase type titanium dioxide can be produced, and the product has high purity, small particle diameter, narrow particle diameter distribution and good dispersibility.
Method for Preparing Nanometer Titanium Dioxide
The present invention belongs to the field of preparation technique of inorganic, functional material and provides a method for preparing nanometer titanium dioxide which comprises the following steps: (1) dissolving ilmenite powder using hydrochloric acid to obtain a raw ore solution; (2) eliminating the iron element in the raw ore solution to obtain a final solution containing titanium ions (3) heating the final solution for hydrolysis to obtain a hydrolyzed product containing titanium dioxide; and (4) calcining the obtained hydrolyzed product to obtain nanometer titanium dioxide. The present invention has the advantages that the raw materials can be easily obtained, the energy consumption is low, both rutile type titanium dioxide and anatase type titanium dioxide can be produced, and the product has high purity, small particle diameter, narrow particle diameter distribution and good dispersibility.
Processes for treating red mud
There are provided processes for treating red mud. For example, the processes can comprise leaching red mud with HCl so as to obtain a leachate comprising ions of a first metal (for example aluminum) and a solid, and separating said solid from said leachate. Several other metals can be extracted from the leachate (Fe, Ni, Co, Mg, rare earth elements, rare metals, etc.). Various other components can be extracted from solid such as TiO.sub.2, SiO.sub.2 etc.
A PREPARATION PROCESS FOR MONOCLINIC TITANIUM DIOXIDE
A method for preparing titanium dioxide that includes the steps of providing at least one titanium precursor: providing one or more potassium precursors: mixing the at least one titanium precursor with the one or more potassium precursors to form a mixture: wherein the mixture has a potassium to titanium (K/Ti) molar ratio of 2.0/4.0<K/Ti<2.0/2.4; sintering the mixture at a temperature in the range of 750 C. to 900 C. for a predetermined time to form a powder: soaking the heated powder in an acidic solution: collecting and drying the acid-soaked powder: and treating the collected powder thermally at a temperature in the range of 300 C. to 500 C. for a predetermined time to form the TiO.sub.2. The titanium oxide formed has a monoclinic crystal structure. TiO.sub.2(B), as its major crystal phase with a mass percentage that is >50% of the overall mas of the TiO.sub.2.