Methods of sulfurizing metal containing particles in the absence of hydrogen are described. One method includes contacting a bed of metal containing particles with a gaseous stream comprising hydrogen sulfide and inert gas under reaction conditions sufficient to produce sulfided metal containing particles. The gaseous stream is introduced into a vertical reactor at an inlet positioned at the bottom portion of the reactor and any unreacted hydrogen sulfide and inert gas is removed at an outlet positioned above the inlet. The sulfided metal containing particles can be removed from the reactor and stored.

Disclosed are beta-type active zinc sulfide and a preparation method therefor. The method includes: adding an oil phase containing styrene monomers into a water phase containing a pore-forming agent, a surfactant, a Zn salt, a complexing agent, a sulfur source and a water-soluble initiator, conducting mixing and emulsification, introducing metal elements, dissolving polystyrene of microspheres prepared through reaction in tetrahydrofuran, and then conducting calcination, pickling and activation to obtain the beta-type active zinc sulfide. The zinc sulfide microspheres prepared by the present invention are beta-type, and have excellent photoelectric properties and broad application prospects.

Disclosed is a method for synthesizing copper sulfide nano powder using plasma synthesis. The method comprises providing a copper compound to a plasma apparatus, adding a sulfur, and performing a plasma process with respect to the copper compound and the sulfur for synthesizing a nano copper sulfide.

Disclosed is a method for synthesizing copper sulfide nano powder using plasma synthesis. The method comprises providing a copper compound to a plasma apparatus, adding a sulfur, and performing a plasma process with respect to the copper compound and the sulfur for synthesizing a nano copper sulfide.

Proposed are copper sulfide nanoparticles having a core-shell structure included in a coating composition for blocking near-infrared light, and a method of manufacturing the same. More particularly, a method of manufacturing copper sulfide nanoparticles having a core-shell structure includes manufacturing CuS nanoparticles, manufacturing Cu.sub.2-xS nanoparticles by heating a mixed solution of the CuS nanoparticles, a reducing agent, and a solvent, and manufacturing Cu.sub.2-xS@Cu.sub.2-yO core-shell nanoparticles by heating a mixed solution of the Cu.sub.2-xS nanoparticles, an oxidizing agent, and a solvent.

The present disclosure relates to a sodium-ion storage material and an electrode material for a sodium-ion battery, an electrode material for a seawater battery, an electrode for a sodium-ion battery, an electrode for a seawater battery, a sodium-ion battery, and a seawater battery, which include the sodium-ion storage material. Specifically, the sodium-ion storage material may include one or more materials selected from the group consisting of Cu.sub.xS, FeS, FeS.sub.2, Ni.sub.3S, NbS.sub.2, SbO.sub.x, SbS.sub.x, SnS and SnS.sub.2, wherein 0<x≤2. When the sodium-ion storage material according to the present disclosure is used, it may exhibit high discharge capacity, and when the sodium-ion storage material is applied to a sodium-ion battery which is a secondary battery, it may exhibit excellent charge/discharge cycle characteristics.

The present disclosure relates to a sodium-ion storage material and an electrode material for a sodium-ion battery, an electrode material for a seawater battery, an electrode for a sodium-ion battery, an electrode for a seawater battery, a sodium-ion battery, and a seawater battery, which include the sodium-ion storage material. Specifically, the sodium-ion storage material may include one or more materials selected from the group consisting of Cu.sub.xS, FeS, FeS.sub.2, Ni.sub.3S, NbS.sub.2, SbO.sub.x, SbS.sub.x, SnS and SnS.sub.2, wherein 0<x≤2. When the sodium-ion storage material according to the present disclosure is used, it may exhibit high discharge capacity, and when the sodium-ion storage material is applied to a sodium-ion battery which is a secondary battery, it may exhibit excellent charge/discharge cycle characteristics.

A method of removing hydrogen peroxide from sulfuric acid includes the following steps: First step of pouring the sulfuric acid having 0.1 wt % to 10 wt % of hydrogen peroxide into a vessel. Second step of adding a catalyst containing copper and a copper compound to the vessel to undergo a reaction with the sulfuric acid to remove the hydrogen peroxide from the sulfuric acid, to generate heat, and to generate metal ions in the sulfuric acid. Third step of activating a cooling device to cool the vessel to a predetermined temperature range. Fourth step of adding hydrogen sulfide to the vessel to undergo a reaction with the metal ions to generate metallic sulfide and metal free sulfuric acid. Fifth step of purifying the metallic sulfide and the metal free sulfuric acid to obtain purified metallic sulfide and purified sulfuric acid as products.

A method of removing hydrogen peroxide from sulfuric acid includes the following steps: First step of pouring the sulfuric acid having 0.1 wt % to 10 wt % of hydrogen peroxide into a vessel. Second step of adding a catalyst containing copper and a copper compound to the vessel to undergo a reaction with the sulfuric acid to remove the hydrogen peroxide from the sulfuric acid, to generate heat, and to generate metal ions in the sulfuric acid. Third step of activating a cooling device to cool the vessel to a predetermined temperature range. Fourth step of adding hydrogen sulfide to the vessel to undergo a reaction with the metal ions to generate metallic sulfide and metal free sulfuric acid. Fifth step of purifying the metallic sulfide and the metal free sulfuric acid to obtain purified metallic sulfide and purified sulfuric acid as products.

Methods of sulfurizing metal containing particles in the absence of hydrogen are described. One method includes contacting a bed of metal containing particles with a gaseous stream comprising hydrogen sulfide and inert gas under reaction conditions sufficient to produce sulfided metal containing particles. The gaseous stream is introduced into a vertical reactor at an inlet positioned at the bottom portion of the reactor and any unreacted hydrogen sulfide and inert gas is removed at an outlet positioned above the inlet. The sulfided metal containing particles can be removed from the reactor and stored.