A nuclear fuel powder production plant comprises a conversion installation (2) for the conversion of uranium hexafluoride (UF.sub.6) into uranium dioxide (UO.sub.2) having a hydrolysis reactor (4) for the conversion of UF.sub.6 into uranium oxyfluoride powder (UO.sub.2F.sub.2) and a pyrohydrolysis furnace (6) for converting the UO.sub.2F.sub.2 powder into UO.sub.2 powder. The nuclear fuel powder production plant also includes a packaging unit (20) for the UO.sub.2 powder comprising a filling station (22) having a chamber (26) for receiving a container (24) to be filled, a filling duct (28) supplied from the furnace (6) and a suction system (32) comprising a suction ring (34) disposed at the outlet (30) of the filling duct (28) for sucking an annular air flow (A) around a stream (P) of UO.sub.2 powder falling from the outlet (30) from the filling duct (28) into the container (24).

A nuclear fuel powder production plant comprises a conversion installation (2) for the conversion of uranium hexafluoride (UF.sub.6) into uranium dioxide (UO.sub.2) having a hydrolysis reactor (4) for the conversion of UF.sub.6 into uranium oxyfluoride powder (UO.sub.2F.sub.2) and a pyrohydrolysis furnace (6) for converting the UO.sub.2F.sub.2 powder into UO.sub.2 powder. The nuclear fuel powder production plant also includes a packaging unit (20) for the UO.sub.2 powder comprising a filling station (22) having a chamber (26) for receiving a container (24) to be filled, a filling duct (28) supplied from the furnace (6) and a suction system (32) comprising a suction ring (34) disposed at the outlet (30) of the filling duct (28) for sucking an annular air flow (A) around a stream (P) of UO.sub.2 powder falling from the outlet (30) from the filling duct (28) into the container (24).

An installation for the conversion of uranium hexafluoride (UF.sub.6) to uranium dioxide (UO.sub.2) comprises a hydrolysis reactor (4) for the conversion of UF.sub.6 into uranium oxyfluoride powder (UO.sub.2F.sub.2), a pyrohydrolysis furnace (6) for converting the UO.sub.2F.sub.2 powder supplied by the reactor (4) into UO.sub.2 powder, a supply device (8) comprising reagent injection ducts (10) for the injection of UF.sub.6, water vapor or H.sub.2, and a control system (16) designed to control the supply device (8) so as to supply at least one of the reagent injection ducts (10) with a neutral gas during a shut-down or start-up phase of the conversion installation.

An installation for the conversion of uranium hexafluoride (UF.sub.6) to uranium dioxide (UO.sub.2) comprises a hydrolysis reactor (4) for the conversion of UF.sub.6 into uranium oxyfluoride powder (UO.sub.2F.sub.2), a pyrohydrolysis furnace (6) for converting the UO.sub.2F.sub.2 powder supplied by the reactor (4) into UO.sub.2 powder, a supply device (8) comprising reagent injection ducts (10) for the injection of UF.sub.6, water vapor or H.sub.2, and a control system (16) designed to control the supply device (8) so as to supply at least one of the reagent injection ducts (10) with a neutral gas during a shut-down or start-up phase of the conversion installation.

A uranium oxide fuel pellet having an inner region and an outer rim region about the inner region, and that the fuel pellet is cylindrical and the inner region and outer rim region are coaxial cylindrical regions. The outer rim region has an excess of oxygen in comparison to the inner region, wherein high burnup structure (HBS) formation will be suppressed or delayed. Preferably, the excess oxygen is obtained by a chemical treatment by immersing the pellet in hydrogen peroxide (H.sub.2O.sub.2) or potassium permanganate (KMnO.sub.4) in solution.

A uranium oxide fuel pellet having an inner region and an outer rim region about the inner region, and that the fuel pellet is cylindrical and the inner region and outer rim region are coaxial cylindrical regions. The outer rim region has an excess of oxygen in comparison to the inner region, wherein high burnup structure (HBS) formation will be suppressed or delayed. Preferably, the excess oxygen is obtained by a chemical treatment by immersing the pellet in hydrogen peroxide (H.sub.2O.sub.2) or potassium permanganate (KMnO.sub.4) in solution.

Described are methods for the recovery of uranium from uranium hexafluoride dissolved directly into ionic liquids.

Described are methods for the recovery of uranium from uranium hexafluoride dissolved directly into ionic liquids.

A conversion process for converting uranium hexafluoride into uranium dioxide includes the steps of hydrolysis of UF6 to uranium oxyfluoride (UO.sub.2F.sub.2) in a hydrolysis reactor (4) by reaction between gaseous UF6 and dry water vapour injected into the reactor (4), pyrohydrolysis of UO.sub.2F.sub.2 to UO.sub.2 in a pyrohydrolysis furnace (6) by reacting UO.sub.2F.sub.2 with dry steam and gaseous hydrogen (H.sub.2) injected into the furnace (6), extracting excess gas in the reactor (4) via a collecting device (50) comprising several filters (52), periodically cleaning the filters (52) by injecting a neutral gas into the filters (52) from the outside to the inside of the reactor (4) to remove powder stuck on the filters (52), and measuring the relative pressure in the reactor (4). The conversion method further includes carrying out point cleaning of the filters (52) when the relative pressure in the reactor (4) exceeds a predetermined point cleaning threshold.

A conversion process for converting uranium hexafluoride into uranium dioxide includes the steps of hydrolysis of UF6 to uranium oxyfluoride (UO.sub.2F.sub.2) in a hydrolysis reactor (4) by reaction between gaseous UF6 and dry water vapour injected into the reactor (4), pyrohydrolysis of UO.sub.2F.sub.2 to UO.sub.2 in a pyrohydrolysis furnace (6) by reacting UO.sub.2F.sub.2 with dry steam and gaseous hydrogen (H.sub.2) injected into the furnace (6), extracting excess gas in the reactor (4) via a collecting device (50) comprising several filters (52), periodically cleaning the filters (52) by injecting a neutral gas into the filters (52) from the outside to the inside of the reactor (4) to remove powder stuck on the filters (52), and measuring the relative pressure in the reactor (4). The conversion method further includes carrying out point cleaning of the filters (52) when the relative pressure in the reactor (4) exceeds a predetermined point cleaning threshold.