Disclosed is a lithium complex oxide and method of manufacturing the same, more particularly, a lithium complex oxide effective in improving the characteristics of capacity, resistance, and lifetime with reduced residual lithium and with different interplanar distances of crystalline structure between a primary particle locating in a internal part of secondary particle and a primary particle locating on the surface part of the secondary particle, and a method of preparing the same.

The present application discloses a composite graphite material, a secondary battery, an apparatus and a preparation method thereof. The composite graphite material includes a core material and a coating layer coating at least a part of the surface of the core material, the core material including graphite; wherein the absolute value K of zeta potential of the composite graphite material in deionized water with a pH of 7 is at least 20 mV. The use of the composite graphite material provided by the present application can improve the cohesion and bonding force of the negative electrode plate, thereby reducing the cyclic expansion of the secondary battery.

The present disclosure generally relates to compositions comprising substrate-free 2D tellurene crystals, and the method of making and using the substrate-free 2D tellurene crystals. The 2D tellurene crystals of the present disclosure are characterized by an X-ray diffraction pattern (CuKα radiation, λ=1.54056 A) comprising a peak at 23.79 (2θ±0.1°) and optionally one or more peaks selected from the group consisting of 41.26, 47.79, 50.41, and 64.43 (2θ±0.1°).

The present invention relates to elastomer compositions comprising adducts between compounds of formula (I) preferably derived from natural sources such as mucic, pyromucic, glucaric, glycaric, galactaric, muconic acid and/or linear derivatives thereof containing ester or amide groups and/or cyclic derivatives thereof with heteroatoms in the ring, such as oxygen or nitrogen, and carbon allotropes in which the carbon is sp.sup.2 hybridized, such as for example carbon nanotubes, graphene or nanographites, carbon black.

An object of the present invention is to provide carbon-coated Si—C composite particles capable of maintaining a high Si utilization rate and suppressing deterioration of initial coulombic efficiency due to oxidation over time of a lithium-ion secondary battery.

The carbon-coated Si—C composite particles of the present invention includes Si—C composite particles containing a carbon material and silicon; and a carbonaceous layer present on surfaces of the Si—C composite particles, wherein the carbon coverage thereof is 70% or more, wherein the BET specific surface area is 200 m.sup.2/g or less; wherein R value (I.sub.D/I.sub.G) is 0.30 or more and 1.10 or less and I.sub.Si/I.sub.G is 0.15 or less, when the peak attributed to Si is present at 450 to 495 cm.sup.−1 and the intensity of the peak is defined as I.sub.Si, in Raman spectrum of the carbon-coated Si—C composite particles: and wherein the full width at half maximum of the peak of a 111 plane of Si is 3.00 deg. or more, and (peak intensity of a 111 plane of SiC)/(peak intensity of the 111 plane of Si) is 0.01 or less, in the XRD pattern measured by powder XRD using a Cu-Kα ray of the carbon-coated Si—C composite particles.

One aspect of the present invention is a solid electrolyte containing lithium, phosphorus, sulfur, halogen, and tin as constituent elements and having a crystal structure.

Several variations of synthetic carbon materials are disclosed. The materials can assume a variety of properties, including high electrical conductivity. The materials also can have favorable structural and mechanical properties. They can form gas impenetrable barriers, form insulating structures, and can have unique optical properties.

The invention relates to a process for the preparation of a vanadium-carbon phosphate composite material, a vanadium-carbon phosphate composite material obtained according to the process, and to the uses of the composite material, especially as a precursor for the synthesis of electrochemically-active materials, electrode or active anode material.

A dielectric material includes a main component represented by (Ba.sub.1-xCa.sub.x)(Ti.sub.1-yZr.sub.y)O.sub.3, (Ba.sub.1-xCa.sub.x)(Ti.sub.1-ySn.sub.y)O.sub.3, or (Ba.sub.1-xCa.sub.x)(Ti.sub.1-yHf.sub.y)O.sub.3 (0≤x≤1 and 0≤y≤0.05) and a subcomponent. When an angle corresponding to a maximum peak is referred to as θ.sub.0 and angles corresponding to a full width at half maximum (FWHM) are respectively referred to as θ.sub.1 and θ.sub.2 (θ1<θ2) in the peaks of (002) and (200) plane of an x-ray diffraction (XRD) pattern using Cu Kα1 radiation (wavelength Δ=1.5406 Å), (θ.sub.2−θ.sub.0)/(θ.sub.0−θ.sub.1) is greater than 0.54 to 1.0 or less.

A method according to an embodiment of the present invention is for preparing powdered composite carbide of tungsten and titanium in which tungsten trioxide (WO.sub.3), titanium dioxide (TiO.sub.2) and carbon (C), each being in powdered form are mixed with a reducing agent powder to obtain a reaction mixture in the mixing step, followed by the synthesis step in which the reaction mixture is heated at a temperature of about 600° C. to 1200° C. to obtain the reaction products, and the washing step in which the reaction products are washed with water. The method for preparing tungsten titanium carbide powder is capable of carrying out both reduction and carburizing at a relatively low temperature and affords homogeneity in shape and particle size in the resultant composite carbide.