Patent classifications
C01P2006/16
METHOD FOR PRODUCING AN AEROGEL MATERIAL
The invention relates to a method for producing an aerogel material with a porosity of at least 0.55 and an average pore size of 10 nm to 500 nm, having the following steps: a) preparing and optionally activating a sol; b) filling the sol into a casting mold (10); c) gelling the sol, whereby a gel is produced, and subsequently aging the gel; at least one of the following steps d) and e), d) substituting the pore liquid with a solvent; e) chemically modifying the aged and optionally solvent-substituted gel (6) using a reaction agent; followed by f) drying the gel, whereby the aerogel material is formed. The casting mold used in step b) is provided with a plurality of channel-forming elements (2) which are designed such that the sol filled into the casting mold lies overall at a maximum distance X from a channel-forming element over a specified minimum length L defined in the channel direction of the elements, with the proviso that X<15 mm and L/X>3.
Solidified porous carbon material and method of manufacturing the same
A solidified porous carbon material uses a plant-derived material as a raw material, a bulk density of the solidified porous carbon material is in the range of 0.2 to 0.4 grams/cm.sup.3, preferably, 0.3 to 0.4 grams/cm.sup.3. A value of a cumulative pore volume in the range of 0.05 to 5 μm in pore size based on a mercury press-in method is in the range of 0.4 to 1.2 cm.sup.3, preferably, 0.5 to 1.0 cm.sup.3 per 1 gram of the solidified porous carbon material.
FERRITE PARTICLES PROVIDED WITH OUTER SHELL STRUCTURE FOR CATALYST SUPPORTING MEDIUM
An object of the present invention is to provide ferrite particles for supporting a catalyst having a small apparent density, various properties are maintained in a controllable state and a specified volume is filled with a small weight, and a catalyst using the ferrite particles for supporting a catalyst. To achieve the object, ferrite particles for supporting a catalyst provided with an outer shell structure containing Ti oxide, a catalyst using the ferrite particles for supporting a catalyst are employed.
CARBON MATERIAL, METHOD FOR PRODUCING SAME, AND USE FOR SAME
A non-flaky carbon material having specific optical structures, wherein the ratio between the peak intensity I110 of (110) plane and the peak intensity I004 of (004) plane of a graphite crystal determined by the powder XRD measurement, I110/I004, is 0.10 or more and 0.35 or less; an average circularity is 0.80 or more and 0.95 or less; d002 is 0.337 nm or less; and the total pore volume of pores having a diameter of 0.4 μm or less measured by the nitrogen gas adsorption method is 25.0 μl/g or more and 40.0 μl/g or less. Also disclosed is a method for producing the carbon material, a carbon material for a battery electrode, a paste for an electrode incorporating the carbon material for a battery electrode, an electrode for a lithium battery incorporating a formed body of the paste for an electrode, a lithium-ion secondary battery including the electrode and a method for producing the electrode.
METHOD OF PRODUCING DIELECTRIC MATERIAL
A method of producing a dielectric material by preparing a slurry by mixing a dielectric powder, water, one of an organic-acid metal salt and an inorganic metal salt, and an organic silicon compound, causing the slurry to come into contact with an anion exchange resin to remove an anion derived from the one of the organic-acid metal salt and the inorganic metal salt from the slurry, and drying the slurry to obtain the dielectric material.
ALUMINIUM AND ZIRCONIUM-BASED MIXED OXIDE
The present invention relates to a mixed oxide of aluminium, of zirconium, of cerium, of lanthanum and optionally of at least one rare-earth metal other than cerium and lanthanum that makes it possible to repair a catalyst that retains, after severe ageing, a good thermal stability and a good catalytic activity. The invention also relates to the process for preparing this mixed oxide and also to a process for treating exhaust gases from internal combustion engines using a catalyst prepared from this mixed oxide.
BORON-SULFUR-CODOPED POROUS CARBON MATERIAL AND PREPARATION METHOD AND USE THEREOF
A boron-sulfur-codoped porous carbon material and a preparation method is disclosed. The boron-sulfur-codoped porous carbon material includes a porous carbon, and B and S doped in the surface and pores of the porous carbon; where B has a doping content of 5.56 wt.% to 7.85 wt.%, and S has a doping content of 0.90 wt.% to 1.55 wt.%. Test results of examples show that the boron-sulfur-codoped porous carbon material has high doping contents of B and S, and abundant pores; in a three-electrode system, the material shows a maximum specific capacitance of 168 F.Math.g.sup.- .sup.1 to 290.7 F.Math.g.sup.-1 at 0.5 A.Math.g.sup.-1; after the material is assembled into a symmetrical supercapacitor, the supercapacitor has an ultra-high energy density of 11.3 Wh.Math.kg.sup.-1 to 16.65 Wh.Math.kg.sup.-1 in a neutral electrolyte system, and has a capacitance retention rate of 97.09% to 100.67% after 10,000 life tests.
TABLETED ALPHA-ALUMINA CATALYST SUPPORT
A tableted catalyst support, characterized by an alpha-alumina content of at least 85 wt.-%, a pore volume of at least 0.40 mL/g, as determined by mercury porosimetry, and a BET surface area of 0.5 to 5.0 m.sup.2/g. The tableted catalyst support is an alpha-alumina catalyst support obtained with high geometrical precision and displaying a high overall pore volume, thus allowing for impregnation with a high amount of silver, while exhibiting a surface area sufficiently large so as to provide optimal dispersion of catalytically active species, in particular metal species. The invention further provides a process for producing a tableted alpha-alumina catalyst support, which comprises i) forming a free-flowing feed mixture comprising, based on inorganic solids content, at least 50 wt.-% of a transition alumina; ii) tableting the free-flowing feed mixture to obtain a compacted body; and iii) heat treating the compacted body at a temperature of at least 1100° C., preferably at least 1300° C., more preferably at least 1400° C., in particular at least 1450° C., to obtain the tableted alpha-alumina catalyst support. The invention moreover relates to a compacted body obtained by tableting a free-flowing feed mixture which comprises, based on inorganic solids content, at least 50 wt.-% of a transition alumina having a loose bulk density of at most 600 g/L, a pore volume of at least 0.6 mL/g, as determined, and a median pore diameter of at least 15 nm. The invention moreover relates to a shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, comprising at least 15 wt.-% of silver, relative to the total weight of the catalyst, deposited on the tableted alpha-alumina catalyst support. The invention moreover relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of the shaped catalyst body.
Method for making porous graphene membranes and membranes produced using the method
Method for making a porous graphene layer of a thickness of less than 100 nm with pores having an average size in the range of 5-900 nm, includes the following steps: providing a catalytically active substrate catalyzing graphene formation under chemical vapor deposition conditions, the catalytically active substrate in or on its surface being provided with a plurality of catalytically inactive domains having a size essentially corresponding to the size of the pores in the resultant porous graphene layer; chemical vapor deposition using a carbon source in the gas phase and formation of the porous graphene layer on the surface of the catalytically active substrate. The pores in the graphene layer are in situ formed due to the presence of the catalytically inactive domains.
Nickel-based active material for lithium secondary battery, method of preparing the same, and lithium secondary battery including positive electrode including the nickel-based active material
A nickel-based active material for a lithium secondary battery, a method of preparing the nickel-based active material, and a lithium secondary battery including a positive electrode including the nickel-based active material, the nickel-based active material comprising a secondary particle having an outer portion with a radially arranged structure and an inner portion with an irregular porous structure, wherein the inner portion of the secondary particle has a larger pore size than the outer portion of the secondary particle.