A heterogeneous material (e.g., a metal-organic framework or “MOF”) is useful for removing heavy metals from a liquid (e.g., water). The heterogeneous material may incorporate a group 16-containing heterocycle supported on solid media. Thiophene-containing MOFs, such as ATF-1 and DUT-67, may be used to remove lead from water. It is postulated that the metal is adsorbed via non-covalent interactions. The systems and methods described herein may also be applicable to other heavy metals. Thus, the applications are not limited to drinking water purification. Instead, the systems and methods may be used for a broad variety of other applications, such as nuclear waste remediation.

Disclosed herein is a fungicide, including a porous carbon material and a silver member adhered to the porous carbon material, wherein a value of a specific surface area based on a nitrogen BET, namely Brunauer, Emmett, and Teller method is equal to or larger than 10 m.sup.2/g, and a volume of a fine pore based on a BJH, namely Barrett, Joyner, and Halenda method and an MP, namely Micro Pore method is equal to or larger than 0.1 cm.sup.3/g.

Contaminant-sequestering coatings include a network of hydrolyzed silane compounds including (i) a plurality of fluorinated functionalities, and (ii) a plurality of thiol functional groups are provided. The network of hydrolyzed silane compounds includes a fluorinated silane including (a) a hydrophilic polar head region. The polar head region includes one or multiple units of ethylene glycol (EG) functionality, (b) a fluorine-containing region, and (c) an anchor region including a silicon atom. The contaminant-sequestering coatings may sequester one or more per- and polyfluoroalkyl substances (PFAS), heavy metals, biological species, or any combination thereof.

A method of sorbing a PFAS compound from a contaminated sample can include admixing a modified clay sorbent with the sample. The modified clay can include a clay intercalated with a blend of mono-quatemary amine compound and multifunctional-quatemary amine compound having a functionality of 3 or more.

Described herein is a functional graphene composition comprising a graphene scaffold and one or more metal chelating functional groups covalently bonded to the graphene scaffold and a porous substrate that includes the functional graphene composition. Also provided is a method of removing dissolved metals from an aqueous liquid, such as, acid mine drainage.

The disclosure relates to the field of metal ion capture, more particularly of selective capture of nickel Ni(II) ions, by a polymeric compound based on a polymer selected from styrenic polymers and chloropolymers. In the polymeric compound, at least one portion of the monomer units of the polymer is functionalised by the ligand, the ligand including at least one chemical group selected from the glyoxime groups.

The glyoxime groups have a strong affinity for the Ni(II) ions, as well as an excellent selectivity vis-à-vis metal ions of chemical properties similar to Ni(II) ions. This ligand thus allows a selective complexation of the Ni(II) ions by the polymeric compound, including in solutions of low concentrations of Ni(II) ions.

The polymeric compound according to at least one embodiment of the disclosure is particularly intended for capturing the Ni(II) ions during the electrogalvanising methods as well as for recycling material comprising nickel.

A filter medium of the present invention includes a porous carbon material having a value of a specific surface area by a nitrogen BET method of 1×10.sup.2 m.sup.2/g or more, a volume of fine pores by a BJH method of 0.3 cm.sup.3/g or more, and a particle size of 75 μm or more, alternatively, a porous carbon material having a value of a specific surface area by a nitrogen BET method of 1×10.sup.2 m.sup.2/g or more, a total of volumes of fine pores having a diameter of from 1×10.sup.−9 m to 5×10.sup.−7 m, obtained by a non-localized density functional theory method, of 1.0 cm.sup.3/g or more, and a particle size of 75 μm or more.

An alternating cascaded system for high-salinity wastewater treatment includes a pollutant removal system and an alternating cascaded water conveyance system embedded in the pollutant removal system. The pollutant removal system includes four partition plates, a pollutant removal zone and a discharge sump; and the alternating cascaded water conveyance system includes feed water distribution channels disposed under a feed water conveyer pipe and on an outer wall of a first pollutant removal subzone, cleaning water distribution channels disposed on an outer wall of a third pollutant removal subzone and located under a cleaning water pipe, and a purified water discharge pipe and a cleaning water discharge pipe that are located in the discharge sump and axially have a same discharge direction from top to bottom.

A high salinity wastewater treatment system is provided according to the present application, which includes a hydrogel loading system and a flow-storage different-oriented-inlet-and-outlet system. The hydrogel loading system includes six separation plates, a wastewater treatment area, a water distribution bin, a rotating shaft, a driving motor and a fixed bracket. The six separation plates evenly separate the wastewater treatment area into six separate treatment sectors in an axial direction. The six separate treatment sectors are filled with hydrogel materials with water purification effect. The high salinity wastewater infiltrates into each separate treatment sector one by one through high salinity wastewater inlet meshes on a surface of the wastewater treatment area, and the purified high salinity wastewater is discharged through a wastewater cleaning outlet pipe with a same water inlet direction as a cleaning filler distribution pipe.

A process for preparing a granular composite adsorbent, that includes combining poly (diallyl dimethyl ammonium halide) and a clay mineral in water, maintaining the mixture under stirring, recovering a wet mass, forming the wet mass into granules and drying the granules to obtain the granular adsorbent having surface layer with positive zeta potential. The granular material and methods using the granular material in water treatment are also disclosed.