Highly mesoporous activated carbon products are disclosed with mesoporosities characterized by mesopore volumes of 0.7 to 1.0 cubic centimeters per gram or greater. Also disclosed are activated carbon products characterized by a Molasses Number of about 500 to 1000 or greater. Also disclosed are activated carbon products characterized by a Tannin Value of about 100 to 35 or less. The activated carbon products may be further characterized by total pore volumes of at least 0.85 cubic centimeters per gram and BET surface areas of at least about 800 square meters per gram. The activated carbon product may be derived from a renewable feedstock.

Contaminate-sequestering coatings including a network of hydrolyzed silane compounds including a plurality of thiol functional groups, a plurality of fluorinated functionalities, or both are provided. The contaminate-sequestering coatings may sequester one or more per- and polyfluoroalkyl substances (PFAS), heavy metals, biological species or any combination thereof. Methods of functionalizing a substrate surface with contaminate-sequestering functionalities that sequester one or more PFAS, heavy metals, or both are also provided. Methods of removing contaminants from contaminate-containing liquids, and devices including the contaminate-sequestering coatings are also provided.

The present application relates to a novel method for reductive degradation of perfluoroalkyl-containing compounds, such as perfluoroalkyl sulfonates, by activated carbon (AC) supported zero valent iron-nickle nanoparticles (nNi.sup.0Fe.sup.0).

A system using electrical discharge plasma (EDP) for treating a liquid, such as water or waste water to degrade or destroy polar contaminants such as per- and polyfluoroalkyl substances (PFAS) compounds, the system includes a sealed process tank and multiple submerged EDP channels stacked horizontally. Each EDP channel consists of a cathode and an anode, a gas hood, and a gas diffuser. The basic submerged EDP channel is bounded by a plate at the bottom and a submerged gas hood at the top which creates a gas headspace, and hence, a local water surface to provide a local gas/liquid interface in each channel. The cathode lies above the local water surface and anode lies below the local water surface. Each EDP channel may have a gas diffuser at the bottom of the EDP channel for introducing a process gas into the liquid creating bubbles that carry contaminants in the liquid to the local gas/liquid interface. An electrical discharge arcs between the cathode and the anode to generate a plasma used for destruction of contaminants in the water or wastewater at the local gas/liquid interface.

A method of destroying a fluorocarbon compound includes regenerating an adsorbent to remove the fluorocarbon compound and to produce a regeneration fluid having a concentration of the fluorocarbon compound and directing the regeneration fluid to an electro-oxidation system. The method also includes applying a current to the electro-oxidation system to oxidize the fluorocarbon compound within the regeneration fluid and measuring a quantity of fluorides in the regeneration fluid to determine the progress of the removal of the fluorocarbon compound from the regeneration fluid.

Contaminant-sequestering coatings include a network of hydrolyzed silane compounds including (i) a plurality of fluorinated functionalities, and (ii) a plurality of thiol functional groups are provided. The network of hydrolyzed silane compounds includes a fluorinated silane including (a) a hydrophilic polar head region. The polar head region includes one or multiple units of ethylene glycol (EG) functionality, (b) a fluorine-containing region, and (c) an anchor region including a silicon atom. The contaminant-sequestering coatings may sequester one or more per- and polyfluoroalkyl substances (PFAS), heavy metals, biological species, or any combination thereof.

A method of sorbing a PFAS compound from a contaminated sample can include admixing a modified clay sorbent with the sample. The modified clay can include a clay intercalated with a blend of mono-quatemary amine compound and multifunctional-quatemary amine compound having a functionality of 3 or more.

A system and method for water purification by capture of contaminants in an aqueous mixture is described herein. A system and method for regenerating the capture system is also described. An integrated capture and regeneration system and method is also described including a separation vessel that houses a capture bed and optionally an electrode in electrical contact with the bed with a power source for applying a voltage to the electrode. The applied voltage enhances capture of the contaminant from aqueous liquid on the capture bed and modulation of the applied voltage enhances release of contaminant on the capture bed into aqueous wash liquid to regenerate the bed. The aqueous wash liquid may contain a counter ion that binds to the contaminant forming an aggregate contaminant phase that separates from the aqueous wash liquid.

Per- and polyfluoroalkyl substances (PFAS) are destroyed by oxidation in supercritical conditions. PFAS in water can be concentrated and prepared for destruction in a pretreatment phase. Following annihilation of the PFAS in supercritical conditions to levels below 5 parts per trillion (ppt), the water effluent can be used to recover heat, returned to sub-critical conditions, and then released back into the environment.

Catalyst materials comprising iron and palladium are described. Also described are methods for preparing such materials. In addition, methods for remediating materials such as sediments and groundwater using the catalyst materials are described.