Copper-boron-ferrite (Cu—B—Fe) composites may be prepared and immobilized on graphite electrodes in a silica-based sol-gel, e.g., from rice husks. Different bimetallic loading ratios can produce fast in-situ electrogeneration of reactive oxygen species, H.sub.2O.sub.2 and .OH, e.g., via droplet flow-assisted heterogeneous electro-Fenton reactor system. Loading ratios of, e.g., 10 to 30 wt. % Fe.sup.3+ and 5 to 15% wt. Cu.sup.2+, can improve the catalytic activities towards pharmaceutical beta blockers (atenolol and propranolol) degradation in water. Degradation efficiencies of at least 99.9% for both propranolol and atenolol in hospital wastewater were demonstrated. Radicals of .OH in degradation indicate a surface mechanism at inventive cathodes with correlated contributions of iron and copper. Copper and iron can be embedded in porous graphite electrode surface and catalyze the conversion of H.sub.2O.sub.2 to .OH to enhance the degradation. Inventive cathodes can be stable catalytically after 20 or more cycles under neutral and acidic conditions.

A liquid treatment apparatus includes a water pump and a plasma jet generating device. A liquid inlet of the water pump is immersed in a liquid. A liquid outlet of the water pump is configured to eject the liquid from the liquid inlet out of the water pump without artificial bubbles in the liquid. A gas inlet of the plasma jet generating device is configured to be located out of the liquid. A pair of electrodes of the plasma jet generating device is configured to generate plasma jet by the gas from the gas inlet. The plasma jet outlet is configured to be immersed in the liquid and in proximity to the liquid outlet of the water pump so that the gas is automatically entrained into the gas inlet of the plasma jet generating device when the liquid is ejected out from the liquid outlet.

Methods for electrochemically oxidizing organic compounds in aqueous solution. The methods include contacting an aqueous solution comprising organic compounds with a first anode and electrochemically oxidizing at least a portion of the organic compounds to provide a first aqueous solution comprising oxidation products; and contacting the first aqueous solution comprising oxidation products with a first cathode and electrochemically reducing at least a portion of the oxidation products to provide a first aqueous solution comprising reduced products and residual oxidizable organic compounds. The first aqueous solution can be further treated to electrochemically oxidize at least a portion of the residual oxidizable organic compounds to provide a second aqueous solution comprising oxidation products, and the second aqueous solution can be further treated to electrochemically reduce at least a portion of the oxidation products to provide a third aqueous solution comprising reduced products and residual oxidizable organic compounds. Systems for electrochemically oxidizing organic compounds and effectively carrying out the methods are also provided.

The present invention relates to systems and methods for cleaning materials, such as flooring and upholstery. In some cases, the systems and methods use an electrolytic cell to electrolyze a solution comprising sodium carbonate, sodium bicarbonate, sodium acetate, sodium percarbonate, potassium carbonate, potassium bicarbonate, and/or any other suitable chemical to generate electrolyzed alkaline water and/or electrolyzed oxidizing water. In some cases, the cell comprises a recirculation loop that recirculates anolyte through an anode compartment of the cell. In some cases, the cell further comprises a senor and a processor, where the processor is configured to automatically change an operation of the cell, based on a reading from the sensor. In some cases, a fluid flows past a magnet before entering the cell. In some additional cases, fluid from the cell is conditioned by being split into multiple conduits that run in proximity to each other. Additional implementations are described.

The present invention relates to systems and methods for cleaning materials, such as flooring and upholstery. In some cases, the systems and methods use an electrolytic cell to electrolyze a solution comprising sodium carbonate, sodium bicarbonate, sodium acetate, sodium percarbonate, potassium carbonate, potassium bicarbonate, and/or any other suitable chemical to generate electrolyzed alkaline water and/or electrolyzed oxidizing water. In some cases, the cell comprises a recirculation loop that recirculates anolyte through an anode compartment of the cell. In some cases, the cell further comprises a senor and a processor, where the processor is configured to automatically change an operation of the cell, based on a reading from the sensor. In some cases, a fluid flows past a magnet before entering the cell. In some additional cases, fluid from the cell is conditioned by being split into multiple conduits that run in proximity to each other. Additional implementations are described.

A water treatment apparatus, upper surfaces of two of the consecutively arranged ground electrodes are alternately inclined in opposite directions with respect to a horizontal plane, a gap is formed between a lower surface of an upper side ground electrode and an upper surface of a lower side ground electrode, a voltage is applied to a discharge electrode provided in the gap, thereby forming discharges both in air between the discharge electrode and the lower surface of the upper side ground electrode and in air between the discharge electrode and the upper surface of the lower side ground electrode, and water to be treated is caused to continuously flow downward from the ground electrode of an uppermost part to the ground electrode of a lowermost part along the respective upper surfaces such that the water to be treated is treated.

For bio-electrically generating electric power from organic ingredients of a waste water flowing in a flow direction, an anode is immersed in the waste water in a first spatial area, and oxygen is supplied to a cathode which is electrically connected to the anode and arranged in a second spatial area delimited from the first spatial area by means of a proton-permeable membrane. A voltage between the anode and the cathode is increased by a DC/DC converter located at the anode and the cathode, and a further voltage between a further anode in said or a further first spatial area and a further cathode in said or a further second spatial area is increased by a further DC/DC converter located at the further anode and the further cathode. A DC voltage link is charged with the DC/DC converter and the further DC/DC converter connected in parallel to the DC voltage link.

A three-dimensional electrode-ozone oxidation-electrocatalytic membrane coupled wastewater treatment device, including a circulating fluidized bed reactor. The circulating fluidized bed reactor includes a funnel-shaped internal, a truncated cone, a fiber ball filter, a gas-liquid distribution plate, an inner cylinder, an intermediate cylinder and an outer cylinder. The inner cylinder, the intermediate cylinder and the outer cylinder are coaxial. The inner cylinder is an electrocatalytic membrane assembly; the intermediate cylinder is a gas diffusion electrode; and the outer cylinder is a stainless-steel mesh. A particle electrode is filled between the intermediate cylinder and the outer cylinder, and between the intermediate cylinder and the inner cylinder. The intermediate cylinder is connected to a negative electrode. The inner cylinder and the outer cylinder are connected to a positive electrode. A wastewater treatment method using the device is also provided herein.

The present invention relates to systems and methods for cleaning materials, such as flooring and upholstery. In some cases, the systems and methods use an electrolytic cell to electrolyze a solution comprising sodium carbonate, sodium bicarbonate, sodium acetate, sodium percarbonate, potassium carbonate, potassium bicarbonate, and/or any other suitable chemical to generate electrolyzed alkaline water and/or electrolyzed oxidizing water. In some cases, the cell comprises a recirculation loop that recirculates anolyte through an anode compartment of the cell. In some cases, the cell further comprises a sensor and a processor, where the processor is configured to automatically change an operation of the cell, based on a reading from the sensor. In some cases, a fluid flows past a magnet before entering the cell. In some additional cases, fluid from the cell is conditioned by being split into multiple conduits that run in proximity to each other. Additional implementations are described.

A method and apparatus for treating waste water utilizing two energized agitated electrochemical reaction reactor units (each utilizing approximately 10 amps per gallon) with a reaction time of approximately 5 minutes wherein the first reaction vessel has a pH below 7 and a second reaction vessel has a pH of above the pH of the first reaction vessel and the effluent flows from a first agitated electrochemical reaction vessel to a degassing tank and then flows to a second agitated electrochemical reaction vessel and then to a flocculation tank.