A method of forming a glass sheet comprises: (a) forming a ribbon of glass from molten glass with a pair of forming rollers; (b) reducing horizontal temperature variability of the ribbon of glass to be 10° C. or less across 80 percent of an entire width of the ribbon of glass before the ribbon of glass cools to a glass transition temperature; (c) controlling a cooling rate of the ribbon of glass while the ribbon of glass moves vertically downward within a setting zone such that the ribbon of glass has a first average cooling rate before the ribbon of glass cools to the glass transition temperature and a second average cooling rate after the ribbon of glass cools to the glass transition temperature, the first average cooling rate being less than the second average cooling rate; and (d) separating a glass sheet from the ribbon of glass.

A manufacturing method for a band-shaped glass includes a forming step, which forms a band-shaped glass, an annealing step, which performs an annealing treatment on the band-shaped glass, a cooling step, which cools the annealed band-shaped glass, a direction-changing step, which changes a feeding direction of the cooled band-shaped glass from a longitudinal direction to a horizontal direction, and a horizontal conveying step, which conveys the band-shaped glass in the horizontal direction while supporting the band-shaped glass at a horizontal conveyance part. In the horizontal conveying step, the band-shaped glass is conveyed in the horizontal direction while a first propulsion for driving the conveyance in the horizontal direction is provided at both sides in the width direction of the band-shaped glass by the horizontal conveyance part, the first propulsion being larger than a second propulsion provided at a center in the width direction of the band-shaped glass.

According to one embodiment, an apparatus for forming a glass ribbon may include a forming wedge disposed in a housing and including a pair of downwardly inclined forming surfaces converging at a root. A plurality of heating cartridges may be positioned in ports of the housing. Each heating cartridge may include a heat directing surface that is oriented at an angle of greater than about 90° with respect to a bottom surface of the heating cartridge. The heat directing surface may include at least one heating element positioned adjacent to the heat directing surface. The heating cartridge may be positioned such that the heat directing surface faces the forming wedge and an upper edge of the heat directing surface is positioned above the root to direct heat from the heat directing surface towards the root of the forming wedge.

Described herein are glass forming apparatuses with cooled muffle assemblies and methods for using the same to form glass ribbons. According to one embodiment, a muffle assembly for a fusion forming apparatus may include a muffle frame comprising a back wall, a front wall opposite the back wall, and a pair of sidewalls joining the front wall to the back wall in a closed-loop. At least one first cooling tube may extend through the back wall and the front wall across the closed-loop. At least one second cooling tube may extend through the back wall and the front wall across the closed loop such that the at least one second cooling tube is spaced apart from and parallel with the at least one first cooling tube.

A standalone lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner.

A glass manufacturing apparatus includes a forming apparatus defining a travel path extending in a travel direction. The forming apparatus conveys a ribbon of glass-forming material along the travel path in the travel direction. The glass manufacturing apparatus includes a cooling tube including a first end and a second end. The cooling tube includes a first tube including a closed first sidewall surrounding a first channel. The first tube receives a first cooling fluid within the first channel. The cooling tube includes a second tube including a closed second sidewall surrounding a second channel. The first tube is positioned within the second tube. The second tube receives a second cooling fluid within the second channel. The cooling tube includes a nozzle. The nozzle receives the first cooling fluid and directs the first cooling fluid toward the travel path. Methods include manufacturing a glass ribbon with the glass manufacturing apparatus.

Apparatus for producing glass ribbon comprises a plurality of cooling coils positioned along a cooling axis of the apparatus extending transverse to a draw direction. The cooling coils are configured to control a transverse temperature profile of the glass ribbon along a cooling axis. Each cooling coil can be fabricated from at least one tube and configured to circulate fluid to remove heat from the cooling coil. In further examples, methods of producing a glass ribbon include the step of controlling a transverse temperature profile of the glass ribbon along a width of the glass ribbon. The step of controlling the temperature profile includes selectively removing heat from at least one of a plurality of cooling coils positioned along the cooling axis.

A method of treating a ceramic body in a glass making process includes delivering a molten glass to a heated ceramic body, the ceramic body including a ceramic phase and an intergranular glass phase, the molten glass being in contact with a surface of the ceramic body. The method further includes contacting the ceramic body with a first electrode and contacting the molten glass with a second electrode. The method further includes applying an electric field between the first electrode and the second electrode to create an electric potential difference across the ceramic body between the first and second electrodes, the electric potential difference being less than an electrolysis threshold of the ceramic phase and the intergranular glass phase. The intergranular glass phase demixes under driven diffusion in the applied electric field and mobile cations in the intergranular glass phase enrich proximate one of the first and second electrode.

A strengthened glass article (100), such as a substrate for a p-Si based transistors, includes first and second glass cladding layers (104, 106) and a glass core layer (102) disposed therebetween. A coefficient of thermal expansion [CTE] of each cladding layer (104, 106), which can be made of the same glass, is at least 1×10.sup.−7° C..sup.−1 less than that of the core layer (102). Each of the core and cladding layers has a strain point less than 700° C. A compaction of the glass article (100) is at most about 20 ppm [see FIG. 1]. A method includes forming a glass article and/or heating a glass article to a first temperature of at least about 400° C. The glass article has a glass core layer (102) and a glass cladding layer (104, 106) adjacent to the core layer. The glass article is maintained at a temperature within a range of from 400° C. to 600° C. for a holding period from 30 to 90 minutes and subsequently cooled to a temperature of at most 50° C. over a cooling period from 30 seconds to 5 minutes. The glass article (100) for heat strengthening may have been produced by the fusion overflow down draw process, e.g. as depicted in FIG. 3.

Embodiments of a method of forming a glass article are disclosed. The methods include supplying a glass ribbon in a first direction and redirecting the glass ribbon to a second direction different from the first direction without contacting the glass ribbon with a solid material. The glass ribbon may exhibit a viscosity of less than about 10.sup.8 Poise and a thickness of about 1 mm or less. Embodiments of a glass or glass-ceramic forming apparatus are also disclosed. The apparatus may include a glass feed device for supplying a glass ribbon in a first direction and a redirection system disposed underneath the glass feed device for redirecting the glass ribbon to a second direction. In one or more embodiments, the redirection system comprising at least one gas bearing system for supplying a gas film to support the glass ribbon.