Embodiments of the present invention pertain to antimicrobial glass compositions, glasses, and articles. The articles include a glass, which may include a glass phase and a cuprite phase. In other embodiments, the glasses include a plurality of Cu.sup.1+ ions, a degradable phase including B.sub.2O.sub.3, P.sub.2O.sub.5 and K.sub.2O, and a durable phase including SiO.sub.2. Other embodiments include glasses having a plurality of Cu.sup.1+ ions disposed on the surface of the glass and in the glass network and/or the glass matrix. The article may also include a polymer. The glasses and articles disclosed herein exhibit a 2 log reduction or greater in a concentration of at least one of Staphylococcus aureus, Enterobacter aerogenes, Pseudomonas aeruginosa bacteria, Methicillin Resistant Staphylococcus aureus, and E. coli, under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing condition and under Modified JIS Z 2801 for Bacteria testing conditions.

A glass ceramic seal is formed from a precursor material that includes from 80 mol % to 100 mol % of a primary component containing, on an oxide basis, from 25 mol % to 55 mol % SiO.sub.2, from 20 mol % to 45 mol % CaO, from 5 mol % to 30 mol % MgO, and from 0 mol % to 15 mol % Al.sub.2O.sub.3.

The present invention provides a red light emitting glass ceramic and a preparation method thereof, and an LED/LD light emitting device. A.sub.2Al.sub.4Si.sub.5O.sub.18:Eu.sup.2+ cordierite of the red light emitting glass ceramic capable of realizing blue light excited red light emission is a crystal phase material, wherein A is at least one of Mg, Ca, Sr, Ba and Zn and at least comprises Mg. The present invention particularly provides the red light emitting glass ceramic taking a chemical formula A.sub.2Al.sub.4Si.sub.5O.sub.18:Eu.sup.2+ as a crystal phase. The present invention further provides a preparation method of the transparent glass ceramic. The glass ceramic comprising the crystal phase, with the chemical formula of Mg.sub.2Al.sub.4Si.sub.5O.sub.18:Eu.sup.2+, is excited by blue light to emit red light, the internal/external quantum efficiencies reaching up to 94.5%/70.6%, respectively.

A glass ceramic seal contains by weight, on an oxide basis 40-60% of SiO.sub.2, 25-28% of BaO, 10-20% of B.sub.2O.sub.3, 8-12% of Al.sub.2O.sub.3, 0-2% of ZrO.sub.2, 0-1% of Y.sub.2O.sub.3, 0-1% of CaO, and 0-1% of MgO.

The present invention relates to a glass ceramic having a lithium aluminosilicate composition and including a crystal and a residual glass, in which the residual glass has a composition including, in terms of mol % based on oxides: 25% to 70% of SiO.sub.2; 3% to 35% of Al.sub.2O.sub.3; 0.1% to 20% of Li.sub.2O; 0.1% to 20% of Na.sub.2O; 0% to 10% of K.sub.2O; and 1% to 15% of ZrO.sub.2, and a parameter V is −600 or more and 720 or less, the parameter V being calculated based on the following formula: V=49.589×[SiO.sub.2]+61.806×[Al.sub.2O.sub.3]+45.456×[P.sub.2O.sub.5]+41.151×[MgO]+110.26×[CaO]+50.263×[SrO]+55.693×[Li.sub.2O]+3.598×[Na.sub.2O]+9.503×[K.sub.2O]+6.83×[TiO.sub.2]−2.885×[ZrO.sub.2]−3746.99.

A lead-through or connecting element is provided that includes an assembly having a carrier body of a high-temperature alloy, a functional element, and an at least partially crystallized glass. The crystallized glass is between a portion of the functional element and a portion of the carrier body. The carrier body subjects the crystallized glass to a compressive stress of greater than or equal to zero, at a temperature from at least 20° C. to more than 450° C. Also provided are a method for producing a lead-through or connecting element, the use of such a lead-through or connecting element, and to a measuring device including such a lead-through or connecting element.

The present application provides LAS type transparent glass-ceramics of β-quartz of composition containing a high content of zinc, articles constituted at least in part of said glass-ceramics, glasses precursors of said glass-ceramics (with a low viscosity at high temperature), and also a method of preparing said articles. Said glass-ceramics present a composition, free of arsenic oxide and antimony oxide, except for inevitable traces, expressed as percentages by weight of oxides, containing: 64.5% to 66.5% of SiO.sub.2; 19.0% to 20.6% of Al.sub.2O.sub.3; 3.0% to 3.6% of Li.sub.2O; 0 to 1% of MgO; 1.7% to 3.4% of ZnO; 2% to 3% of BaO; 0 to 3% of SrO; 0 to 1% of CaO; 2% to 4% of TiO.sub.2; 1% to 2% of ZrO.sub.2; 0 to 1% of Na.sub.2O; 0 to 1% of K.sub.2O; with Na.sub.2O+K.sub.2O+BaO+SrO+CaO≤6%; optionally up to 2% of at least one fining agent comprising SnO.sub.2; and optionally up to 2% of at least one coloring agent.

A glass-ceramic article comprises: a center-volume composition comprising (on an oxide basis): 55-75 mol % SiO.sub.2; 0.2-10 mol % Al.sub.2O.sub.3; 0-5 mol % B.sub.2O.sub.3; 15-30 mol % Li.sub.2O; 0-2 mol % Na.sub.2O; 0-2 mol % K.sub.2O; 0-5 mol % MgO; 0-2 mol % ZnO; 0.2-3.0 mol % P.sub.2O.sub.5; 0.1-10 mol % ZrO.sub.2; 0-4 mol % TiO.sub.2; and 0-1.0 mol % SnO.sub.2. Lithium disilicate and either β-spodumene or β-quartz are the two predominant crystalline phases (by weight) of the glass-ceramic article. The glass-ceramic article further comprises tetragonal ZrO.sub.2 as a crystalline phase. The composition of the glass-ceramic article from a primary surface into a thickness of the glass-ceramic article can comprise over 10 mol % Na.sub.2O (on an oxide basis), with the mole percentage of Na.sub.2O decreasing from the primary surface towards the center-volume. The glass-ceramic article exhibits a ring-on-ring load-to-failure of at least 120 kgf, when the thickness of the glass-ceramic article is 0.3 mm to 2.0 mm.

Method for manufacturing coloured glass-ceramic slab articles from a base mix, comprising the steps of a) preparing a mix comprising a colouring pigment, at least one binder and a preponderant amount of a glass frit having a specific composition, b) distributing the mix in a forming support, c) compacting the mix, d) drying the mix, e) sintering the compacted and dried mix by firing to obtain a slab article, and f) cooling the articles under conditions such as to prevent—even partial—devitrification and/or crystallization of the glass frit. The invention also relates to a glass frit for manufacturing base mixes and a coloured glass-ceramic slab article obtained from the base mix.

A transparent gahnite-spinel glass ceramic is provided. The glass ceramic includes a first crystal phase including (Mg.sub.xZn.sub.1−x)Al.sub.2O.sub.4 where x is less than 1 and a second crystal phase including tetragonal ZrO.sub.2. The glass ceramic may be ion exchanged. Methods for producing the glass ceramic are also provided.