A method for producing a ceramic complex includes: preparing a raw material mixture that contains 5% by mass or more and 40% by mass or less of first rare earth aluminate fluorescent material particles containing an activating element and a first rare earth element different from the activating element, 0.1% by mass or more and 32% by mass or less of oxide particles containing a second rare earth element, and the balance of aluminum oxide particles, relative to 100% by mass of the total amount of the first rare earth aluminate fluorescent material particles, the oxide particles, and the aluminum oxide particles; preparing a molded body of the raw material mixture; and obtaining a sintered body by calcining the molded body in a temperature range of 1,550 C. or higher and 1,800 C. or lower.

Sub-ambient daytime radiative cooling (SDRC) coating comprising: an alkali activated metakaolin, BaSO.sub.4, and silica nanospheres, wherein the alkali activated metakaolin is prepared by reaction of metakaolin with an alkali activator comprising waterglass and a strong base selected from the group consisting of LiOH, NaOH, KOH, Ca(OH).sub.2, Li.sub.2O Na.sub.2O, K.sub.2O, CaO, and a mixture thereof, a coating formulation comprising the same, and a method of preparation and use thereof.