Disclosed are: damage-resistant ECMCs that need to work and remain elastic between minus 120° C. and positive 300° C.; ECMCs that need to be able to contain a flame of 1900° C. for more than 90 minutes; and composite structures, especially highly stressed structures. One of the characteristic problems of ceramic matrices is their fragility. Indeed, when a fracture starts, it propagates easily in the matrix. Disclosed are elastic ceramic matrix composites (ECMCs), for which: the ceramic matrix is split into solid “ceramic microdomains” (CMDs); the CMDs are connected to one another by a dense network of “elastic microelements” (EMEs); and the bonds between the EMEs and the CMDs are strong chemical bonds, preferably covalent.

Aspects of the present disclosure provide for cement, cement paste, cementitious paste, cementitious mortar, and concrete, methods of making cement, cement paste, cementitious paste, cementitious mortar, and concrete, structures incorporating the concrete, and the like, where the cement, cement paste, cementitious paste, cementitious mortar, and the concrete include elemental boron and/or one or more boron compounds (e.g., boron-doped cement, cement paste, cementitious paste, cementitious mortar, and concrete). The boron and/or a boron compound can be homogeneously distributed throughout the cement, cement paste, cementitious paste, cementitious mortar and/or concrete.

Aspects of the present disclosure provide for cement, cement paste, cementitious paste, cementitious mortar, and concrete, methods of making cement, cement paste, cementitious paste, cementitious mortar, and concrete, structures incorporating the concrete, and the like, where the cement, cement paste, cementitious paste, cementitious mortar, and the concrete include elemental boron and/or one or more boron compounds (e.g., boron-doped cement, cement paste, cementitious paste, cementitious mortar, and concrete). The boron and/or a boron compound can be homogeneously distributed throughout the cement, cement paste, cementitious paste, cementitious mortar and/or concrete.

A catalyst fibrous structure having a catalyst metal carried on a fibrous structure, wherein (a) a Log differential micropore volume distribution curve thereof obtained by measurement using a mercury intrusion technique has a peak having a maximum micropore diameter in the range of from 0.1 μm to 100 μm; (b) a Log differential micropore volume at the peak is 0.5 mL/g or more; and (c) an amount of a catalyst metal compound and a binder carried per unit volume is 0.05 g/mL or more. A production method for producing a catalyst fibrous structure having: (1) mixing a catalyst metal compound or a catalyst precursor, and an inorganic binder and a solvent; (2) grinding the mixture to obtain a coating material of the catalyst metal compound or the catalyst precursor having a median particle diameter of 2 μm or less and a viscosity of from 10 mPa.Math.s to 200 mPa.Math.s; (3) impregnating a fibrous structure with the coating material to fill up voids of the fibrous structure with the coating material of the catalyst metal compound or the catalyst precursor; (4) heating and drying the fibrous structure, directly as it is, at a temperature not lower than the boiling point of the solvent; and (5) heating and calcination the dried fibrous structure at a temperature not lower than the dehydration temperature of the inorganic binder to obtain a catalyst fibrous structure.

A catalyst fibrous structure having a catalyst metal carried on a fibrous structure, wherein (a) a Log differential micropore volume distribution curve thereof obtained by measurement using a mercury intrusion technique has a peak having a maximum micropore diameter in the range of from 0.1 μm to 100 μm; (b) a Log differential micropore volume at the peak is 0.5 mL/g or more; and (c) an amount of a catalyst metal compound and a binder carried per unit volume is 0.05 g/mL or more. A production method for producing a catalyst fibrous structure having: (1) mixing a catalyst metal compound or a catalyst precursor, and an inorganic binder and a solvent; (2) grinding the mixture to obtain a coating material of the catalyst metal compound or the catalyst precursor having a median particle diameter of 2 μm or less and a viscosity of from 10 mPa.Math.s to 200 mPa.Math.s; (3) impregnating a fibrous structure with the coating material to fill up voids of the fibrous structure with the coating material of the catalyst metal compound or the catalyst precursor; (4) heating and drying the fibrous structure, directly as it is, at a temperature not lower than the boiling point of the solvent; and (5) heating and calcination the dried fibrous structure at a temperature not lower than the dehydration temperature of the inorganic binder to obtain a catalyst fibrous structure.

Disclosed embodiments concern a composition comprising a diatom frustule and two or more photocatalytic nanoparticles dispersed on the surface of the frustule. Also disclosed are embodiments of a method for making the composition. The nanoparticles are dispersed such that they are separate and not in physical contact with each other. An average distance between the nanoparticles may be from greater than 0 nm to 100 nm. The nanoparticles may comprise a dopant material. Paint compositions comprising the diatom frustule compositions are also contemplated. The diatom frustule composition may be useful for removing and/or degrading volatile organic compounds, such as those present in the atmosphere.

Disclosed embodiments concern a composition comprising a diatom frustule and two or more photocatalytic nanoparticles dispersed on the surface of the frustule. Also disclosed are embodiments of a method for making the composition. The nanoparticles are dispersed such that they are separate and not in physical contact with each other. An average distance between the nanoparticles may be from greater than 0 nm to 100 nm. The nanoparticles may comprise a dopant material. Paint compositions comprising the diatom frustule compositions are also contemplated. The diatom frustule composition may be useful for removing and/or degrading volatile organic compounds, such as those present in the atmosphere.

In one aspect, the present invention is directed to a coating composition. The coating composition comprises photocatalytic particles and an alkali metal silicate binder comprising an alkoxysilane. In another aspect, the present invention is directed to a coated article. The coated article has a photocatalytic coating with improved durability on its external surface that is formed from the aforesaid coating composition.

The present disclosure relates to roofing granules, such as solar-reflective roofing granules having one or more of low crystalline silica content, high stain resistance and algae resistance. The present disclosure provides a mineral roofing granule having at its mineral outer surface a first fired mixture comprising an aluminosilicate clay, the first fired material having no more than 2 wt % crystalline silica. The present disclosure also provides a mineral roofing granule having a mineral body and a mineral outer surface, the mineral roofing granule having at its mineral outer surface a first fired material, the first fired material being a first fired mixture comprising an aluminosilicate clay; one or more of a feldspar, a sodium silicate and a nepheline syenite; and, optionally, a zinc source.

Process for the preparation of an additive comprising TiO.sub.2 particles dispersed on a support of pseudo-layered phyllosilicate-type, comprising the dispersion in water of the support, the acid activation of the support and the high-shear dispersion of the support with the TiO.sub.2 particles Use of the particles obtained by this process as additives with photocatalytic activity for water purification and disinfection, for purification of polluted gas streams and to provide materials, in particular construction materials, with self-cleaning, biocide, deodorization and/or pollution reduction properties in the presence of air and ultraviolet light.