A downhole tool comprising a cylindrical housing, a sleeve disposed in the cylindrical housing, forming an annular space between the sleeve and the cylindrical housing, and a tool cement composition disposed in the annular space, wherein prior to setting the tool cement composition comprises a cement, sand, a silicon-containing material, a dispersant, and water, and wherein upon setting the tool cement composition provides an annular seal having a fluid leakage of less than 750 ml over 15 minutes at a pressure of 7500 psi and a temperature of 400° F.

A downhole tool comprising a cylindrical housing, a sleeve disposed in the cylindrical housing, forming an annular space between the sleeve and the cylindrical housing, and a tool cement composition disposed in the annular space, wherein prior to setting the tool cement composition comprises a cement, sand, a silicon-containing material, a dispersant, and water, and wherein upon setting the tool cement composition provides an annular seal having a fluid leakage of less than 750 ml over 15 minutes at a pressure of 7500 psi and a temperature of 400° F.

A downhole tool comprising a cylindrical housing, a sleeve disposed in the cylindrical housing, forming an annular space between the sleeve and the cylindrical housing, and a tool cement composition disposed in the annular space, wherein prior to setting the tool cement composition comprises a cement, sand, a silicon-containing material, a dispersant, and water, and wherein upon setting the tool cement composition provides an annular seal having a fluid leakage of less than 750 ml over 15 minutes at a pressure of 7500 psi and a temperature of 400° F.

The present invention is directed to processes for preparing a silicone surfactant intercalated clay and a polymer-clay nanocomposite. The processes use silicone surfactants having a molecular weight in the range of 10,000 to 100,000 Dalton to achieve fully exfoliating clay structures. Using these macromolecular silicone surfactants, along with the engineered control of the processing pH and drying stress conditions, this invention provides simple and low-cost methods of making a fully-exfoliated polymer-clay nanocomposite.

The present invention relates to a composition for use as component of a multicomponent resin-modified glass ionomer cement, to a multicomponent resin-modified glass ionomer cement and also to a process for the preparation of the corresponding compositions and of cured dental materials. The invention furthermore relates to the corresponding use of one or more compounds (S) selected from the group consisting of sulfinic acids, salts of sulfinic acids and salts of organoboron compounds.

The present invention is directed to processes for preparing a silicone surfactant intercalated clay and a polymer-clay nanocomposite. The processes use silicone surfactants having a molecular weight in the range of 10,000 to 100,000 Dalton to achieve fully exfoliating clay structures. Using these macromolecular silicone surfactants, along with the engineered control of the processing pH and drying stress conditions, this invention provides simple and low-cost methods of making a fully-exfoliated polymer-clay nanocomposite.

Hydrophobic aggregates for use in refractory castables and gunning mixtures and methods of their preparation. The aggregates here are formed by crushing insulating fire brick and coating the resulting particles with a hydrophobic component. The hydrophobic component may be a polydimethylsiloxane having a terminal silanol group. As a result of the coating process, the coated aggregate has very low levels of alkalis. The aggregates may be used to form refractory castables that do not undergo substantial alkaline hydrolysis due to the reduced levels of alkalis. The castables made from these aggregates display superior physical properties, including lower water content, lower permanent linear change, high strength, and superior thermal conductivity/insulation properties, while at the same time possessing lower density and requiring less water to be used during castable formation. These improved properties also are observed in gunning mixtures formed from these aggregates.

Compositions including a curable resin and organophilically-modified clay for subterranean oil well applications and methods of using the same. A method of treating a subterranean formation including placing in a subterranean formation a curable composition that includes at least one of a curable organic resin and a thermosetting polymer. The curable composition also includes an organophilically-modified clay.

Compositions including a curable resin and organophilically-modified clay for subterranean oil well applications and methods of using the same. A method of treating a subterranean formation including placing in a subterranean formation a curable composition that includes at least one of a curable organic resin and a thermosetting polymer. The curable composition also includes an organophilically-modified clay.

A cement slurry composition, containing hydraulic cement, water, and from 1 to less than 4% of an organically modified nanoclay. A method for cementing a high pressure high temperature well by pumping the cement composition of claim 1 between a casing and a formation of a well bore to fill a gap between the casing and the formation, and allowing the cement to harden.