A ceramic composition contains Fe, Cu, Ni, Zn, Co, and Cr. When Fe, Cu, Ni, and Zn are converted to Fe.sub.2O.sub.3, CuO, NiO, and ZnO, respectively, and a total amount of Fe.sub.2O.sub.3, CuO, NiO, and ZnO is 100 parts by mole, the ceramic composition contains from 48.20 to 49.85 parts by mole Fe in terms of Fe.sub.2O.sub.3, from 2.00 parts to 8.00 parts by mole Cu in terms of CuO, from 11.90 to 18.70 parts by mole Ni in terms of NiO, and from 27.00 to 33.50 parts by mole Zn in terms of ZnO. When Fe, Cu, Ni, and Zn are converted to Fe.sub.2O.sub.3, CuO, NiO, and ZnO, respectively, and a total amount of Fe.sub.2O.sub.3, CuO, NiO, and ZnO is 100 parts by weight, the ceramic composition contains from 5 to 100 ppm Co in terms of CoO and from 10 to 400 ppm in terms of Cr.sub.2O.sub.3.

A ferrite sintered magnet comprising an M type Sr ferrite having a hexagonal structure as a main phase, wherein the ferrite sintered magnet does not substantially comprise a rare earth element and Co, a content of B is 0.005 to 0.9% by mass in terms of B.sub.2O.sub.3, and a content of Zn is 0.01 to 1.2% by mass in terms of ZnO.

In an aspect, a ferrite composition comprises a Ru—Co.sub.2Z ferrite having the formula: (Ba.sub.3-xM.sub.x)Co.sub.2(M′Ru).sub.yFe.sub.24-2y-zO.sub.41, wherein M is at least one of Sr, Pb, or Ca; M′ is at least one of Co, Zn, Mg, or Cu; x is 1 to 3; y is greater than 0 to 2; and z is −4 to 4. In another aspect, an article comprises the ferrite composition. In yet another aspect, method of making the ferrite composition comprises mixing ferrite precursor compounds comprising Fe, Ba, Co, and Ru; and sintering the ferrite precursor compounds in an oxygen atmosphere to form the Ru—Co.sub.2Z ferrite.

To provide a ferrite sintered magnet having a high residual magnetic flux density (Br) and a high coercive force (HcJ), and also able to produce at a low cost. The ferrite sintered magnet includes a hexagonal M-type ferrite including A, R, Fe, and Co in an atomic ratio of A.sub.1-xR.sub.x(Fe.sub.12-yCo.sub.y).sub.zO.sub.19. A is at least one selected from Sr, Ba, and Pb. R is La only or La and at least one selected from rare earth elements. 0.13≤x≤0.23, 10.80≤(12−y)z≤12.10, and 0.13≤yz≤0.20 are satisfied.

A ferrite sintered magnet including ferrite grains having a hexagonal crystal structure. The ferrite grains satisfy 0.56≤W≤0.68 where W is an average value of circularities of the ferrite grains in a cross section parallel to an axis of easy magnetization.

Provided is a red mud-based composite calcium ferrite and a preparation method and use thereof. The preparation method of the red mud-based composite calcium ferrite includes the following steps: mixing red mud and a calcium source, and roasting an obtained mixture in an oxygen-containing atmosphere to obtain the red mud-based composite calcium ferrite; where the calcium source is selected from the group consisting of lime and calcium carbonate. In the present disclosure, the composite calcium ferrite is prepared using a solid waste red mud, with a greatly reduced cost of raw materials; on the other hand, compared with traditional calcium ferrite, the composite calcium ferrite mainly has phase structures of CaFe.sub.2O.sub.4, Ca.sub.2FeAlO.sub.5, and Ca.sub.2Fe.sub.2O.sub.5. Therefore, the composite calcium ferrite has a lower melting point, a higher lime dissolution efficiency, and better fluxing and dephosphorization effects during primary smelting and refining of molten steel, and has broad prospects for use in industry.

To provide a ferrite sintered magnet having a high residual magnetic flux density (Br), a high coercive force (HcJ), a good production stability, and also able to produce at a low cost. The ferrite sintered magnet includes a hexagonal M-type ferrite including A, R, Fe, and Co in an atomic ratio of A.sub.1-xR.sub.x(Fe.sub.12-yCo.sub.y).sub.zO.sub.19. A is at least one selected from Sr, Ba, and Pb. R is La only or La and at least one selected from rare earth elements. 0.14≤x≤0.22, 11.60≤(12-y)z≤11.99, and 0.13≤yz≤0.17 are satisfied. 0.30≤Mc≤0.63 is satisfied in which Mc is CaO content (mass %) converted from a content of Ca included in the ferrite sintered magnet.

A ferrite sintered magnet 100 comprises M-type ferrite crystal grains 4 and multiple-crystal grain boundaries 6b surrounded by three or more of the M-type ferrite crystal grains 4. The ferrite sintered magnet 100 contains at least Fe, Ca, B, and Si, and contains 0.005 to 0.9 mass % of B in terms of B.sub.2O.sub.3. The multiple-crystal grain boundaries 6b contain Si and Ca, and in a case where the molar ratio of Ca to Si in the multiple-crystal grain boundaries 6b is represented by (Ca/Si).sub.G, the following formula is satisfied.
0.1<(Ca/Si).sub.G<0.9

This ferrite sintered magnet comprises ferrite phases having a magnetoplumbite type crystal structure. This magnet comprises an element R, an element M, Fe, Co, B, Mn and Cr, the element R is at least one element selected from rare earth elements including Y, the element M is at least one element selected from the group consisting of Ca, Sr and Ba, with Ca being an essential element, and when an atomic composition of metallic elements is represented by R.sub.1-xM.sub.xFe.sub.m-yCo.sub.y, x, y and m satisfy formulae:
0.2≤x≤0.8  (1)
0.1≤y≤0.65  (2)
3≤m<14  (3). Additionally, a content of B is 0.1 to 0.4% by mass in terms of B.sub.2O.sub.3, a content of Mn is 0.15 to 1.02% by mass in terms of MnO, and a content of Cr is 0.02 to 2.01% by mass in terms of Cr.sub.2O.sub.3.

Provided is a ferrite sintered magnet including: magnetoplumbite type ferrite crystal grains; and a two-grain boundary interposed between the ferrite crystal grains. The two-grain boundary contains Ca and La, and an atomic ratio Ca/La at the two-grain boundary is 0.3 to 3.0.