C07C15/50

METHOD FOR DECOMPOSING PHENOLIC BY-PRODUCT
20220009868 · 2022-01-13 ·

The present disclosure provides a method for decomposing a phenolic by-product, the method including: a step S10 of injecting and mixing a bisphenol A by-product produced in a bisphenol A production process, a mixed by-product stream of phenol by-products produced in a phenol production process, a decomposition apparatus side discharge stream, and a process water stream in a mixing apparatus; a step S20 of injecting a mixing apparatus discharge stream discharged from the mixing apparatus into a phase separation apparatus and phase-separating the mixing apparatus discharge stream into an oil-phase stream and a liquid-phase stream; a step S30 of feeding the oil-phase stream, which is phase-separated in the step S20 and discharged from the phase separation apparatus, to a decomposition apparatus to decompose the oil-phase stream; and a step S40 of circulating the decomposition apparatus side discharge stream obtained by the decomposition in the step S30 to the mixing apparatus in the step S10.

PCNHCP METAL COMPLEXES AND USES THEREOF
20230322647 · 2023-10-12 ·

The present invention provides PC.sub.NHCP pincer metal complexes, which are useful as catalysts in various chemical reactions such as hydrogen isotope exchange (HIE) in C(sp.sup.3)-H and/or C(sp.sup.2)-H bond of an organic compound, e.g., a pharmaceutically active compound; hydroboration of alkynes with excellent selectivity; and alkene isomerization with high stereo- and regioselectivity.

PCNHCP METAL COMPLEXES AND USES THEREOF
20230322647 · 2023-10-12 ·

The present invention provides PC.sub.NHCP pincer metal complexes, which are useful as catalysts in various chemical reactions such as hydrogen isotope exchange (HIE) in C(sp.sup.3)-H and/or C(sp.sup.2)-H bond of an organic compound, e.g., a pharmaceutically active compound; hydroboration of alkynes with excellent selectivity; and alkene isomerization with high stereo- and regioselectivity.

METHOD OF DECOMPOSING PHENOLIC BY-PRODUCTS
20220259125 · 2022-08-18 ·

Provided is a method of decomposing phenolic by-products, and more particularly, a method of decomposing phenolic by-products including: supplying a phenolic by-product stream to a decomposition device to perform thermal decomposition; separating an upper discharge stream including effective components and a lower discharge stream including materials having a high boiling point in the decomposition device; supplying the lower discharge stream from the decomposition device, a side discharge stream from the decomposition device, and a process water stream to a mixing device and mixing these streams; and supplying a discharge stream from the mixing device to a layer separation device to separate the discharge stream from the mixing device into an oil phase and an aqueous phase.

METHOD OF DECOMPOSING PHENOLIC BY-PRODUCTS
20220259125 · 2022-08-18 ·

Provided is a method of decomposing phenolic by-products, and more particularly, a method of decomposing phenolic by-products including: supplying a phenolic by-product stream to a decomposition device to perform thermal decomposition; separating an upper discharge stream including effective components and a lower discharge stream including materials having a high boiling point in the decomposition device; supplying the lower discharge stream from the decomposition device, a side discharge stream from the decomposition device, and a process water stream to a mixing device and mixing these streams; and supplying a discharge stream from the mixing device to a layer separation device to separate the discharge stream from the mixing device into an oil phase and an aqueous phase.

FUNCTIONALIZED POLYCYCLIC AROMATIC HYDROCARBON COMPOUND AND LIGHT-EMITTING DEVICE INCLUDING THE SAME

Provided are a functionalized polycyclic aromatic hydrocarbon compound and a light-emitting device including the same. The functionalized polycyclic aromatic hydrocarbon compound is structurally stable, and exhibits high light-emission characteristics since aggregation caused by π-π stacking is inhibited, and thus may have high efficiency and long lifespan characteristics.

METHOD FOR PRODUCING ARENE COMPOUNDS AND ARENE COMPOUNDS PRODUCED BY THE SAME
20210188739 · 2021-06-24 ·

Provided is a method for producing (alkyl)arene compounds represented by Formulae 3-1, 3-2, and 3-3 by the Friedel-Crafts alkylation reaction of alkyl halide compounds and arene compounds using organic phosphine compounds as a catalyst.

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METHOD FOR PRODUCING ARENE COMPOUNDS AND ARENE COMPOUNDS PRODUCED BY THE SAME
20210188739 · 2021-06-24 ·

Provided is a method for producing (alkyl)arene compounds represented by Formulae 3-1, 3-2, and 3-3 by the Friedel-Crafts alkylation reaction of alkyl halide compounds and arene compounds using organic phosphine compounds as a catalyst.

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IONIC METAL ALKYLIDENE COMPOUNDS AND USE THEREOF IN OLEFINIC METATHESIS REACTIONS

A compound of formula (I) wherein: M is selected from Mo or W; X is selected from O or NR.sup.5; R.sup.1 and R.sup.2 are independently selected from H, C.sub.1-6 alkyl, and aryl; C.sub.1-6 alkyl and aryl optionally being substituted with one or more of C.sub.1-6 alkyl, C.sub.1-6 alkoxy, and OC.sub.6H.sub.5; R.sup.3 is selected from a nitrogen-containing aromatic heterocycle being bound to M via said nitrogen; and from halogen; R.sup.4 is an aryl oxy group being bound to M via said oxygen of said aryl oxy group; wherein said aryl group Ar of said aryl oxy group is bound to a group Cat such to form a cationic ligand Cat.sup.+-ZArO, wherein Z is either a covalent bond or a linker; R.sup.5 is alkyl or aryl, optionally substituted.

##STR00001##

IONIC METAL ALKYLIDENE COMPOUNDS AND USE THEREOF IN OLEFINIC METATHESIS REACTIONS

A compound of formula (I) wherein: M is selected from Mo or W; X is selected from O or NR.sup.5; R.sup.1 and R.sup.2 are independently selected from H, C.sub.1-6 alkyl, and aryl; C.sub.1-6 alkyl and aryl optionally being substituted with one or more of C.sub.1-6 alkyl, C.sub.1-6 alkoxy, and OC.sub.6H.sub.5; R.sup.3 is selected from a nitrogen-containing aromatic heterocycle being bound to M via said nitrogen; and from halogen; R.sup.4 is an aryl oxy group being bound to M via said oxygen of said aryl oxy group; wherein said aryl group Ar of said aryl oxy group is bound to a group Cat such to form a cationic ligand Cat.sup.+-ZArO, wherein Z is either a covalent bond or a linker; R.sup.5 is alkyl or aryl, optionally substituted.

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